Heat treatable coated articles with metal nitride layer and methods of making same

• US 20030031879A1
• Filed: 05/03/2001
• Published: 02/13/2003
• Est. Priority Date: 05/03/2001
• Status: Active Grant

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: Wang, Hong, Stachowiak, Grzegorz, Neuman, George
• Granted Patent: US 6,524,714 B1
• Time in Patent Office: Days
• US Class Current: 428/428
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: Y10T 428/12847 Cr-base component
• CPC Class Codes: Y10T 428/12944 Ni-base component

Abstract

A heat treatable coated article including a solar management layer for reflecting infrared (IR) or the like, is provided between a substrate and an overlying dielectric layer. An underlying dielectric layer between the substrate and solar management layer is optional. In certain embodiments, the solar management layer may include NiCrN_x while the dielectric layer(s) may include a nitride such as silicon nitride. By nitriding the solar management layer, it has been found that the resulting coated article is more color stable upon heat treatment (HT). For example, the coated article may have a ΔE* value (transmissive and/or glass side reflective) of no greater than 5.0, more preferably no greater than 4.0, and most preferably no greater than 3.0. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windows, or the like.

Claims

1. A coated article comprising:

a layer system supported by a glass substrate, said layer system comprising a metal nitride inclusive layer located between first and second dielectric layers, wherein the second dielectric layer is at least partially nitrided and positioned so that the metal nitride inclusive layer is between the second dielectric layer and the glass substrate; and

wherein said coated article has a transmissive Δ

E*_T value no greater than 5.0 after at least about 5 minutes of heat treatment at a temperature(s) of at least about 600 degrees C.

2. The coated article of claim 1, wherein said coated article has a transmissive Δ

E*_T value no greater than 4.0 after said heat treatment.

3. The coated article of claim 1, wherein said coated article has a transmissive Δ

E*_T value no greater than 3.0 after said heat treatment, and wherein the coated article has a transmissive a* color value that is negative both before and after said heat treatment.

4. The coated article of claim 1, wherein said coated article has a transmissive Δ

a* value no greater than 1.3 following said heat treatment.

5. The coated article of claim 4, wherein said coated article has a transmissive Δ

a* value no greater than 1.1 following said heat treatment.

6. The coated article of claim 5, wherein said coated article has a transmissive Δ

a* value no greater than 0.8 following said heat treatment.

7. The coated article of claim 1, wherein the coated article has a transmissive a* color value that is negative both before and after said heat treatment.

8. The coated article of claim 1, wherein said metal nitride inclusive layer comprises NiCrN_x.

9. The coated article of claim 8, wherein said second dielectric layer comprises silicon nitride.

10. The coated article of claim 1, wherein said first dielectric layer comprises silicon nitride and is from 30-250 {acute over (Å

)} thick, said metal nitride inclusive layer comprises NiCrN_x and is from 20-600 {acute over (Å

)} thick, and said second dielectric layer comprises silicon nitride and is from 100-500 {acute over (Å

)} thick.

11. The coated article of claim 10, wherein said first dielectric layer is from 50-120 {acute over (Å

)} thick, said metal nitride inclusive layer is from 50-350 {acute over (Å

)} thick, and said second dielectric layer is from 210-310 {acute over (Å

)} thick.

12. The coated article of claim 1, wherein the article is characterized by the following transmissive color characteristics before said heat treatment:

a* 0.0 to −

5.0

b* −

2.0 to −

15.0

L* 10.0 to 70.0.

13. The coated article of claim 12, wherein the article is characterized by the following transmissive color characteristics before said heat treatment:

a* 0.0 to −

2.0

b* −

3.0 to −

9.0

L* 20.0 to 50.0.

14. The coated article of claim 1, wherein the coated article has a sheet resistance (R_s) of no greater than 250 ohms/sq. after said heat treatment, and wherein said heat treatment causes sheet resistance of said coated article to decrease.

37. The coated article of claim 1, wherein said coated article has a glass side reflective Δ

b*_G value no greater than 1.1 following said heat treatment.

38. The coated article of claim 1, wherein said coated article has a glass side reflective Δ

b*_G value no greater than 0.7 following said heat treatment.

15. A coated article comprising:

a layer system supported by a glass substrate, said layer system comprising a metal nitride inclusive layer located between said glass substrate and an at least partially nitrided dielectric layer, wherein the metal nitride comprises at least one of NiN_x and CrN_x and contacts said dielectric layer; and

wherein said coated article has a glass side reflective Δ

E*_G value no greater than 5.0 in view of thermal tempering including heat treating for at least about 5 minutes.

16. The coated article of claim 15, wherein said coated article has a Δ

E*_G value no greater than 4.0 after said thermal tempering.

17. The coated article of claim 16, wherein said coated article has a Δ

E*_G value no greater than 3.0 after heat treatment comprising heat treatment for at least about 5 minutes at temperature of at least about 600 degrees C., and wherein the coated article has a glass side reflective a* color value that is negative both before and after said heat treatment.

18. The coated article of claim 15, wherein said coated article has a glass side reflective Δ

a* value no greater than 1.0 following said thermal tempering.

19. The coated article of claim 18, wherein said coated article has a glass side reflective Δ

a* value no greater than 0.6 following said thermal tempering.

20. The coated article of claim 18, wherein said coated article has a glass side reflective Δ

a* value no greater than 0.3 following said thermal tempering.

21. The coated article of claim 15, wherein the coated article has a glass side reflective a* color value that is negative both before and after said thermal tempering.

22. The coated article of claim 15, wherein said metal nitride inclusive layer comprises NiCrN_x.

23. The coated article of claim 15, wherein said dielectric layer is in contact with said metal nitride inclusive layer and comprises silicon nitride.

24. The coated article of claim 15, wherein the coated article has a sheet resistance (R_s) of no greater than 500 ohms/sq. after said thermal tempering, and an wherein said thermal tempering causes sheet resistance of said coated article to decrease.

39. The coated article of claim 15, wherein said coated article has a glass side reflective Δ

b*_G value no greater than 1.1 following said thermal tempering.

25. A coated article comprising:

a layer system supported by a glass substrate, said layer system comprising a NiCrN_x inclusive layer wherein at least 50% of the Cr is nitrided, said NiCrN_x inclusive layer being located between and contacting first and second dielectric layers, wherein the second dielectric layer is at least partially nitrided and positioned so that the NiCrN_x inclusive layer is between the second dielectric layer and the glass substrate; and

wherein said coated article has a transmissive Δ

E*_T value no greater than 5.0 following or due to heat treatment.

26. The coated article of claim 25, wherein said NiCrN_x inclusive layer is sufficiently nitrided so that the coated article has a Δ

E* <

=4.0 following heat treatment for at least about 5 minutes at temperature of at least 600 degrees C.

40. The coated article of claim 25, wherein said coated article has a glass side reflective Δ

b*_G value no greater than 1.1 following said heat treatment.

27. A method of making a coated article, the method comprising:

providing a glass substrate;

depositing a metal on the substrate in an atmosphere including a significant amount of nitrogen in order to form a metal nitride inclusive layer on the glass substrate;

depositing a dielectric nitride inclusive layer on the substrate over the metal nitride inclusive layer; and

heat treating the article which includes at least the metal nitride inclusive layer and the dielectric nitride inclusive layer for at least 5 minutes, the metal nitride inclusive layer being nitrided to an extent so that after said heat treating the article has a Δ

E value of no greater than 5.0.

28. The method of claim 27, wherein the article has a Δ

E value of no greater than 4.0.

29. The method of claim 28, wherein the article has a Δ

E value of no greater than 3.0.

30. The method of claim 27, further comprising depositing another dielectric layer onto the substrate, so that the metal nitride inclusive layer is deposited onto the substrate over the another dielectric layer.

31. The method of claim 27, where the metal nitride inclusive layer comprises NiCrN_x, and wherein the dielectric nitride comprises silicon nitride.

32. The method of claim 27, wherein the Δ

E value is transmissive or glass side reflective.

33. The method of claim 27, wherein the metal nitride comprises CrN_x.

34. A coated article comprising:

a layer system supported by a glass substrate, said layer system comprising a metal nitride inclusive layer located between first and second dielectric layers, wherein the second dielectric layer is at least partially nitrided and positioned so that the metal nitride inclusive layer is between the second dielectric layer and the glass substrate; and

wherein said coated article has a transmissive Δ

a* value no greater than 1.1 after at least about 5 minutes of heat treatment at temperature of at least about 600 degrees C.

35. The coated article of claim 34, wherein said coated article has a transmissive Δ

a* value no greater than 0.8 after at least about 5 minutes of heat treatment at temperature of at least about 600 degrees C.

36. A method of making a coated article, the method comprising:

providing a glass substrate;

depositing a metal on the substrate in an atmosphere including a significant amount of nitrogen in order to form a metal nitride inclusive layer on the glass substrate;

depositing a dielectric nitride inclusive layer on the substrate over the metal nitride inclusive layer; and

heat treating the article which includes at least the metal nitride inclusive layer and the dielectric nitride inclusive layer for at least 5 minutes, the metal nitride inclusive layer being nitrided to an extent so that after said heat treating the article has a transmissive Δ

a* value of no greater than 1.1.

41. A coated article comprising:

a layer system supported by a glass substrate, said layer system comprising a metal nitride inclusive layer located between first and second dielectric layers, wherein the second dielectric layer is at least partially nitrided and positioned so that the metal nitride inclusive layer is between the second dielectric layer and the glass substrate; and

wherein said coated article has a glass side reflective Δ

b*_G value no greater than 1.1 after at least about 5 minutes of heat treatment at temperature of at least about 600 degrees C.

42. The coated article of claim 41, wherein said coated article has a glass side reflective Δ

b*_G value no greater than 0.7 following said heat treatment.