Pressure sensitive adhesive, particularly for apolar surfaces

• US 20030096111A1
• Filed: 05/21/2002
• Published: 05/22/2003
• Est. Priority Date: 06/20/2001
• Status: Active Grant

• Current Assignee: Tesa SE (Maxingvest AG)
• Original Assignee: Tesa AG (Maxingvest AG)
• Inventors: Zollner, Stephan, Husemann, Marc
• Granted Patent: US 6,652,963 B2
• Time in Patent Office: Days
• US Class Current: 428/355.0AC
• CPC Class Codes: C08F 290/04 Polymers provided for in subclasses C08C or C08F
• CPC Class Codes: C08F 293/005 using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
• CPC Class Codes: C08F 297/02 using a catalyst of the anionic type
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C09J 153/00 Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
• CPC Class Codes: Y10S 526/931 Pressure sensitive adhesive
• CPC Class Codes: Y10T 428/2891 including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof

Abstract

A pressure sensitive adhesive based on block copolymers which have at least one unit composed of a series of three alternating polymer blocks P(A) and P(B), wherein

P(A) represents a homopolymer or copolymer block formed from a component A which itself comprises at least one acrylated macromonomer of general formula

CH₂═CH(R^I)(COOR^II)  (I)

in which R^I=H or CH₃ and R^II is an aliphatic linear, branched or cyclic, unsubstituted or substituted, saturated or unsaturated, alkyl radical having more than 30 carbon atoms, and the average molecular weight M_n of said at least one macromonomer being between 492 g/mol and 30 000 g/mol,

P(B) represents a homopolymer or copolymer block formed from a monomeric component B which itself comprises at least one monomer B1, the polymer block P(B) having a softening temperature of from −80° C. to +20° C., and

the polymer blocks P(A) being immiscible with the polymer blocks P(B).

Claims

1. A pressure sensitive adhesive based on block copolymers, said block copolymers having at least one unit composed of a series of three alternating polymer blocks, each of which blocks are selected from the group consisting of P(A) and P(B), wherein

P(A) represents a homopolymer or copolymer block formed from a component A which itself comprises at least one monomer A1,

said at least one monomer A1 being an acrylated macromonomer of general formula

CH₂═

CH(R^I)(COOR^II) 

 

(I)

in which R^I=H or CH₃ and R^II is an aliphatic linear, branched or cyclic, unsubstituted or substituted, saturated or unsaturated, alkyl radical having more than 30 carbon atoms, and the average molecular weight M_n of said at least one macromonomer being between 492 g/mol and 30 000 g/mol,

P(B) represents a homopolymer or copolymer block formed from a monomeric component B which itself comprises at least one monomer B1, the polymer block P(B) having a softening temperature of from −

80°

C. to +20°

C., and

the polymer blocks P(A) being immiscible with the polymer blocks P(B).

2. The pressure sensitive adhesive of claim 1, wherein monomer A1 is selected from the group consisting of hydrogenated ethylene/propylene macromonomers and hydrogenated ethylene/butylene macromonomers which possess a softening temperature of not more than 0°

C. and have an acrylate or methacrylate end group.

3. The pressure sensitive adhesive of claim 1, wherein component B is composed at least in part of monomers B1 selected from the following groups:

(a) acrylic and methacrylic acid derivatives of the general formula

CH₂═

CH(R^III)(COOR^IV) 

 

(II)

in which R^III=H or CH₃ and R^IV represents a linear or branched aliphatic alkyl chain having from 2 to 20 carbon atoms,

(b) vinyl compounds,

component B being composed of from 60 to 100% by weight of compounds from group (a) and from 0 to 40% by weight of compounds from group (b).

4. The pressure sensitive adhesive of claim 3, wherein at least one of the monomers of component B contains one or more functional groups through which the block copolymer is crosslinkable.

5. The pressure sensitive adhesive of claim 1, wherein the polymer blocks P(B) of component B form a two-phase domain structure with the copolymer blocks P(A) of component B.

6. The pressure sensitive adhesive of claim 1, wherein the block copolymers have an average molecular weight (number average) of between 5 000 and 600 000 g/mol.

7. The pressure sensitive adhesive of claim 1, wherein the polymer blocks P(B) comprise between 10 and 60% by weight of the overall block copolymer.

8. The pressure sensitive adhesive as of claim 1, comprising up to 50% by weight of resins, and/or additives selected from the group consisting of crosslinkers, aging inhibitors, light stabilizers, ozone protectants, fatty acids, plasticizers, nucleators, expandants, accelerators and fillers.

9. An adhesive tape comprising the pressure sensitive adhesive of claim 1.

10. A process for preparing the pressure sensitive adhesive of claim 1, which comprises preparing the block copolymer by means of a thioester- or trithiocarbonate-controlled radical polymerization.

11. The pressure sensitive adhesive of claim 3, wherein said linear or branched aliphatic alkyl chain has from 4 to 14 carbon atoms.

12. The pressure sensitive adhesive of claim 11, wherein said linear or branched aliphatic alkyl chain has from 4 to 9 carbon atoms.

13. The pressure sensitive adhesive of claim 3, wherein said vinyl groups comprise one or more functional groups capable of crosslinking.

14. The pressure sensitive adhesive of claim 4, wherein said at least one of the monomers of component B is a monomer of group (b) and said block copolymer is crosslinkable by thermal or radiation-chemical crosslinking.

15. The pressure sensitive adhesive of claim 14, wherein said block copolymer is crosslinkable by UV radiation or electron-beam radiation.

16. The pressure sensitive adhesive of claim 6, wherein said molecular weight is between 80,000 and 450,000 g/mol.

17. The pressure sensitive adhesive of claim 7, wherein said polymer blocks P(B) comprise between 15-40% by weight of the overall block copolymer.

18. The pressre sensitive adhesive of claim 8, wherein said weight per cent is from 20 to 40%.

19. A method of bonding an adhesive tape to an apolar surface, which comprises bonding said apolar surface with the adhesive tape of claim 9.