Surfactant systems for agriculturally active compounds

• US 20030050194A1
• Filed: 09/05/2002
• Published: 03/13/2003
• Est. Priority Date: 09/07/2001
• Status: Active Grant

• Current Assignee: Syngenta Crop Protection Incorporated (China National Chemical Corporation)
• Original Assignee: Syngenta Crop Protection Incorporated (China National Chemical Corporation)
• Inventors: Hopkinson, Michael J., Moore, Carolyn E., Fowler, Jeffrey D.
• Granted Patent: US 6,746,988 B2
• Time in Patent Office: Days
• US Class Current: 504/363
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 37/18 containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
• CPC Class Codes: A01N 37/22 the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
• CPC Class Codes: A01N 43/54 1,3-Diazines; Hydrogenated 1,3-diazines
• CPC Class Codes: A01N 43/70 Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
• CPC Class Codes: A01N 43/84 six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
• CPC Class Codes: A01N 57/20 containing acyclic or cycloaliphatic radicals

Abstract

The invention provides surfactant systems comprising alkyl polyglycosides, anionic surfactants and basic compounds. The invention also provides agricultural compositions comprising agriculturally active compounds, alkyl polyglycosides, anionic surfactants and basic compounds. The surfactant systems and agricultural compositions may further comprise nonionic surfactants.

Claims

1. An agricultural composition comprising

at least one agriculturally active compound;

at least one alkyl polyglycoside;

at least one anionic surfactant selected from a polyaryIphenol polyalkoxyether sulfate and a polyarylphenol polyalkoxyether phosphate; and

at least one basic compound;

wherein the at least one anionic surfactant is neutralized to the inflection point in the titration curve with the at least one basic compound.

2. The agricultural composition of claim 1, further comprising at least one nonionic surfactant.

3. The agricultural composition of claim 1, wherein the polyarylphenol polyalkoxyether sulfate is a polyarylphenol polyethoxyether sulfate and the polyarylphenol polyalkoxyether phosphate is a polyarylphenol polyethoxyether phosphate.

4. The agricultural composition of claim 3, wherein the polyarylphenol polyethoxyether sulfate is a tristyrylphenol polyethoxyether sulfate, and the polyarylphenol polyethoxyether phosphate is a tristyrylphenol polyethoxyether phosphate.

5. The agricultural composition of claim 1, wherein the alkyl polyglycoside is a compound of formula (I):

R₁O(R₂O)_b(Z)_a 

 

(I)

wherein R₁ is a monovalent organic radical having from about 6 to about 30 carbon atoms;

R₂ is a divalent alkylene radical having from about 2 to about 4 carbon atoms;

b is 0 to about 100;

Z is a saccharide residue having about 5 to about 6 carbon atoms; and

a is an integer from about 1 to about 6.

6. The agricultural composition of claim 5, wherein R₁ is a C_8-11 alkyl group, b is 0, a is 2, and Z is glucose.

7. The agricultural composition of claim 1, wherein the basic compound is an inorganic base, a C_8-18 alkyl amine polyalkoxylate, an alkanol amine, an alkanol amide, or a mixture thereof.

8. The agricultural composition of claim 1, wherein the basic compound is a tallow amine ethoxylate, a cocoamine alkoxylate, a oleylamine alkoxylate, a stearylamine alkoxylate, a linoleic diethanolamide, or a mixture thereof.

9. The agricultural composition of claim 2, wherein the nonionic surfactant is an ethylene oxide-propylene oxide block copolymer, ethylene oxide-butylene oxide block copolymer, a C_2-6 alkyl adduct of an ethylene oxide-propylene oxide block copolymer, a C_2-6 alkyl adduct of an ethylene oxide-butylene oxide block copolymer, a polypropylene glycol, a polyethylene glycol, a polyarylphenol polyethoxy ether, a polyalkylphenol polyethoxy ether, a polyglycol ether derivative of a saturated fatty acid, a polyglycol ether derivative of an unsaturated fatty acid, a polyglycol ether derivative of an aliphatic alcohol, a polyglycol ether derivative of a cycloaliphatic alcohol, a fatty acid ester of polyoxyethylene sorbitan, an alkoxylated vegetable oil, an alkoxylated acetylenic diol, or a mixture thereof.

10. The agricultural composition of claim 1, wherein the at least one agriculturally active compound is present in an amount of about 1 to about 75% by weight;

the at least one alkyl polyglycoside is present in an amount of about 0.1 to about 8% by weight;

the at least one anionic surfactant is present in an amount of about 0.1 to about 8% by weight; and

the at least one basic compound is present in an amount of about 0.1 to about 8% by weight.

11. The agricultural composition of claim 10, wherein the at least one agriculturally active compound is present in an amount of about 15 to about 70% by weight;

the at least one alkyl glycoside is present in an amount of about 1 to about 4% by weight;

the at least one anionic surfactant is present in an amount of about 1 to about 4% by weight; and

the at least one basic compound is present in an amount of about 0.5 to about 4% by weight.

12. The agricultural composition of claim 2, wherein the at least one agriculturally active compound is present in an amount of about 1 to about 75% by weight;

the at least one alkyl polyglycoside is present in an amount of about 0.1 to about 8% by weight;

the at least one anionic surfactant is present in an amount of about 0.1 to about 8% by weight;

the at least one basic compound is present in an amount of about 0.1 to about 8% by weight; and

the at least one nonionic surfactant is present in an amount of about 0.1 to about 8% by weight.

13. The agricultural composition of claim 12, wherein the at least one agriculturally active compound is present in an amount of about 15 to about 70% by weight;

the at least one alkyl glycoside is present in an amount of about 1 to about 4% by weight;

the at least one anionic surfactant is present in an amount of about 1 to about 4% by weight;

the at least one basic compound is present in an amount of about 0.5 to about 4% by weight; and

the at least one nonionic surfactant is present in an amount of about 0.5 to about 3% by weight.

14. The agricultural composition of claim 1, wherein the at least one agriculturally active compound is glyphosate;

S-metolachlor;

atrazine;

glufosinate;

acetochlor;

mesotrione;

glyphosate and S-metolachlor;

glyphosate, S-metolachlor and atrazine;

glyphosate, S-metolachlor, atrazine and benoxacor;

S-metolachlor and atrazine;

S-metolachlor, atrazine and benoxacor;

S-metolachlor, atrazine and butavenacil;

S-metolachlor, atrazine, benoxacor and butafenacil;

glyphosate, acetochlor and atrazine;

glyphosate, S-metolachlor and atrazine;

glufosinate, acetochlor and atrazine;

glufosinate, S-metolachlor and atrazine;

mesotrione and S-metolachlor;

mesotrione, S-metolachlor and benoxacor;

mesotrione, S-metolachlor and atrazine;

or mesotrione, S-metolachlor, benoxacor and atrazine.

15. The agricultural composition of claim 1, wherein the agriculturally active compound is a fungicide, an insecticide, an herbicide, a growth regulator, a safener, a plant activator, or a mixture thereof.

16. The agricultural composition of claim 15, wherein the fungicide is azoxystrobin, benalaxyl, benomyl, bitertanol, borax, bromocuonazole, sec-butylamine, captafol, captan, calcium polysulfide, carbendazim, chinomethionat, chlorothalonin, chlozolinate, copper sulfate, cyprodinil, cyproconazole, dichlofluanid, dichlorophen, diclomezine, dicloran, diethofencarb, difenoconazole, dimethomorph, diniconazole, dithianon, epoxiconazole, famoxadone, fenarimol, fenbuconazole, fenfuram, fenpiclonil, fenpropidin, fenpropimorph, fentin, fluazinam, fludioxonil, fluoroimide, fluqinconazole, flusulfamide, flutolanil, folpet, fosetyl, furalaxyl, guazatine, hexachlorobenzene, hexaconazole, hydroxyquinoline sulfate, imibenconazole, iminoctadine, ipconazole, iprodione, kasugamycin, kresoxim-methyl, mancozeb, maneb, mefenoxam, mepanipyrim, mepronil, mercuric chloride, metam, metalaxyl, metconazole, metiram, nabam, nickel bis(dimethyldithiocarbamate), nuarimol, oxadixil, oxine-copper, oxolinic acid, penconazole, pencycuron, phthalide, polyoxin B, procymidone, propamocarb, propiconazole, propineb, pyrifenox, pyroquilon, quintozene, sulfur, tebuconazole, tecloftalam, tccnazene, thiabendazole, thifluzamide, thiophanate-methyl, thiram, tolclofos-methyl, tolylfluanid, triadimefon, triadimenol, triazoxide, trifloxystrobin, triforine, triticonazole, vinclozolin, zineb, ziram, salts thereof, or a mixture thereof.

17. The agricultural composition of claim 15, wherein the insecticide is abamectin, acephate, acrinathrin, amitraz, azadirachtin, azamethiphos, azinphos-methyl, azocyclotin, bensultap, bifenthrin, bromopropylate, buprofezin, butoxycarboxim, cartap, chlorfenapyr, chlorfenson, chlorfluazuron, clofentezine, coumaphos, cyfluthrin, beta-cyfluthrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, theta-cypermethrin, cyromazine, DDT, deltamethrin, diafenthiuron, dicofol, dicrotophos, difenthiuron, diflubenzuron, emamectin benzoate, endosulfan, esfenvalerate, etoxazole, fenazaquin, fenbutatin oxide, fenoxycarb, fenpyroximate, fipronil, fluazuron, flucycloxuron, flufenoxuron, tau-fluvalinate, formetanate, furathiocarb, halofenozide, gainma-HCH, hexaflumuron, hexythiazox, hydramethylnon, hydrogen cyanide, lufenuron, methamidophos, methidathion, methiocarb, methomyl, methoxychlor, mevinphos, milbemectin, monocrotophos, nicotine, nitenpyram, novaluron, omethoate, organophosphorus compounds, oxamyl, oxydemeton-methyl, pentachlorophenol, phosphamidon, pymetrozin, permethrin, profenofos, pyridaben, resmethrin, rotenone, sulfluramid, tebufenozide, tebufenpyrad, tebupirimfos, teflubenzuron, tetrachlorvinphos, tetradifon, tetramethrin, thiamethoxam, thiocyclam, thiodicarb, tralomethrin, trichlorfon, friflumuron, trimethacarb, vamidothion, and salts thereof, or a mixture thereof.

18. The agricultural composition of claim 15, wherein the herbicide is acetochlor, acifluorfen, aclonifen, acrolein, alachlor, ametryne, amitrole, asulam, atrazine, benazolin, bensulfuron-methyl, bentazon, benzofenap, bialaphos, bifenox, bromacil, bromobutide, bromofenoxim, bromoxynil, butachlor, butafenacil, chlomethoxyfen, chloramben, chloroacetic acid, chlorbromuron, chlorimuron-ethyl, chlorotoluron, chlornitrofen, chlorotoluron, chlorthal-dimethyl, clodinafop, clopyralid, clomeprop, cyanazine, 2,4-D, 2,4-DB, daimuron, dalapon, desmedipham, desmetryn, dicamba, dichlobenil, dichloroprop, diclofop, difenzoquat, diflufenican, dimefuron, dimethachlor, dimethametryn, dimethenamid, dinitramine, diquat, diuron, endothall, ethametsulfuron-methyl, fenac, fenclorim, fenoxaprop, fenoxaprop-ethyl, flamprop-methyl, flazasulfuron, fluazifop, fluazifop-p-butyl, flumetsulam, flumiclorac-penyl, fluoroglycofen, flumetsulam, flumeturon, flumioxazin, flupoxam, flupropanate, fluridone, flurtamone, fomasafen, fosamine, glufosinate, glyphosate, haloxyfop, imazaineth, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, ioxynil, isoproturon, isoxaben, isoxapyrifop, lactofen, lenacil, linuron, MCPA, MCPB, mecoprop, mefenacet, mesotrione, metazachlor, methabenzthiazuron, methylarsonic acid, metolachlor, metobenzuron, naproanilide, naptalam, neburon, nonanoic acid, norflurazon, oryzalin, oxadiazon, oxyfluorfen, paraquat, phenmedipham, picloram, pretilachlor, prodiamine, prometon, prometryn, propachlor, propazine, propisochlor, propyzamide, pyrazolynate, pyrazosulfuron-ethyl, pyributicarb, pyridate, quinclorac, quizalofop-ethyl, rimsulfuron, siduron, simazine, simetryn, sulfamic acid, 2,3,6-TBA, terbumeton, terbuthylazine, terbutryn, trichloroacetic acid, triclopyr, trietazine, thenylchlor, thiazopyr, tralkoxydim, trietazine, salts thereof, or a mixture thereof.

19. The agricultural composition of claim 15, wherein the growth regulator is 6-benzylaminopurine, chlormequat, chlorphonium, cimectacarb, clofencet, cloxyfonac, cyanamide, cyclanilide, daminozide, dikegulac, ethephon, flumetralin, forchlorfenuron, inabenfide, 2-(1-naphthyl)acetamide, mepiquat, paclobutrazol, N-phenylphthalamic acid, thidiazuron, uniconzole, salts thereof, or a mixture thereof.

20. The agricultural composition of claim 15, wherein the safener is benoxacor, cloquintocet, dichliormid, fenclorim, fluxofenime, furilazole, oxabetrinil, salts thereof, or a mixture thereof.

21. The agricultural composition of claim 15, wherein the plant activator is acibenzolar-S-methyl.

22. The agricultural composition of claim 1, further comprising water.

23. The agricultural composition of claim 1, further comprising a thickener.

24. The agricultural composition of claim 1, further comprising an anti-foaming agent.

25. The agricultural composition of claim 1, further comprising a frost protecting agent.