Method for producing coatings, adhesive layers or sealing layers for primed or unprimed substrates

• US 20030148039A1
• Filed: 10/10/2002
• Published: 08/07/2003
• Est. Priority Date: 03/01/2000
• Status: Abandoned Application

• Current Assignee: BASF Coatings AG (BASF SE)
• Original Assignee: BASF Coatings AG (BASF SE)
• Inventors: Keller, Peter, Blum, Rainer, Hilger, Christopher
• Application Number:
  US10/203,391
• Publication Number:
  US 20030148039A1
• Time in Patent Office: Days
• US Class Current: 427/557
• CPC Class Codes: B05D 3/0209 Multistage baking
• CPC Class Codes: B05D 3/0263 with IR heaters
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 3/068 using ionising radiations (gamma, X, electrons)

Abstract

Process for producing coatings, adhesive films or seals which comprises

(1) applying coating materials, adhesives and sealing compounds comprising a constituent (A) which contains groups (a) containing bonds which can be activated with actinic radiation, and also photoinitiators (B), in the form of a water-free and solvent-free liquid or melt, a powder, a powder slurry, a dispersion or a solution in at least one organic solvent, dispersion or solution in an aqueous medium to and/or into a primed or unprimed substrate,

(2) drying the powder slurry layer or the layer of a dispersion or solution, or causing the layer of the melt to solidify or maintaining it in the melted state by heating,

(3) melting the solid layers by heating, and

(4) first irradiating the liquid layers resulting from step (1) of the process or the melted layers resulting from step (2) or (3) of the process in the melted state, during solidification and/or after solidification with near infrared radiation and then fully curing them with UV radiation and/or electron beams or fully curing them simultaneously with NIR radiation and UV radiation and/or electron beams.

Claims

1. A process for producing coatings, adhesive films or seals for primed or unprimed substrates, which comprises

(1) applying at least one free-radically and/or ionically curable coating material and/or adhesive and/or sealing compound comprising

(A) at least one constituent containing on average per molecule at least one group (a) containing at least one bond which can be activated with actinic radiation, and

(B) at least one photoinitiator,

in the form of

(1.1) a water-free and solvent-free liquid or melt,

(1.2) a powder,

(1.3) a powder slurry,

(1.4) a dispersion or a solution in at least one organic solvent, or

(1.5) a dispersion or a solution in an aqueous medium to and/or into the primed or unprimed substrate,

(2) drying the resultant powder slurry layer (1.3) or the resultant layer of a dispersion or a solution (1.4) or (1.5) or causing the resultant layer of the melt (1.1) to solidify or maintaining it in a melted state by heating,

(3) melting, by heating, the resultant solid layer (1.2), (1.3), (1.4) or (1.5), and

(4) first irradiating the liquid layer resulting from step (1) of the process or the melted layer resulting from step (2) or (3)of the process

(4.1) in the liquid or melted state,

(4.2) during solidification, and/or

(4.3) after solidification

with near infrared (NIR) radiation and then curing it with UV radiation and/or electron beams or fully curing it simultaneously with NIR and UV radiation and/or electron beams.

2. The process as claimed in claim 1, wherein the heating in step (2) is carried out with the aid of NIR radiation.

3. The process as claimed in claim 1 or 2, wherein the heating in step (3) is carried out with the aid of NIR radiation.

4. The process as claimed in any of claims 1 to 3, using NIR radiation of a wavelength for which the solid layers (1.2), (1.3), (1.4) and (1.5), the liquids and melts (1.1), and the melts resulting from step (4) are partly transparent.

5. The process as claimed in claim 4, wherein the solid layers (1.2), (1.3), (1.4) and (1.5), the liquids and melts (1.1), and the melts resulting from step (4) absorb from 20 to 80% of the irradiated NIR radiation.

6. The process as claimed in claim 4 or 5, wherein the NIR radiation has a wavelength of from 600 to 1400 nm.

7. The process as claimed in any of claims 1 to 6, wherein the bonds which can be activated with actinic radiation comprise carbon-hydrogen single bonds or carbon-carbon, carbon-oxygen, carbon-nitrogen, carbon-phosphorus or carbon-silicon single bonds or double bonds.

8. The process as claimed in claim 7, wherein the bonds are carbon-carbon double bonds.

9. The process as claimed in claim 8, wherein (meth)acrylate, ethacrylate, crotonate, cinnamate, vinyl ether, vinyl ester, dicyclopentadienyl, norbornenyl, isoprenyl, isopropenyl, allyl or butenyl groups;

dicyclopentadienyl ether, norbornenyl ether, isoprenyl ether, isopropenyl ether, allyl ether or butenyl ether groups;

or dicyclopentadienyl ester, norbornenyl ester, isoprenyl ester, isopropenyl ester, allyl ester or butenyl ester groups are used.

10. The process as claimed in claim 9, wherein acrylate groups are used.

11. The process as claimed in any of claims 1 to 10, wherein the constituent (A) is a solid.

12. The process as claimed in claim 11, wherein the constituent (A) is amorphous, partially crystalline, or crystalline.

17. The process as claimed in any of claims 1 to 16, wherein the groups (a) in the compound (A) are attached to the parent structure by way of urethane, urea, allophanate, ester, ether, and/or amide groups.

18. The process as claimed in claim 17, wherein the groups (a) in the constituent (A) are attached to the parent structure by way of urethane groups.

19. The process as claimed in any of claims 1 to 18, wherein the constituent (A) further comprises at least one reactive functional group (c) which with groups (c) of its own kind and/or with complementary reactive functional groups (d) is able to enter into thermal crosslinking reactions.

20. The process as claimed in any of claims 1 to 19, wherein the constituent (A) further comprises at least one chemically bonded stabilizer (e).

21. The process as claimed in claim 20, wherein a HALS compound is used as chemically bonded stabilizer (e).

22. The process as claimed in claim 21, wherein the 2,2,6,6-tetramethylpiperidine N-oxide-4-oxy group is used as chemically bonded HALS compound (e).

23. The process as claimed in any of claims 1 to 22, wherein the coating material, the adhesive or the sealing compound comprises at least one crosslinking agent (C) containing on average per molecule at least two complementary reactive functional groups (d).

24. The process as claimed in any of claims 1 to 23, wherein the coating material, the adhesive or the sealing compound comprises at least one additive (D).

25. The process as claimed in any of claims 1 to 24, wherein the solvent-free or water-free constituent (A) has a melting range or a melting point in the temperature range from 40 to 130°

C.

26. The process as claimed in any of claims 1 to 25, wherein the solvent-free or water-free constituent (A) has a melt viscosity at 130°

C. of from 50 to 20 000 mPas.

27. A primed or unprimed substrate comprising at least one coating, at least one adhesive film and/or at least one seal which can be produced by the process as claimed in any of claims 1 to 26.

28. The primed or unprimed substrate as claimed in claim 27, selected from constructions, doors, windows, motor vehicle bodies, furniture or industrial components, including coils, containers, and electrical components.

13. The process as claimed in claim 13, wherein the parent structure of the constituent (A) is of low molecular mass, oligomeric and/or polymeric.

14. The process as claimed in claim 13, wherein the oligomeric and/or polymeric parent structure of the constituent (A) comprises olefinically unsaturated double bonds.

15. The process as claimed in claim 13 or 14, wherein the oligomeric and/or polymeric parent structure of the constituent (A) is derived from random, alternating and/or block, linear, branched, hyperbranched, dendrimeric and/or comb polyaddition resins, polycondensation resins and/or addition (co)polymers of ethylenically unsaturated monomers.

16. The process as claimed in claim 15, wherein the addition (co)polymers are poly(meth)acrylates and/or partially saponified polyvinyl esters and the polyaddition resins and/or polycondensation resins are polyesters, alkyds, polyurethanes, polyester-polyurethanes, polylactones, polycarbonates, polyethers, polyester-polyethers, epoxy resin-amine adducts, polyureas, polyamides or polyimides, especially polyesters, polyester-polyethers, polyurethanes, and polyester-polyurethanes.