Anti-fogging element and method for forming the same

• US 20030179476A1
• Filed: 02/06/2003
• Published: 09/25/2003
• Est. Priority Date: 06/11/2001
• Status: Abandoned Application

• Current Assignee: Murakami Corporation
• Original Assignee: Murakami Corporation
• Inventors: Kobayashi, Masaki, Kuzuya, Norihiko
• Application Number:
  US10/343,745
• Publication Number:
  US 20030179476A1
• Time in Patent Office: Days
• US Class Current: 359/883
• CPC Class Codes: A47G 1/02 Mirrors used as equipment hand, pocket, or shaving mirrors A45D42/00; optical viewing means for vehicles B60R1/00
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: C03C 17/3411 with at least two coatings of inorganic materials C03C17/36, C03C17/42 take precedence
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/425 consisting of a porous layer
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C09D 1/00 Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
• CPC Class Codes: G02B 1/18 Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films G02B1/16 takes precedence
• CPC Class Codes: G02B 27/0006 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation G02B1/18 takes precedence; cleaning in general B08B

Abstract

In an anti-fog element comprising a substrate, a photocatalyzer film formed on the surface of the substrate, and a porous hydrophilic film formed thereon, and a process for forming the same, a titanium peroxide solution obtainable by causing a titanium peroxide gel (orthotitanic acid) to act with hydrogen peroxide is used as a material for the photocatalyzer film. When the titanium peroxide solution is used to form a photocatalyzer film, an anatase type titanium dioxide film can be obtained at a low temperature, for example, of 200° C. Consequently, in the course of the fabrication of the anti-fog element, any alkaline substance is difficult to be dispersed into the photocatalyzer film and, thus, even if a soda lime glass is used as the substrate, no film for preventing the alkali dispersion is required. For this reason, no photocatalytic property is impaired even if no film for preventing the alkali dispersion is provided. Due to the treatment at a low temperature, it is difficult for the reflecting film to be oxidized, not impairing the reflecting ratio. What is more, the treatment at a low temperature saves energy and reduces the cost, leading decreased cost.

Claims

1. An anti-fog element comprising a substrate, a photocatalyzer film formed on the surface of the substrate, and a porous hydrophilic film formed thereon,

a titanium peroxide solution obtainable by causing a titanium peroxide gel (orthotitanic acid) to act with hydrogen peroxide being used as a material for the photocatalyzer film.

2. The anti-fog element as claimed in claim 1, wherein said photocatalyzer film is an anatase type titanium dioxide obtained by a heat treatment not less than 200°

C. and not greater than 400°

C.

3. The anti-fog element as claimed in claim 1 or 2, which has an intermediate film between the surface of said substrate and said photocatalyzer film.

4. The anti-fog element as claimed in any one of claims 1 to 3, wherein said hydrophilic substance film is a transparent inorganic oxide film.

5. The anti-fog element as claimed in any one of claims 1 to 4, which is transparent in its entirety and is configured as an automobile window.

6. The anti-fog element as claimed in any one of claims 1 to 5, wherein said substrate is transparent and which further comprises a reflecting film formed on the rear surface of the transparent substrate to form an anti-fog mirror.

7. The anti-fog element as claimed in any one of claims 1 to 6, which comprises a reflecting film formed on the rear surface of the substrate, a transparent photocatalyzer film catalyzing a photocatalytic reaction formed on the surface of the substrate, and a transparent hydrophilic substance film formed thereon in a porous state to form an anti-fog mirror having a hydrophilic surface.

8. The anti-fog element as claimed in claim 6 or 7, which is configured as an automobile outer mirror.

9. A process for forming an anti-fog element comprising a substrate, a photocatalyzer film formed on the surface of the substrate, and a porous hydrophilic film formed thereon,

using a titanium peroxide solution obtainable by causing a titanium peroxide gel (orthotitanic acid) to act with hydrogen peroxide as a material for the photocatalyzer film.

10. The process for forming an anti-fog element as claimed in claim 9, wherein said substrate is a soda lime glass, and after a reflecting film is formed on the front or rear surface of the substrate, said photocatalyzer film is formed, and thermally treated at a temperature not less than 200°

C. and not greater than 400°

C.