Electrophoretic medium and display with improved image stability

• US 20020180687A1
• Filed: 04/02/2002
• Published: 12/05/2002
• Est. Priority Date: 04/02/2001
• Status: Active Grant

• Current Assignee: E Ink Holdings Incorporated
• Original Assignee: E Ink Holdings Incorporated
• Inventors: Webber, Richard M.
• Granted Patent: US 7,170,670 B2
• Time in Patent Office: Days
• US Class Current: 345/107
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 2202/022 polymeric
• CPC Class Codes: G09G 2320/0233 Improving the luminance or brightness uniformity across the screen
• CPC Class Codes: G09G 2320/0252 Improving the response speed
• CPC Class Codes: G09G 2330/021 Power management, e.g. power saving
• CPC Class Codes: G09G 3/344 based on particles moving in a fluid or in a gas, e.g. electrophoretic devices electrophoretic devices per se G02F1/167

Abstract

An electrophoretic medium comprises a plurality of particles suspended in a suspending fluid, the particles being capable of moving through the fluid upon application of an electric field to the medium, the fluid having dissolved or dispersed therein a polymer having a number average molecular weight in excess of about 20,000, the polymer being essentially non-absorbing on the particles. The polymer improves the bistability of the display (i.e., the period for which a written image persist without the display being refreshed) but does not greatly increase the viscosity of the suspending fluid, thus keeping the switching time of the display within reasonable limits. The medium may be encapsulated, or may be in the form a polymer-dispersed electrophoretic medium.

Claims

1. An electrophoretic medium comprising a plurality of particles suspended in a suspending fluid, the particles being capable of moving through the fluid upon application of an electric field to the medium, the fluid having dissolved or dispersed therein a polymer having a number average molecular weight in excess of about 20,000, the polymer being essentially non-absorbing on the particles.

2. An electrophoretic medium according to claim 1 wherein the polymer has a number average molecular weight in excess of about 100,000.

3. An electrophoretic medium according to claim 2 wherein the polymer has a number average molecular weight in the range of about 150,000 to about 3,000,000.

4. An electrophoretic medium according to claim 1 wherein the polymer has a weight average molecular weight in excess of about 100,000.

5. An electrophoretic medium according to claim 4 wherein the polymer has a weight average molecular weight in the range of about 300,000 to about 3,000,000.

6. An electrophoretic medium according to claim 1 wherein the polymer has a polydispersity index not greater than about 2.

7. An electrophoretic medium according to claim 1 wherein the polymer is a hydrocarbon polymer essentially free from aromatic groups.

8. An electrophoretic medium according to claim 7 wherein the polymer is a polyolefin.

9. An electrophoretic medium according to claim 8 wherein the polymer is a polyisobutylene.

10. An electrophoretic medium according to claim 9 wherein the polyisobutylene has a viscosity average molecular weight in the range of about 200,000 to 1,200,000 g/mole.

11. An electrophoretic medium according to claim 1 wherein the polymer is a polysiloxane.

12. An electrophoretic medium according to claim 1 wherein the suspending fluid is an aliphatic hydrocarbon.

13. An electrophoretic medium according to claim 1 wherein the suspending fluid is a mixture of an aliphatic hydrocarbon and a halogenated hydrocarbon.

14. An electrophoretic medium according to claim 1 wherein the suspending fluid and polymer are such that the scaling exponent for variation of intrinsic velocity with molecular weight falls in the range of about 0.55 to about 0.8.

15. An electrophoretic medium according to claim 1 wherein the polymer is present in an amount of from about 0.25 to about 2.5 percent by weight of the suspending fluid.

16. An electrophoretic medium according to claim 15 wherein the polymer is present in an amount of from about 1 to about 2 percent by weight of the suspending fluid.

17. An electrophoretic medium according to claim 1 which is encapsulated, with the suspending fluid and particles being retained within a plurality of capsules.

18. An electrophoretic medium according to claim 1 which is of a two-phase type, the suspending fluid and particles forming a discontinuous phase comprising a plurality of droplets, the droplets being surrounded by a continuous phase.

19. An electrophoretic medium according to claim 18 wherein said droplets comprise at least about 40 percent by volume of the electrophoretic medium.

20. An electrophoretic medium according to claim 1 which is of the dual particle type having two different types of particles having different electrophoretic mobilities.

21. An electrophoretic medium according to claim 20 which is encapsulated, with the suspending fluid and the two types of particles being retained within a plurality of capsules.

22. An electrophoretic medium according to claim 1 having an image stability of at least about 1,000 seconds.

23. An electrophoretic medium according to claim 22 having an image stability of at least about 10,000 seconds.

25. An electrophoretic display comprising an electrophoretic medium according to claim 1 and at least one electrode arranged adjacent the medium and capable of applying an electric field to the medium.

26. An electrophoretic display according to claim 25 having two electrodes disposed on opposed sides of the electrophoretic medium, at least one of the electrodes being substantially transparent such that the electrophoretic medium can be viewed through the substantially transparent electrode.

27. An electrophoretic display according to claim 25, wherein the suspending fluid and particles being retained within a plurality of capsules, the capsules being retained within a solid binder, and the electrode being secured to the binder.

24. An electrophoretic medium comprising a plurality of particles suspended in a hydrocarbon suspending fluid, the particles being capable of moving through the fluid upon application of an electric field to the medium, the fluid having dissolved or dispersed therein a polyisobutylene having a viscosity average molecular weight in the range of about 400,000 to 1,200,000 g/mole, the polyisobutylene comprising from about 0.5 to about 2.5 percent by weight of the suspending fluid.

28. An electrophoretic medium comprising a plurality of particles suspended in a suspending fluid, the particles being capable of moving through the fluid upon application of an electric field to the medium, the fluid having dissolved or dispersed therein a polymer having an instrinsic viscosity of η

in the suspending fluid and being substantially free from ionic or ionizable groups in the suspending fluid, the polymer being present in the suspending fluid in a concentration of from about 0.5 [η

]<sup>−

1</sup> to about 2.0 [η

]<sup>−

1</sup>.