Transesterification process for production of biodiesel

• US 20030032826A1
• Filed: 07/19/2002
• Published: 02/13/2003
• Est. Priority Date: 07/20/2001
• Status: Abandoned Application

• Current Assignee: Board of Regents of the University of Nebraska
• Original Assignee: Board of Regents of the University of Nebraska
• Inventors: Hanna, Milford A.
• Application Number:
  US10/200,061
• Publication Number:
  US 20030032826A1
• Time in Patent Office: Days
• US Class Current: 554/124
• CPC Class Codes: C10L 1/026 for compression ignition
• CPC Class Codes: C11B 13/00 Recovery of fats, fatty oils or fatty acids from waste materials
• CPC Class Codes: C11C 3/003 by esterification of fatty acids with alcohols C11C3/02 takes precedence
• CPC Class Codes: C11C 3/10 Ester interchange
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02W 30/74 Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes

Abstract

A process for the production of fatty acid esters from a triglyceride feedstock is provided. The process comprises introducing a catalyst and a triglyceride feed stream comprising the triglyceride feedstock into a reaction zone and introducing an alcohol into the feed stream within the reaction zone to form a product mixture comprising fatty acid esters, glycerol and unreacted alcohol. The feed stream into which the alcohol is introduced is characterized as having a Reynolds number of at least about 2100.

The invention further provides for a process and apparatus for introducing the alcohol into the triglyceride feed stream via a distributed feed system.

Claims

1. A process for the production of fatty acid esters from a triglyceride feedstock, the process comprising:

introducing a triglyceride feed stream comprising the triglyceride feedstock into a reaction zone;

introducing a catalyst into the reaction zone;

introducing an alcohol into the triglyceride feed stream within the reaction zone, the triglyceride feed stream into which the alcohol is introduced being characterized as having a Reynolds number of at least about 2100; and

reacting the triglyceride feedstock and the alcohol to form a product mixture comprising fatty acid esters, glycerol and unreacted alcohol.

2. A process as set forth in claim 1, wherein the catalyst is introduced into the triglyceride feed stream within the reaction zone.

3. A process as set forth in claim 2, wherein the alcohol and the catalyst are simultaneously introduced into the triglyceride feed stream.

4. A process as set forth in claim 1 further comprising:

neutralizing the product mixture;

evaporating unreacted alcohol from the product mixture; and

separating said fatty acid esters from said glycerol in said product mixture.

5. A process as set forth in claim 4 wherein the evaporated alcohol is recycled to the reaction zone.

6. A process as set forth in claim 1 wherein the triglyceride feedstock comprises a vegetable oil, an animal fat or a mixture thereof.

7. A process as set forth in claim 6 wherein the triglyceride feedstock is selected from the group consisting of beef tallow, corn oil, soybean oil, rapeseed oil, peanut oil, sunflower oil, canola oil and mixtures thereof.

8. A process as set forth in claim 1 wherein the triglyceride feedstock comprises used cooking oil.

9. A process as set forth in claim 1 wherein the alcohol is a primary or secondary monohydric aliphatic alcohol having one to eight carbon atoms.

10. A process as set forth in claim 9 wherein the alcohol is selected from the group consisting of methanol, ethanol, propanol, butanol and amyl alcohol.

11. A process as set forth in claim 9 wherein the alcohol is methanol or ethanol.

12. A process as set forth in claim 9 wherein the alcohol is methanol.

13. A process as set forth in claim 1 wherein the catalyst comprises an alkali metal.

14. A process as set forth in claim 13 wherein the catalyst is selected from the group consisting of an alkali metal hydroxide, an alkali metal carbonate, an alkali metal alkoxide and mixtures thereof.

15. A process as set forth in claim 14 wherein the alkali metal is selected from the group consisting of sodium and potassium.

16. A process as set forth in claim 14 wherein the catalyst is potassium hydroxide or sodium hydroxide.

17. A process as set forth in claim 14 wherein the catalyst is sodium hydroxide.

18. A process as set forth in claim 1 wherein the catalyst comprises an acid selected from the group consisting of sulfuric acid, hydrochloric acid, sulfonic acid and mixtures thereof.

19. A process as set forth in claim 1 wherein the catalyst comprises a biocatalyst.

20. A process as set forth in claim 19 wherein the catalyst is a lipase.

21. A process as set forth in claim 1 wherein the molar ratio of alcohol to triglyceride introduced into the reaction zone is less than about 6:

1.

22. A process as set forth in claim 21 wherein the molar ratio of alcohol to triglyceride introduced into the reaction zone is about 5:

1.

23. A process as set forth in claim 22 wherein the molar ratio of alcohol to triglyceride introduced into the reaction zone is about 4:

1.

24. A process as set forth in claim 1 wherein the triglyceride feed stream into which the alcohol is introduced is characterized as having a Reynolds number of from about 2100 to about 4000.

25. A process as set forth in claim 1 wherein the triglyceride feed stream into which the alcohol is introduced is characterized as having a Reynolds number of at least about 4000.

26. A process as set forth in claim 1 wherein the reaction zone comprises a venturi injector.

27. A continuous process for the production of fatty acid esters by transesterification of a triglyceride feedstock with an alcohol in the presence of a catalyst, the process comprising:

introducing a triglyceride feed stream comprising the triglyceride feedstock into a first mixing zone of a reaction zone comprising two or more mixing zones in series;

introducing the alcohol into the triglyceride feed stream within the first mixing zone of said series of mixing zones;

introducing the catalyst into the reaction zone;

reacting the triglyceride feedstock and the alcohol in the reaction zone to produce an intermediate reaction mixture stream comprising fatty acid esters, glycerol and unreacted triglyceride feedstock and alcohol;

introducing the intermediate reaction mixture stream into a second mixing zone of said series of mixing zones;

introducing the alcohol into the intermediate reaction mixture stream within the second mixing zone of said series of mixing zones;

reacting the unreacted triglyceride feedstock in the intermediate reaction mixture stream with the alcohol introduced into the intermediate reaction mixture stream in the reaction zone; and

withdrawing a final reaction product mixture containing fatty acid esters, glycerol and unreacted alcohol from the reaction zone.

28. A process as set forth in claim 27 wherein the triglyceride feed stream into which the alcohol is introduced is characterized as having a Reynolds number of at least about 2100.

29. A process as set forth in claim 28 wherein the triglyceride feed stream into which the alcohol is introduced is characterized as having a Reynolds number of from about 2100 to about 4000.

30. A process as set forth in claim 28 wherein the triglyceride feed stream into which the alcohol is introduced is characterized as having a Reynolds number of at least about 4000.

31. A process as set forth in claim 27 wherein the catalyst is introduced into the triglyceride feed stream within the first mixing zone of said series of mixing zones.

32. A process as set forth in claim 31 wherein the alcohol and catalyst are simultaneously introduced into the triglyceride feed stream within the first mixing zone of said series of mixing zones.

33. A process as set forth in claim 31 wherein additional catalyst is introduced into intermediate reaction mixture stream within the second mixing zone of said series of mixing zones.

34. A process as set forth in claim 27 wherein the reaction zone comprises from two to twelve mixing zones in series.

35. A process as set forth in claim 34 wherein the alcohol is introduced into the intermediate reaction mixture stream within each mixing zone after the first mixing zone of said series of mixing zones.

36. A process as set forth in claim 35 wherein the catalyst is introduced into the triglyceride feed stream within the first mixing zone and additional catalyst is introduced into the intermediate reaction mixture stream within one or more mixing zones after the first mixing zone of said series of mixing zones.

37. A process as set forth in claim 35 wherein additional catalyst is introduced into the intermediate reaction mixture stream within each mixing zone after the first mixing zone of said series of mixing zones.

38. A process as set forth in claim 35 wherein the reaction zone comprises four mixing zones in series.

39. A process as set forth in claim 38 wherein each mixing zone is provided by a venturi injector.

40. A process as set forth in claim 35 wherein the triglyceride feed stream and the intermediate reaction mixture stream into which the alcohol is introduced are characterized as having a Reynolds number of at least about 2100.

41. A process as set forth in claim 40 wherein the triglyceride feed stream and the intermediate reaction mixture stream into which the alcohol is introduced is characterized as having a Reynolds number of from about 2100 to about 4000.

42. A process as set forth in claim 40 wherein the triglyceride feed stream and the intermediate reaction mixture stream into which the alcohol is introduced is characterized as having a Reynolds number of at least about 4000.

43. A process as set forth in claim 27 wherein the triglyceride feedstock comprises a vegetable oil, an animal fat or a mixture thereof.

44. A process as set forth in claim 43 wherein the triglyceride feedstock is selected from the group consisting of beef tallow, corn oil, soybean oil, rapeseed oil, peanut oil, sunflower oil, canola oil and mixtures thereof.

45. A process as set forth in claim 27 wherein the triglyceride feedstock comprises used cooking oil.

46. A process as set forth in claim 27 wherein the alcohol is a primary or secondary monohydric aliphatic alcohol having one to eight carbon atoms.

47. A process as set forth in claim 46 wherein the alcohol is selected from the group consisting of methanol, ethanol, propanol, butanol and amyl alcohol

48. A process as set forth in claim 46 wherein the alcohol is methanol or ethanol.

49. A process as set forth in claim 46 wherein the alcohol is methanol.

50. A process as set forth in claim 27 wherein the catalyst comprises an alkali metal.

51. A process as set forth in claim 50 wherein the catalyst is selected from the group consisting of an alkali metal hydroxide, an alkali metal carbonate, an alkali metal alkoxide and mixtures thereof.

52. A process as set forth in claim 50 wherein the alkali metal is selected from the group consisting of sodium and potassium.

53. A process as set forth in claim 52 wherein the catalyst is sodium hydroxide or potassium hydroxide.

54. A process as set forth in claim 52 wherein the catalyst is sodium hydroxide.

55. A process as set forth in claim 27 wherein the catalyst comprises an acid selected from the group consisting of sulfuric acid, hydrochloric acid, sulfonic acid and mixtures thereof.

56. A process as set forth in claim 27 wherein the catalyst comprises a biocatalyst.

57. A process as set forth in claim 56 wherein the catalyst is a lipase.

58. A process as set forth in claim 27 wherein the molar ratio of alcohol to triglyceride feedstock introduced into the reaction zone is less than about 6:

1.

59. A process as set forth in claim 58 wherein the molar ratio of alcohol to triglyceride feedstock introduced into the reaction zone is about 5:

1.

60. A process as set forth in claim 59 wherein the molar ratio of alcohol to triglyceride feedstock introduced into the reaction zone is about 4:

1.

61. A process as set forth in claim 27 further comprising:

neutralizing the final product mixture;

evaporating unreacted alcohol from the final product mixture; and

separating the fatty acid esters from the glycerol contained in said final product mixture.

62. A process as set forth in claim 61 wherein the evaporated alcohol is recycled to the reaction zone.