Multimodal polymer particles and uses thereof

• US 20030130418A1
• Filed: 12/02/2002
• Published: 07/10/2003
• Est. Priority Date: 12/14/2001
• Status: Active Grant

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Wills, Morris Christopher, Petoff, Jennifer Lynn, Hamilton, Raymond Gerard, Adamo, Joseph Robert
• Granted Patent: US 6,884,844 B2
• Time in Patent Office: Days
• US Class Current: 525/50
• CPC Class Codes: C08F 257/02 on to polymers of styrene or alkyl-substituted styrenes
• CPC Class Codes: C08F 265/04 on to polymers of esters
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C08F 279/02 on to polymers of conjugated dienes
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/04 grafted on to rubbers

Abstract

A multimodal polymer particle composition containing two or more populations of polymer particles having a total rubbery weight fraction of less than 90 weight percent is provided. Also disclosed is a process for preparing multimodal polymer particle compositions that can be dried to a powder. Multimodal polymer particle dispersions are disclosed for preparing impact modifiers that can be dried to a powder. Also provided are polymeric compositions having a matrix resin component and impact modifiers prepared from multimodal polymer particles.

Claims

1. A multimodal polymer particle composition, comprising:

(a) a larger mode of polymer particles, and

(b) a smaller mode of polymer particles,

wherein the mean particle size of the larger mode of polymer particles is at least 50 percent larger than the mean particle size of the smaller mode of particles, said smaller mode of polymer particles having a mean particle size of greater than 200 nm,

and wherein the total rubbery weight fraction of the larger and smaller modes of polymer particles is at most 90 weight percent.

2. A multimodal polymer particle composition as recited in claim 1, further comprising up to 20 weight percent, based on total weight of polymer particles in the composition, of a third population of polymer particles having a mean particle size smaller than 200 nm.

3. A multimodal polymer particle composition as recited in claim 1, wherein the total rubbery weight fraction of the larger and smaller modes of polymer particles is at least 70 weight percent.

4. A multimodal polymer particle composition as recited in claim 1, further comprising at least one oil.

5. A multimodal polymer particle composition as recited in claim 1, wherein the composition is in the form of a powder.

6. A multimodal polymer particle dispersion, comprising:

(a) water, and

(b) polymer particles, said polymer particles comprising;

(i) a larger mode of polymer particles, and

(ii) a smaller mode of polymer particles,

wherein the mean particle diameter of the larger mode of polymer particles is at least 50 percent larger than the mean particle diameter of the smaller mode of particles, said smaller mode of polymer particles having a mean particle size of greater than 200 nm,

and wherein the total rubbery weight fraction of the larger and smaller modes of polymer particles is at most 90 weight percent.

7. A multimodal polymer particle dispersion as recited in claim 6, wherein the dispersion has a viscosity up to 2000 centipoise.

8. A multimodal polymer particle dispersion as recited in claim 6, further comprising at least one oil.

9. A multimodal polymer particle dispersion as recited in claim 6, further comprising up to 20 weight percent, based on total weight of polymer particles in the composition, of a third population of polymer particles having a mean particle size smaller than 200 nm.

10. A polymeric composition, comprising:

(a) a matrix resin component, and

(b) an impact modifier, the impact modifier comprising,

(i) a larger mode of polymer particles, and

(ii) a smaller mode of polymer particles,

wherein the mean particle diameter of the larger mode of polymer particles is at least 50 percent larger than the mean particle diameter of the smaller mode of particles, said smaller mode of polymer particles having a mean particle size of greater than 200 nm,

and wherein the total rubbery weight fraction of the larger and smaller modes of polymer particles is at most 90 weight percent.