Compositions comprising solid particles and binder

• US 20030065082A1
• Filed: 05/08/2002
• Published: 04/03/2003
• Est. Priority Date: 05/08/2001
• Status: Abandoned Application

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Schoneveld, Erik, Van Helden, Arend Kuindert, Blanken, Thomas Carel, Wisse, Willem, Reynhout, Marinus Johannes, Mooiweer, Hendrik Harm, Majoor, Joannes Cornelis Jozef Emmanuel
• Application Number:
  US10/141,152
• Publication Number:
  US 20030065082A1
• Time in Patent Office: Days
• US Class Current: 524/492
• CPC Class Codes: B29B 17/0026 by agglomeration or compacting
• CPC Class Codes: B29K 2023/06 PE, i.e. polyethylene
• CPC Class Codes: B29K 2023/083 EVA, i.e. ethylene vinyl acetate copolymer
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2105/16 Fillers
• CPC Class Codes: B29L 2031/7158 Bottles
• CPC Class Codes: C04B 24/2611 Polyalkenes
• CPC Class Codes: C04B 26/006 Waste materials as binder
• CPC Class Codes: C04B 26/18 Polyesters; Polycarbonates
• CPC Class Codes: C04B 40/0085 involving melting of at least part of the composition
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

Compositions of especially good properties particularly for use in the construction industry have been found which comprise a matrix of solid particles, comprising at least two groups of particle types selected from aggregate, sand and filler, embedded in a binder, which is predominantly polyethylene terephthalate, wherein the binder is present in an amount in the range of from 1 to 50% by weight. Also provided is a process for the preparation of such a composition, which comprises mixing heated particles and binder, shaping if desired, and allowing the mixture to solidify, wherein solid particles and binder are heated independently of each other prior to mixing such that on mixing the temperature of the mixture is in the range of from 230 to 300° C., and wherein the solid particles are heated to a higher temperature than the binder.

Claims

1. A process for the preparation of a composition comprising a matrix of solid particles embedded in a binder, wherein the binder is present in an amount in the range of from 1 to 50% by weight and comprises a synthetic thermoplastic polymer, said process comprising mixing heated particles and binder, optionally shaping, and allowing the mixture to solidify, wherein solid particles and binder are heated independently of each other prior to mixing such that on mixing the temperature of the mixture is in the range of from 230 to 300°

C., and wherein the solid particles are heated to a higher temperature than the binder.

2. The process of claim 1 wherein the binder content is at least 15% by weight.

3. The process of claim 1 wherein the polymer present in the binder is waste or recycled polymer selected from the group consisting of polypropylene, polyethylene terephthalate, polybutylene terephthalate, and mixtures thereof, which is heated prior to mixing to a temperature in the range of from 50 to 240°

C., and wherein solid particles heated prior to mixing are heated to a temperature in the range of from 150 to 350°

C.

4. The process of claim 3 wherein the polymer is waste or recycled polyethylene terephthalate, optionally in admixture with waste or recycled polypropylene, which is preheated to a temperature in the range of from 180 to 240°

C. and wherein the solid particles are preheated to a temperature of 300°

C.

5. The process of claim 1 wherein the solid particles are a combination of aggregate, filler and sand, all of which are heated prior to mixing with the binder, with the aggregate and sand materials being mixed first with the binder, and the filler mixed in subsequently.

6. A composition comprising a matrix of solid particles, which comprises at least two groups of particle types selected from aggregate, sand and filler, embedded in a binder, which is predominantly polyethylene terephthalate, wherein the binder is present in an amount in the range of from 1 to 50% by weight.

7. The composition of claim 6 wherein the binder also contains polypropylene and the binder is present in an amount in the range of from 20 to 35% by weight.

8. The composition of claim 6 which contains titanium dioxide as filler in an amount in the range of from 2 to 9% by weight.

9. The composition of claim 6 wherein the flexural strength of the composition is at least 3 N/mm² according to the standard NEN 7014.

10. The composition of claim 6 wherein the flexural strength of the composition is at least 10 N/mm² according to the NEN EN198-1.

11. A construction element comprising composition of claim 6 and at least one additive.

12. A construction element comprising a composition of claim 6.

13. A construction element comprising a composition of claim 7.

14. A decorative element comprising the composition of claim 6.

15. A decorative element comprising the composition of claim 7.