Process and system for the self-regulated remediation of groundwater

• US 20030155309A1
• Filed: 02/14/2003
• Published: 08/21/2003
• Est. Priority Date: 02/15/2002
• Status: Abandoned Application

• Current Assignee: Water Remediation Technology, LLC
• Original Assignee: Water Remediation Technology, LLC
• Inventors: Schindler, A. Russell
• Application Number:
  US10/366,966
• Publication Number:
  US 20030155309A1
• Time in Patent Office: Days
• US Class Current: 210/747
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: C02F 1/008 Control or steering systems not provided for elsewhere in subclass C02F
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 2103/06 Contaminated groundwater or leachate
• CPC Class Codes: C02F 2209/001 Upstream control, i.e. monitoring for predictive control
• CPC Class Codes: C02F 2209/03 Pressure
• CPC Class Codes: C02F 2209/22 O2
• CPC Class Codes: C02F 2209/24 CO2

Abstract

A process and system for the self-regulated remediation of groundwater situated beneath the surface of a contaminated ground site is herein proposed. The process includes the steps of selecting a ground site to be tested for potential contamination, extracting soil gas samples from interspersed locations within an underground soil layer, gleaning information from the extracted soil gas samples to both determine the extent of any contamination and delimit any specific area of contamination at the selected ground site, determining both an appropriate concentration of a preselected oxidant or oxygen-releasing agent within a solution and an appropriate flow rate of injection according to the determined extent of contamination, determining both an appropriate number of groundwater injection points and an appropriate spacing between the groundwater injection points according to the delimited specific area of contamination, and delivering the determined preselected oxidant solution under pressure into the groundwater within the delimited specific area of contamination via the groundwater injection points at the determined injection flow rate.

Claims

1. A process for the self-regulated remediation of groundwater situated beneath the surface of a contaminated ground site, said self-regulated groundwater remediation process comprising the steps of:

selecting a ground site to be tested for potential contamination;

extracting soil gas samples from interspersed locations within an underground soil layer disposed above the surface level of groundwater situated beneath the surface of said selected ground site;

gleaning information from said extracted soil gas samples to both determine the extent of any contamination and delimit any specific area of contamination at said selected ground site;

determining both an appropriate concentration of a preselected oxygen-releasing agent within a solution and an appropriate flow rate of injection according to said determined extent of contamination at said selected ground site;

determining both an appropriate number of groundwater injection points and an appropriate spacing between said groundwater injection points according to said delimited specific area of contamination at said selected ground site; and

delivering said determined preselected oxygen-releasing agent solution under pressure into said groundwater within said delimited specific area of contamination at said selected ground site via said groundwater injection points at said determined injection flow rate.

2. The self-regulated groundwater remediation process according to claim 1, wherein said selected ground site includes a gas station.

3. The self-regulated groundwater remediation process according to claim 1, wherein said underground soil layer from which said soil gas samples are extracted is within the vadose zone.

4. The self-regulated groundwater remediation process according to claim 1, wherein said groundwater surface level coincides with the water table beneath said selected ground site.

5. The self-regulated groundwater remediation process according to claim 1, wherein the step of extracting soil gas samples includes the steps of:

installing a plurality of monitoring wells at said selected ground site such that each said monitoring well provides fluid communication between said surface of said selected ground site, said underground soil layer, and said groundwater; and

providing a vacuum pump for each said monitoring well at said selected ground site; and

utilizing each said vacuum pump to create a vacuum within each said monitoring well to thereby draw and obtain said soil gas samples from said interspersed locations within said underground soil layer.

6. The self-regulated groundwater remediation process according to claim 1, said self-regulated groundwater remediation process further comprising the steps of:

extracting soil samples from said selected ground site; and

extracting water samples from said groundwater situated beneath said surface of said selected ground site; and

gleaning additional information from both said extracted soil samples and said extracted water samples to both further help determine the extent of any contamination and further help delimit any specific area of contamination at said selected ground site.

7. The self-regulated groundwater remediation process according to claim 6, wherein said gleaned additional information from both said extracted soil samples and said extracted water samples includes the detected presence, the species identification, and the population size of any microbial population present at said selected ground site.

8. The self-regulated groundwater remediation process according to claim 1, wherein said gleaned information from said extracted soil gas samples includes both the concentration of oxygen and the concentration of carbon dioxide within said underground soil layer.

9. The self-regulated groundwater remediation process according to claim 8, wherein the step of gleaning information from said extracted soil gas samples is accomplished with a soil gas meter.

10. The self-regulated groundwater remediation process according to claim 8, said self-regulated groundwater remediation process further comprising the step of:

regulating both said delivery pressure and said determined injection flow rate of said determined preselected oxidant solution to thereby maintain said oxygen concentration within a range of 15 to 25 percent within said underground soil layer within said delimited specific area of contamination at said selected ground site.

11. The self-regulated groundwater remediation process according to claim 1, wherein said preselected oxygen-releasing agent is hydrogen peroxide.

12. The self-regulated groundwater remediation process according to claim 1, said self-regulated groundwater remediation process further comprising the step of:

arranging said groundwater injection points in a substantially horizontal and grid-like fashion within said groundwater within said delimited specific area of contamination at said selected ground site.

13. The self-regulated groundwater remediation process according to claim 12, said self-regulated groundwater remediation process further comprising the step of:

utilizing a known local groundwater flow rate determined over a recent two-month period to determine said appropriate spacing between said groundwater injection points within said groundwater within said delimited specific area of contamination at said selected ground site.

14. The self-regulated groundwater remediation process according to claim 1, said self-regulated groundwater remediation process further comprising the step of:

utilizing a known vertical profile of said groundwater within said delimited specific area of contamination at said selected ground site to situate said groundwater injection points at approximately one-third of the way down through said known vertical profile of said groundwater within said delimited specific area of contamination at said selected ground site.

15. The self-regulated groundwater remediation process according to claim 1, said self-regulated groundwater remediation process further comprising the step of:

utilizing a pressure regulator to thereby maintain said delivery pressure of said determined preselected oxidant solution within a range of 25 to 75 pounds per square inch.

16. A process for the self-regulated remediation of groundwater situated beneath the surface of a contaminated ground site, said self-regulated groundwater remediation process comprising the steps of:

selecting a ground site to be tested for potential contamination;

extracting soil gas samples from interspersed locations within an underground soil layer disposed above the water table defined by groundwater situated beneath the surface of said selected ground site;

gleaning information from said extracted soil gas samples to both determine the extent of any contamination and delimit any specific area of contamination at said selected ground site;

determining both an appropriate concentration of hydrogen peroxide within a solution and an appropriate flow rate of injection according to said determined extent of contamination at said selected ground site;

determining both an appropriate number of groundwater injection points and an appropriate spacing between said groundwater injection points according to said delimited specific area of contamination at said selected ground site; and

delivering said determined hydrogen peroxide solution under pressure into said groundwater within said delimited specific area of contamination at said selected ground site via said groundwater injection points at said determined injection flow rate.

17. A system for the self-regulated remediation of groundwater situated beneath the surface of a contaminated ground site, said self-regulated groundwater remediation system comprising:

a plurality of monitoring wells installed interspersedly at a selected ground site to be tested for potential contamination, each said monitoring well thereby providing fluid communication between the surface of said selected ground site, groundwater situated beneath said surface of said selected ground site, and an underground soil layer disposed above the surface level of said groundwater;

a matching plurality of vacuum pumps in fluid communication with the surface openings of said monitoring wells at said selected ground site;

a matching plurality of soil gas meters in fluid communication with said surface openings of said monitoring wells at said selected ground site;

a first tank for containing a substantially inert gas under pressure;

a second tank for containing a preselected oxygen-releasing agent;

a pressure regulator interposed between said first tank and said second tank for providing pressure-regulated fluid communication between said first tank and said second tank; and

a multiplicity of groundwater injection points in fluid communication with said second tank and spaced apart within said groundwater within a delimited specific area of contamination at said selected ground site.

18. The self-regulated groundwater remediation system according to claim 17, wherein said substantially inert gas includes air.

19. The self-regulated groundwater remediation system according to claim 17, wherein said preselected oxygen-releasing agent is hydrogen peroxide.

20. The self-regulated groundwater remediation system according to claim 17, wherein said groundwater injection points have a spacing arrangement that is substantially horizontal and grid-like within said groundwater within said delimited specific area of contamination at said selected ground site.