Thermally stable blends of highly paraffinic distillate fuel component and conventional distillate fuel component

• US 20030098261A1
• Filed: 10/19/2001
• Published: 05/29/2003
• Est. Priority Date: 10/19/2001
• Status: Active Grant

• Current Assignee: Sasol Technology Limited (Sasol Limited)
• Original Assignee: Chevron USA Incorporated (Chevron Corp.)
• Inventors: Bacha, John D., OʼRear, Dennis J.
• Granted Patent: US 6,776,897 B2
• Time in Patent Office: Days
• US Class Current: 208/170
• CPC Class Codes: C10L 1/04 essentially based on blends of hydrocarbons

Abstract

A stable distillate fuel blend useful as a fuel or as a blending component of a fuel that is suitable for use in an internal combustion engine, said fuel blend prepared from at least one highly paraffinic distillate fuel component and at least one highly aromatic petroleum-derived distillate fuel component and a process for preparing same involving the blending of at least two components having antagonistic properties with respect to one another.

Claims

1. A distillate fuel blend useful as a fuel or as a blending component of a fuel suitable for use in an internal combustion engine, said distillate fuel blend comprising:

(a) at least one highly paraffinic distillate fuel component having a paraffin content of not less than 70 percent by weight and

(b) at least one petroleum-derived distillate fuel component having an aromatic content of not less than 30 percent by weight,

wherein the distillate fuel blend has an ASTM D6468 reflectance value of at least 65 percent when measured at 150°

C. after 90 minutes.

2. The distillate fuel blend of claim 1 wherein the paraffin content of the highly paraffinic distillate fuel component is not less than 80 percent by weight.

3. The distillate fuel blend of claim 2 wherein the paraffin content of the highly paraffinic distillate fuel component is not less than 90 percent by weight.

4. The distillate fuel blend of claim 1 wherein the aromatic content of the petroleum-derived distillate fuel component is not less than 50 percent by weight.

5. The distillate fuel blend of claim 4 wherein the aromatic content of the petroleum-derived distillate fuel component is not less than 70 percent by weight.

6. The distillate fuel blend of claim 1 further including at least one of an additional component selected from the group consisting of a non-nitrate containing ignition improver, an alklylcycloparaffin-containing blend component, an alkylaromatic-containing blend component, an anti-oxidant, a dispersant, and any combination thereof.

7. The distillate fuel blend of claim 1 wherein the reflectance value is at least 80 percent.

8. The distillate fuel blend of claim 7 wherein the reflectance value is at least 80 percent when measured at 180 minutes.

9. The distillate fuel blend of claim 8 wherein the reflectance value is at least 90 percent when measured at 180 minutes.

10. The distillate fuel blend of claim 1 further including a peroxide inhibitor.

11. The distillate fuel blend of claim 10 containing 1 ppm or greater of sulfur.

12. The distillate fuel blend of claim 1 wherein the highly paraffinic distillate fuel component is at least partially derived from a Fischer Tropsch process.

13. A process for preparing a stable distillate fuel blend comprising at least two components having antagonistic properties with respect to one another, said distillate fuel blend being useful as a fuel or as a blending component of a fuel suitable for use in an internal combustion engine which comprises the steps of:

(a) blending at least one highly paraffinic distillate fuel component having a paraffin content of not less than 70 percent by weight with at least one highly aromatic petroleum derived distillate fuel component;

(b) determining the thermal stability of the blend of step (a) using a suitable standard analytical method;

(c) modifying the blending of step (a) to achieve a pre-selected stability value as determined by the analytical method of step (b); and

(d) recovering a distillate fuel blend that is characterized by having a reflectance value of at least 65 percent as determined by ASTM D6468 when measured at 150°

C. after 90 minutes.

14. The process of claim 13 wherein modifying the blending of step (c) is accomplished by adjusting the blending ratio of the highly paraffinic distillate fuel component and the highly aromatic petroleum-derived distillate fuel component.

15. The process of claim 13 wherein modifying the blending of step (c) is accomplished by adjusting the boiling range of the highly paraffinic distillate fuel component.

16. The process of claim 13 wherein modifying the blending of step (c) is accomplished by adjusting the extent of isomerization of the highly paraffinic distillate fuel component.

17. The process of claim 13 wherein at least one further component is present in the blend, which further component is selected from the group consisting of a non-nitrate containing ignition improver, an alklylcycloparaffin-containing blend component, an alkylaromatic-containing blend component, an anti-oxidant, a dispersant and any combination thereof.

18. The process of claim 13 including an additional step of hydrotreating to reduce the aromatics present in at least one highly aromatic petroleum-derived distillate fuel component prior to blending step (a).

19. The process of claim 13 including an additional step of solvent extracting to reduce the aromatics present in at least one highly aromatic petroleum-derived distillate fuel component prior to blending step (a).

20. The process of claim 13 including an additional step of adsorbing to reduce the aromatics present in at least one highly aromatic petroleum-derived distillate fuel component prior to blending step (a).

21. The process of claim 13 wherein the distillate fuel blend recovered from step (d) is characterized by having a reflectance value of at least 80 percent as determined by ASTM D6468 when measured at 150°

C. after 90 minutes.

22. The process of claim 13 wherein the distillate fuel blend recovered from step (d) is characterized by having a reflectance value of at least 80 percent as determined by ASTM D6468 when measured at 150°

C. after 180 minutes.

23. The process of claim 13 wherein the highly parafffinic distillate fuel component is at least partially derived from the oligomerization and hydrogenation of olefins.

24. The process of claim 13 wherein the highly paraffinic distillate fuel component is at least partially derived from the hydrocracking of paraffins.

25. The process of claim 13 wherein the highly paraffinic distillate fuel component is at least partially derived from the Fischer Tropsch process.

26. The process of claim 13 wherein the paraffin content of at least one highly paraffinic distillate fuel component is greater than 80 percent by weight and the aromatic content of at least one petroleum-derived fuel component is greater than 50 percent by weight.

27. The process of claim 13 wherein at least one of the highly aromatic petroleum derived distillate fuel components contains not less than 30 percent by weight of aromatics.

28. A process for preparing a stable distillate fuel blend comprising at least two components having antagonistic properties with respect to one another, said distillate fuel blend being useful as a fuel or as a blending component of a fuel such that the blend has acceptable deposit characteristics, said process comprising the steps of:

(a) blending at least one highly paraffinic distillate fuel component having a paraffin content of not less than 70 percent by weight with at least one petroleum derived distillate fuel component having an aromatic content of not less than 30 percent by weight;

(b) determining the reflectance value of the blend of step (a) using ASTM D6468 when measured at 150°

C. after 90 minutes;

(c) modifying the blending of step (a) to achieve a reflectance value of at least 65 percent; and

(d) recovering a distillate fuel blend that is characterized by having a reflectance value of at least 65 percent as determined by ASTM D6468 when measured at 150°

C. after 90 minutes.

29. The process of claim 28 wherein the highly paraffinic distillate fuel component is at least partially derived from the Fischer Tropsch process.