Method for protecting a tire against ozone

• US 20030127170A1
• Filed: 12/09/2002
• Published: 07/10/2003
• Est. Priority Date: 06/05/2001
• Status: Abandoned Application

• Current Assignee: Michelin Recherche et Technique SA (Compagnie Generale DES Etablissements Michelin SCA)
• Original Assignee: Michelin Recherche et Technique SA (Compagnie Generale DES Etablissements Michelin SCA)
• Inventors: Peyron, Georges, Cottin, Alain
• Application Number:
  US10/314,702
• Publication Number:
  US 20030127170A1
• Time in Patent Office: Days
• US Class Current: 152/524
• CPC Class Codes: B29C 71/00 After-treatment of articles without altering their shape; Apparatus therefor B29C44/56, B29C73/00 take precedence; surface shaping B29C59/00 ; for joined or sealed parts B29C66/03; after-treatment specially adapted for vulcanising tyres B29D30/0633
• CPC Class Codes: B29D 30/0633 After-treatment specially adapted for vulcanising tyres
• CPC Class Codes: B29K 2995/0058 Inert to chemical degradation
• CPC Class Codes: B60C 1/00 Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
• CPC Class Codes: B60C 13/002 Protection against exterior elements
• CPC Class Codes: C08J 2321/00 Characterised by the use of unspecified rubbers
• CPC Class Codes: C08J 2475/00 Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: Y10T 152/10495 Pneumatic tire or inner tube

Abstract

The present invention relates to a method for anti-ozone protection of at least a part of the outer surface of a vulcanized tire, where the composition of the tire is based on essentially unsaturated dienic elastomers. The present method comprises: (1) subjecting the surface of the vulcanized tire to a treatment in order to polarize and functionalize the elastomers of the surface; (2) applying at least one layer comprising an aqueous polyurethane dispersion to this treated surface; and (3) allowing this layer to dry until a protective coating is formed. The present invention further relates to a tire comprising an anti-ozone protective coating, where the protective coating is formed according to the method described above.

Claims

1. A tire having a rubber outer surface based on essentially unsaturated dienic elastomers, wherein at least a part of the rubber outer surface is covered with a coating for protection against ozone, wherein said coating comprises at least one layer in contact with the air, wherein the layer comprises surfactants and polyurethane prepared from a polyol selected from the group consisting of aliphatic polyethers, aliphatic polyesters, and polyethers and polyesters whose main chain is semi-aromatic, and wherein bonds between the elastomer and the polyurethane are formed as a result of polar functions on the elastomer.

2. The tire of claim 1, wherein the surfactants comprise functional groups carried by the chain of the polyurethane.

3. The tire of claim 1, wherein the surfactants comprise anionic polar groups.

4. The tire of claim 1, wherein the coating comprises azomethine molecules.

5. The tire of claim 1, wherein the polyurethane has a glass transition temperature of less than or equal to −

20°

C. and an elongation at break of greater than or equal to 100%.

6. The tire of claim 5, wherein the elongation at break of the polyurethane is greater than 200%.

7. The tire of claim 1, wherein the polar functions are chlorinated functions or oxidized functions.

8. The tire of claim 1, wherein the layer comprising polyurethane has a thickness of greater than or equal to 5 μ

m.

9. The tire of claim 8, wherein the layer comprising polyurethane has a thickness of between 100 μ

m and 500 μ

m.

10. The tire of claim 1, wherein the part of the rubber outer surface of the tire covered with the coating for protection against ozone is the outer surface of the tread of the tire.

11. The tire of claim 1, wherein the part of the rubber outer surface of the tire covered with the coating for protection against ozone is the surface of the bottoms of the profile grooves of the tread of the tire.

12. The tire of claim 1, wherein the part of the rubber outer surface of the tire covered with the coating for protection against ozone is the surface of one of the sidewalls of the tire.

13. A method for protecting at least part of a rubber outer surface of a vulcanized tire from ozone, wherein the rubber outer surface is based on essentially unsaturated dienic elastomers, said method comprising:

(1) subjecting the surface of the vulcanized tire to a treatment in order to polarize and functionalize the elastomers of the surface;

(2) applying at least one layer comprising an aqueous polyurethane dispersion to the treated surface; and

(3) allowing the layer to dry until a protective coating is formed.

14. The method of claim 13, wherein the aqueous polyurethane dispersion is applied at ambient temperature.

15. The method of claim 13, wherein the layer comprising the aqueous polyurethane dispersion is dried at ambient temperature.

16. The method of claim 13, wherein the layer comprising the aqueous polyurethane dispersion is dried using heat such that the temperature of the surface on which the protective coating is formed does not exceed 60°

C.

17. The method of claim 13, wherein the treatment of the surface of the vulcanized tire comprises depositing a functionalizing agent in a solvent on the surface and drying the surface until the solvent evaporates.

18. The method of claim 17, wherein the functionalizing agent in the solvent is deposited on the surface at ambient temperature.

19. The method of claim 17, wherein the functionalizing agent in the solvent is dried at ambient temperature.

20. The method of claim 17, wherein the functionalizing agent in the solvent is dried using heat such that the temperature of the surface on which the functionalizing agent has been deposited does not exceed 60°

C.

21. The method of claim 17, wherein the functionalizing agent is selected from the group consisting of alkali metal hypochlorites added to hydrochloric acid and alkaline-earth metal hypochlorites added to hydrochloric acid.

22. The method of claim 21, wherein the functionalizing agent is selected from the group consisting of sodium, potassium and calcium hypochlorites added to hydrochloric acid.

23. The method of claim 17, wherein the functionalizing agent is trichloroisocyanuric acid.

24. The method of claim 23, wherein the trichloroisocyanuric acid is dissolved in ethyl acetate.

25. The method of claim 13, wherein the aqueous polyurethane dispersion comprises surfactants.

26. The method of claim 25, wherein the surfactants comprise functional groups carried by the chain of the polyurethane.

27. The method of claim 25, wherein the surfactants comprise anionic polar groups.

28. The method of claim 13, wherein the polyurethane is self-crosslinkable.

29. The method of claim 13, wherein the concentration of polyurethane in the aqueous polyurethane dispersion is between 10 and 50% by weight.

30. The method of claim 13, wherein the polyurethane used in the aqueous polyurethane dispersion is prepared from a polyol selected from the group consisting of aliphatic polyethers, aliphatic polyesters, and polyethers and polyesters whose main chain is semi-aromatic, wherein the polyurethane has a glass transition temperature of less than or equal to −

20°

C. and an elongation at break of greater than or equal to 100%.