Bipolar electrodes with semiconductor layers providing integrated procedures for the electrolysis of water

• US 20020130051A1
• Filed: 02/26/2002
• Published: 09/19/2002
• Est. Priority Date: 02/18/2000
• Status: Abandoned Application

• Current Assignee: Provera GmbH
• Original Assignee: Provera GmbH
• Inventors: Janicke, Rene Nikolai, Haug, Helmar
• Application Number:
  US10/083,096
• Publication Number:
  US 20020130051A1
• Time in Patent Office: Days
• US Class Current: 205/742
• CPC Class Codes: C25B 1/55 Photoelectrolysis
• CPC Class Codes: C25B 11/091 consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
• CPC Class Codes: C25B 11/093 at least one noble metal or noble metal oxide and at least one non-noble metal oxide
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02P 20/129 Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

The invention concerns a bipolar electrode with a semiconductor coating and a cathode, as well as a procedure for the electrolytic dissociation of water, especially for the recovery of hydrogen. The body material of the cathode and/or the anode in this procedure is preferably comprised of titanium or platinum coated titanium, whereby, on the anode an additional semiconductor coating is applied, said coating being preferentially titanium dioxide (TiO₂), which is dosed with iron (Fe). The advantage of the bipolar electrode is that an increased volume of hydrogen per time unit can be recovered and further, with these bipolar electrodes a simple procedure at ambient surroundings and conditions is achieved without expensive equipment for hydrogen production. In addition the anode of the invented bipolar electrodes can also be radiated with UV-radiation for the purpose of an increase in efficiency.

Claims

1. A bipolar electrode with a semiconductor coating, comprising an anode and a cathode, said anode and cathode displaced apart from one another, said cathode and anode comprising a body material selected from the group consisting of elements of the main groups III, IV and the groups 4-7 of the periodic system or mixtures thereof, and a semiconductor coating on the outer surface of said anode body, said semiconductor coating selected from the group consisting of at least one element of groups 4-7 of the periodic system.

2. A bipolar electrode with a semiconductor coating in accordance with claim 1 wherein in that the body material of the cathode and/or the anode consists of titanium alone or in combination with another group III, IV or groups 4-7 element.

3. A bipolar electrode with a semiconductor coating in accord with claim 1 wherein the semiconductor coating applied on the body material of the anode comprises a titanium oxide (Ti_xO_y), wherein x and y are positive integers.

4. A bipolar electrode with a semiconductor coating in accordance with claim 3 wherein said semiconductor coating is TiO₂.

5. A bipolar electrode with a semiconductor coating in accordance with claim 1 wherein the body material of at least one of the two electrodes is provided with a coating of at least one element selected from the group consisting of subordinate groups 1, 2 and 8 of the periodic system, or mixtures thereof.

6. A bipolar electrode with a semiconductor coating in accordance with claim 5 wherein said coating comprises platinum.

7. A bipolar electrode with a semiconductor coating in accordance with claim 5 wherein the thickness coating on the anode is between 1 and 2 μ

m.

8. A bipolar electrode with a semiconductor coating in accordance with claim 1 wherein the semiconductor coating applied to the body material of the anode is dosed with one or more of the elements of the first, second, and/or eighth subordinate groups of the periodic system.

9. A bipolar electrode with a semiconductor coating in accordance with claim 8 wherein iron (Fe) is employed as an element for dosing of the semiconductor.

10. A bipolar electrode with a semiconductor coating in accordance with claim 9 wherein the concentration of iron (Fe) in the semiconductor coating is in the range of 1 wt % to 33 wt %.

11. A bipolar electrode with a semiconductor coating in accordance with claim 9 wherein the concentration of iron (Fe) in the semiconductor coating is approximately 23 wt %.

12. A bipolar electrode with a semiconductor coating in accordance with claim 4 wherein the titanium oxide coating is applied by means of a sol-gel procedure.

13. A bipolar electrode with a semiconductor coating in accordance with claim 9 wherein the dosing of the titanium dioxide coating with iron (Fe) is carried out by means of a sol-gel procedure.

14. A bipolar electrode with a semiconductor coating in accordance with claim 13 wherein the application of the titanium dioxide coating and the dosing with iron (Fe) is done substantially simultaneously.

15. A procedure for the electrolytic dissociation of water employing a bipolar electrode in accordance with claim 1, comprising the following process steps:

a.) preparing a bipolar electrode in accordance with claim 1;

b) inserting the bipolar electrode into an appropriate electrolyte within a container;

(c) adjusting the pH value of the electrolyte to a pH of about 13-14;

(d) applying a direct current voltage to the bipolar electrodes;

(e) continuously circulating the electrolyte liquid by means of a circulation apparatus; and

(f) discharging the gases evolved at the electrodes by means of a pair of gas lines.

16. A procedure in accordance with claim 15 wherein the temperature of the electrolysis is regulated at ca. 22°

C.

17. A procedure in accordance with claim 15 further containing the step of continuously radiating the anode with UV-radiation in the range of ca. 250 to 380 nm.

18. A procedure in accordance with claim 17 wherein the source of the UV-radiation lies outside of the container for the electrolyte liquid.