Method for simultaneous removal and sequestration of CO2 in a highly energy efficient manner

• US 20030017088A1
• Filed: 07/20/2001
• Published: 01/23/2003
• Est. Priority Date: 07/20/2001
• Status: Abandoned Application

• Current Assignee: McDermott Technology, Inc.
• Original Assignee: McDermott Technology, Inc.
• Inventors: Downs, William, Sarv, Hamid
• Application Number:
  US09/909,592
• Publication Number:
  US 20030017088A1
• Time in Patent Office: Days
• US Class Current: 422/176
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/77 Liquid phase processes
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A CO₂ removal and sequestration system uses a limestone bed of coarse crushed limestone covering pipes which carry a flue gas. The pipes have spaced openings which permit flue gas to pass into the limestone bed. Water fills the bed to about {fraction (2/3 )} of the height of the limestone, which is higher than the depth of the pipes. The water flows through the bed at a predetermined rate. The bed is arranged as a series of parallel rows of beds with open channels between each pair of adjacent rows. The open channels are alternating water inlet and outlet channels. A flue gas delivery system includes headers and manifolds for distributing the flue gas at sufficient pressure to overcome existing water pressure at the pipe openings. The process includes the steps of removing CO₂ from the flue gas in the bed, dissolving CO₂ in the water in the bed, and then returning the water/CO₂ to the ocean, river, lake or other area which may be used to store CO₂.

Claims

1. A system for removing and sequestering a preselected amount of carbon dioxide (CO₂) from a gas having an original CO₂ concentration, the system comprising:

a reaction bed;

distribution means for introducing a gas having an original concentration of CO₂ to the bed;

a CO₂ solvent supplied to the bed;

chemical means disposed within the bed for removing a preselected amount of CO₂ from the gas;

means for dissolving the removed, preselected amount of CO₂ into the solvent; and

means for disposing of a portion of the solvent which contains the removed, preselected and dissolved CO₂.

2. A system according to claim 1, wherein the distribution means comprises a plurality of perforated pipes.

3. A system according to claim 1, wherein the solvent is at least one selected from the group consisting of:

fresh water, salt water and brackish water.

4. A system according to claim 1, wherein the chemical means comprises limestone.

5. A system according to claim 1, wherein the means for dissolving the CO₂ into the solvent comprises a series of drains integrated into the bed.

6. A system according to claim 1, wherein the means for disposing of the solvent includes transporting the portion of the solvent which contains the removed, preselected and dissolved CO₂ to at least one of:

a CO₂ storage facility, a deep ocean location, an underground aquifer and a depleted gas well.

7. A system according to claim 1, wherein the means for disposing of the solvent is driven by gravitational forces.

8. A system according to claim 4, wherein the chemical means comprises limestone.

9. A system according to claim 8, wherein the limestone is granulated.

10. A system according to claim 9, wherein the granulated limestone comprises a plurality of stones of a discrete diameter and wherein the diameter of the stones is determined by a Sauter mean diameter calculation.

11. A system according to claim 1, wherein at least 90% of the original CO₂ concentration of the gas is dissolved in the portion of the solvent that is disposed of.

12. A system according to claim 1, wherein no more than 90% of the original CO₂ concentration of the gas is dissolved in the portion of the solvent that is disposed of.

14. An apparatus according to claim 13, wherein the distribution means comprises a plurality of perforated pipes.

15. An apparatus according to claim 13, wherein the means for transporting the water comprises at least one drain grate.

16. An apparatus according to claim 13, wherein the number, length and height of at least one of:

the inlet channels and the outlet channels, is determined by the flow rate of the water divided by a superficial velocity of the water.

17. An apparatus according to claim 13, wherein at least 90% of the original CO₂ concentration of the gas is dissolved in the water transported to the outlet channels.

18. An apparatus according to claim 13, wherein no more than 90% of the original CO₂ concentration of the gas is dissolved in the water transported to the outlet channels.

19. An apparatus according to claim 13, wherein the water is supplied from at least one selected from the group consisting of:

a fresh water source, a salt water source and a brackish water source.

20. An apparatus according to claim 13, wherein the means for transporting the water is driven by gravitational forces.

13. An apparatus having a defined reaction bed for removing and sequestering CO₂ from a gas, the apparatus comprising:

a plurality of inlet channels having a defined length and height;

means for supplying water at a controlled flow rate into at least one inlet channel;

chemical means for removing CO₂ from a gas having an original concentration of CO₂, the chemical means being in fluidic contact with at least one inlet channel;

distribution means for distributing the gas so that the gas comes into contact with the chemical means;

a plurality of outlet channels having a defined length and height located proximate to the chemical means; and

means for transporting the water from the chemical means into at least one outlet channel, the means for transporting the water being in fluidic contact with the chemical means.