Apparatus for measuring concentration of ammonia gas

• US 20030062264A1
• Filed: 09/10/2002
• Published: 04/03/2003
• Est. Priority Date: 09/11/2001
• Status: Abandoned Application

• Current Assignee: NGK Spark PLUG Company Limited
• Original Assignee: NGK Spark PLUG Company Limited
• Inventors: Kitanoya, Shoji, Ishida, Noboru
• Application Number:
  US10/237,877
• Publication Number:
  US 20030062264A1
• Time in Patent Office: Days
• US Class Current: 204/424
• CPC Class Codes: G01N 33/0054 for ammonia
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

An apparatus for measuring the concentration of ammonia gas, including a solid electrolyte body having oxygen ion conductivity, a reference electrode formed on a first inner surface of the solid electrolyte body and contacting a reference gas, a detecting electrode formed on a second outer surface of the solid electrolyte body and containing a noble metal and/or a metal oxide therein, a Pd catalyst layer formed on an outer surface of the detecting electrode and including a Pd-containing porous body, and a heater element for heating the solid electrolyte body.

Claims

1. An apparatus for measuring the concentration of ammonia gas, the apparatus comprising:

a solid electrolyte body having oxygen ion conductivity,

a reference electrode formed on a first surface of the solid electrolyte body for contacting a reference gas,

a detecting electrode formed on a second surface of the solid electrolyte body and containing at least one of a noble metal and/or a metal oxide therein, and

a Pd catalyst layer formed on an outer surface of the detecting electrode and including a Pd-containing porous body.

3. The apparatus as claimed in claim 1, further comprising a heater element for heating the solid electrolyte body, and wherein said first surface of the solid electrolyte body is an inner surface.

5. The apparatus as claimed in claim 3, wherein the detecting electrode is formed on only a portion of said second surface of the solid electrolyte body corresponding to a heating resistor provided in the interior of the heater element.

7. The apparatus as claimed in claim 3, wherein:

the solid electrolyte body has a closed cylindrical shape,

the detecting electrode is formed on only a portion of said second surface of the solid electrolyte body that extends from the position on said second surface corresponding to the region of an interface between a heating resistor provided in the interior of the heater element and a lead portion of the heating resistor, to the position on said second surface which corresponds to a closed end portion of the solid electrolyte body.

9. The apparatus as claimed in claim 3, comprising a temperature control unit adapted to control a voltage applied to the heater element, on the basis of internal resistance of the solid electrolyte body.

11. The apparatus according to claim 9, comprising an internal resistance measuring electrode which is formed on said first surface of the solid electrolyte body and in the vicinity of a heating resistor of the heater element so as to be separated from the reference electrode, and which is adapted to measure internal resistance of the solid electrolyte body,

the temperature control unit being adapted to measure the internal resistance of the solid electrolyte body by the internal resistance measuring electrode and detecting electrode.

2. An apparatus for measuring the concentration of ammonia gas, the apparatus comprising:

a solid electrolyte body having oxygen ion conductivity,

a reference electrode formed on a first surface of the solid electrolyte body for contacting a reference gas,

a detecting electrode formed on a second surface of the solid electrolyte body and containing at least one of a noble metal and/or a metal oxide therein, and

a Pd catalyst layer formed on an outer surface of the detecting electrode and including a porous body and Pd supported by said porous body.

4. The apparatus as claimed in claim 2, further comprising a heater element for heating the solid electrolyte body, and wherein said first surface of the solid electrolyte body is an inner surface.

6. The apparatus as claimed in claim 4, wherein the detecting electrode is formed on only a portion of said second surface of the solid electrolyte body corresponding to a heating resistor provided in the interior of the heater element.

8. The apparatus as claimed in claim 4 wherein:

the solid electrolyte body has a closed cylindrical shape,

the detecting electrode is formed on only a portion of said second surface of the solid electrolyte body that extends from the position on said second surface corresponding to the region of an interface between a heating resistor provided in the interior of the heater element and a lead portion of the heating resistor, to the position on said second surface which corresponds to a closed end portion of the solid electrolyte body.

10. The apparatus as claimed in claim 4, comprising a temperature control unit adapted to control a voltage applied to the heater element, on the basis of internal resistance of the solid electrolyte body.

12. The apparatus as claimed in claim 10, comprising an internal resistance measuring electrode which is formed on said first surface of the solid electrolyte body and in the vicinity of a heating resistor of the heater element so as to be separated from the reference electrode, and which is adapted to measure internal resistance of the solid electrolyte body,

the temperature control unit being adapted to measure the internal resistance of the solid electrolyte body by the internal resistance measuring electrode and detecting electrode.