Foamed Polymer System employing blowing agent performance enhancer

• US 20030050352A1
• Filed: 09/03/2002
• Published: 03/13/2003
• Est. Priority Date: 09/04/2001
• Status: Abandoned Application

• Current Assignee: L&L Products Inc.
• Original Assignee: Symyx Technologies Incorporated (Dassault Systemes SA)
• Inventors: Guenther, Thomas, Carlson, David
• Application Number:
  US10/233,919
• Publication Number:
  US 20030050352A1
• Time in Patent Office: Days
• US Class Current: 521/50
• CPC Class Codes: C08J 9/0052 Organo-metallic compounds
• CPC Class Codes: C08J 9/10 developing nitrogen , the blowing agent being a compound containing a nitrogen-to-nitrogen bond

Abstract

A foamed polymer system includes a blowing agent performance enhancer to ensure that the foaming rate of the blowing agent is sufficient to achieve the desired foam characteristics and to improve control over the blowing agent performance. The system includes a combination of an azo-type compound with a metallic salt of an organic acid in the manufacture of the foamed polymer.

Claims

1. A foamed polymer article, comprising:

a polymer material having a plurality of cells defined therein wherein said cells are the product of an interaction involving;

a blowing agent; and

a blowing agent performance enhancer.

2. The article according to claim 1, wherein said blowing agent is an azo-type blowing agent.

3. The article according to claim 1, wherein said blowing agent is selected from the group consisting of a dinitrosopentanethylenetetramine-type blowing agent, an oxibis benzene-sulfonyl hydrazide-type blowing agent, a toluene sulfonyl hydrazide-type blowing agent, and a rubber type blowing agent.

4. The article according to claim 1 wherein said blowing agent performance enhancer is a metallic salt of an organic acid.

5. The article according to claim 1 wherein said blowing agent is azo-bis-dicarbonamide.

6. The article according to claim 4. wherein said metallic component of said metallic salt is one selected from the group consisting of alkali metals, alkali earth metals and mixtures thereof.

7. The article according to claim 6 wherein said metallic component of said metallic salt is selected from the group consisting of zinc, potassium, lithium, sodium, calcium, magnesium and mixtures thereof.

8. The article according to claim 7, wherein said metallic component of said metallic salt is sodium.

9. The article according to claim 4, wherein said organic acid component of said performance enhancer has about 2 to about 22 carbon atoms per molecule.

10. The article according to claim 9, wherein said organic acid component of said performance enhancer has about 2 to about 22 carbon atoms per molecule.

11. The article according to claim 10, wherein said organic acid component of said performance enhancer is selected from the group consisting of acetates, stearates, propionates and mixtures thereof.

12. The article according to claim 11, wherein said organic acid component of said performance enhancer is an acetate.

13. The article according to claim 4, wherein said performance enhancer is selected from the group consisting of sodium acetate, potassium acetate, and calcium acetate.

14. The article according to claim 2, further wherein said performance enhancer is selected from the group consisting of sodium acetate, potassium acetate, and calcium acetate.

15. The article according to claim 5, further wherein said performance enhancer is sodium acetate.

16. The article according to claim 1, wherein the amount of said performance enhancer to the amount of said blowing agent is about 1:

25.

17. The article according to claim 16 wherein the amount of said blowing agent comprises an azobisdicarbonamide.

18. A blowing agent performance enhancement system for making foamed polymer articles, comprising:

an azo-type blowing agent; and

an organic acid of a metallic salt.

19. The system according to claim 18, wherein said blowing agent is azodicarbonamide and said organic acid of a metallic salt is sodium acetate.

20. A foamed polymer article, comprising:

a cellular polymer foam structure prepared by the interaction of;

an azobisdicarbonamide and sodium acetate.

21. The article according to claim 20 wherein said ratio of azobisdicarbonamide to sodium acetate is about 6:

1.