Method and apparatus for monitoring equivalent series resistance and for shunting a fuel cell

• US 20030203249A1
• Filed: 05/06/2003
• Published: 10/30/2003
• Est. Priority Date: 01/23/2002
• Status: Active Grant

• Current Assignee: Emergent Power Inc. (Plug Power Inc.)
• Original Assignee: Relion Incorporated (Plug Power Inc.)
• Inventors: Lott, David R., Bai, Lijun, Martin, Vanell L.
• Granted Patent: US 6,805,987 B2
• Time in Patent Office: Days
• US Class Current: 429/13
• CPC Class Codes: H01G 11/08 Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04589 of fuel cell stacks
• CPC Class Codes: H01M 8/04626 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/0488 of fuel cell stacks
• CPC Class Codes: H01M 8/0491 of fuel cell stacks
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell power system comprising a fuel cell having a cathode and an anode adapted to be coupled to a fuel supply, and which is configured to produce electrical power having a current and voltage output; a controller electrically coupled with the fuel cell, and configured to selectively short the anode to the cathode of the fuel cell; and circuitry configured to measure resistance of the fuel cell in timed relation to the shorting.

Claims

1. A fuel cell power system comprising:

a fuel cell having a cathode and an anode adapted to be coupled to a fuel supply, and which is configured to produce electrical power having a current and voltage output;

a controller electrically coupled with the fuel cell, and configured to selectively short the anode to the cathode of the fuel cell; and

circuitry configured to measure resistance of the fuel cell in timed relation to the shorting.

2. A fuel cell power system in accordance with claim 1 wherein the circuitry configured to measure resistance of the fuel cell comprises a voltage sensor and a current sensor which are disposed in sensing relation relative to the anode and cathode of the fuel cell, and wherein resistance is determined by dividing fuel cell voltage drop caused by shorting, measured by the voltage sensor, by fuel cell current increase caused by shorting, measured by the current sensor.

3. A fuel cell power system in accordance with claim 1 wherein the circuitry configured to measure resistance of the fuel cell comprises a voltage sensor and a current sensor which are disposed in sensing relation relative to the anode and cathode of the fuel cell to measure current generated by and voltage across the fuel cell, and wherein resistance of the fuel cell is determined by determining change in fuel cell voltage between during shorting and immediately after the short is removed, by determining change in fuel cell current between during shorting and immediately after the short is removed, and by dividing the determined voltage change by the determined current change.

4. A fuel cell power system as claimed in claim 1, and further comprising an electrical switch which has open and closed electrical conditions, wherein the controller selectively causes the electrical switch to move between the open and closed electrical conditions, wherein the fuel cell has performance parameters comprising current and voltage outputs, and wherein in the first condition, the voltage output of the fuel cell is less than the performance parameters;

and wherein in the second condition, the electrical switch periodically opens and closes during the duty cycle to cause a resulting increase in the electrical power output of the fuel cell.

5. A fuel cell power system as claimed in claim 1, and further comprising an electrical switch which has open and closed electrical conditions, wherein the controller selectively causes the electrical switch to move between the open and closed electrical conditions, wherein the fuel cell has performance parameters comprising current and voltage outputs, and wherein in the second condition the fuel cell has an operating and duty cycle, and wherein the operating and duty cycles are individually and selectively adjusted by the controller at least in part by reference to the performance parameters of the fuel cell.

6. A fuel cell power system as claimed in claim 1, and further comprising an electrical switch which has open and closed electrical conditions, wherein the controller selectively causes the electrical switch to move between the open and closed electrical conditions, wherein the fuel cell has performance parameters comprising current and voltage outputs, and wherein in the second condition the fuel cell has a duty cycle, and an operating cycle of about 0.01 seconds to about 4 minutes, and wherein the operating and duty cycles are individually and selectively adjusted by the controller at least in part by reference to the changing performance parameters of the fuel cell in relative comparison to the performance parameters of other fuel cells.

7. A fuel cell power system as claimed in claim 1, wherein the fuel cell is serially electrically coupled with another cell.

8. A fuel cell power system as claimed in claim 7, wherein the controller is electrically coupled with each of the fuel cells to short current between the anode and cathode of selected ones of the fuel cells.

9. A fuel cell power system as claimed in claim 8, wherein the fuel cell has a duty cycle and an operating cycle of 0.01 seconds to about 4 minutes, and wherein in the second condition, the controller which is coupled with each of the fuel cells periodically shunts current during the duty cycle between anode and cathode of each of the fuel cells to cause a resulting increased electrical power output from the serially electrically coupled fuel cells.

10. A fuel cell power system as claimed in claim 9, wherein in the second condition, the duty and operating cycles are individually selectively adjusted to optimize the electrical power output of the respective fuel cells;

and wherein the electrical power output of the serially electrically connected fuel cells increases by at least about 5 percent; and

wherein the duration of the shorting during the duty cycle is less than about 20% of the operating cycle.

11. A fuel cell power system as claimed in claim 10, and wherein the electrical switch comprises a field effect transistor, and wherein the controller which is operable to short the anode and cathode of each of the serially connected fuel cells further comprises passive by-pass electrical circuitry which operates upon failure of the field effect transistor to short between the anode and cathode of each of the fuel cells.

12. A fuel cell power system as claimed in claim 11, and wherein the passive by-pass electrical circuitry comprises a diode, and the controller is a digital controller.

13. A fuel cell power system as claimed in claim 1, wherein the controller is configured to, at times, initiate a shunting operation, the shunting operation comprising the shorting of the anode and cathode of the fuel cell.

14. A fuel cell power system comprising at least one fuel cell configured to supply power to a load, and circuitry configured to measure equivalent series resistance of at least one fuel cell of the power system while the power system continues to substantially serve the load.

15. A fuel cell power system in accordance with claim 14 wherein the fuel cell has a controllable operational parameter, and wherein the fuel cell power system includes circuitry configured to control the operational parameter in response to the determined equivalent series resistance.

16. A fuel cell power system in accordance with claim 14 and comprising a plurality of fuel cells, and configured such that at least one of the fuel cells is selectively decoupled from the load while other fuel cells continue to supply power to the load.

17. A fuel cell power system in accordance with claim 16 wherein the circuitry configured to measure equivalent series resistance does so in timed relation to decoupling of at least one of the fuel cells from the load.

18. A fuel cell power system in accordance with claim 17 and further comprising circuitry configured to selectively short circuit at least one of the fuel cells in timed relation to decoupling of at least one of the fuel cells from the load.

19. A fuel cell power system comprising:

a pair of output terminals;

a plurality of fuel cells respectively having an anode adapted to be coupled to a fuel supply, and a cathode, which fuel cells are selectively coupled to the output terminals, and which, in operation, convert chemical energy into electrical power having a current and voltage output, wherein one or more of the fuel cells are selectively decoupled from the output terminals while other fuel cells continue to provide power to the output terminals; and

circuitry configured to measure the equivalent series resistance of one of the decoupled fuel cells in situ while the other fuel cells continue to produce electrical power.

20. A fuel cell power system in accordance with claim 19 wherein the circuitry configured to measure the equivalent series resistance is circuitry other than AC measurement circuitry.

21. A fuel cell power system in accordance with claim 19 wherein the circuitry configured to measure resistance of the fuel cell comprises a voltage sensor and a current sensor which are disposed in sensing relation relative to the anode and cathode of the fuel cell to measure current generated by and voltage across the fuel cell, and wherein equivalent series resistance is determined by shorting the anode and cathode of one of the fuel cells, measuring fuel cell voltage and current changes between before and immediately after a short is applied, and dividing the voltage change by the current change.

22. A fuel cell power system in accordance with claim 19 wherein the circuitry configured to measure resistance of the fuel cell comprises a voltage sensor and a current sensor which are disposed in sensing relation relative to the anode and cathode of the fuel cell to measure current generated by and voltage across the fuel cell, and wherein equivalent series resistance is determined by shorting the anode and cathode of one of the fuel cells, measuring fuel cell voltage and current changes between during shorting and immediately after a short is removed, and dividing the voltage change by the current change.

23. A fuel cell power system comprising:

a fuel cell having a cathode and an anode adapted to be coupled to a fuel supply, and configured to produce electrical power having a current and voltage output;

a voltage sensor;

a current sensor; and

a controller electrically coupled with the fuel cell, the voltage sensor, and the current sensor, and configured to, at times, perform a shunting operation including shorting the anode to the cathode of the fuel cell according to a duty cycle, the controller further being configured to determine equivalent series resistance of the fuel cell based on fuel cell current and voltage changes during a shunting operation, determined using the current sensor and voltage sensor, and the controller being configured to selectively adjust the duty cycle in response to the determined equivalent series resistance.

24. A fuel cell power system in accordance with claim 23 wherein the controller is configured to change the frequency of shorting if equivalent series resistance exceeds a predetermined threshold.

25. A fuel cell power system in accordance with claim 23 wherein the controller is configured to change the duration of shorting if equivalent series resistance exceeds a predetermined threshold.

26. A fuel cell power system in accordance with claim 25 wherein the voltage sensor is configured to measure voltage across the fuel cell, wherein the current sensor is configured to measure current through the fuel cell, and wherein the controller determines equivalent series resistance by dividing a voltage value by a current value, the current value being selected in response to current measured by the current sensor, immediately after a shorting is initiated, the voltage value being selected in response to fuel cell voltage change measured by the voltage sensor, immediately after a shorting is initiated.

27. A fuel cell power system in accordance with claim 25 wherein the voltage sensor is configured to measure voltage across the fuel cell, wherein the current sensor is configured to measure current through the fuel cell, and wherein the controller determines equivalent series resistance by dividing a current value by a voltage value, the current value being selected in response to current measured by the current sensor immediately after a shorting is removed, the voltage value being selected in response to fuel cell voltage measured by the voltage sensor, immediately after a shorting is removed.

28. A fuel cell power system comprising at least one fuel cell configured to supply power to a load, and circuitry configured to determine hydration level of at least one fuel cell of the power system while the power system continues to substantially serve the load.

29. A fuel cell power system in accordance with claim 28 wherein the fuel cell has a controllable operational parameter, and wherein the fuel cell power system includes circuitry configured to control the operational parameter in response to the determined hydration level.

30. A fuel cell power system in accordance with claim 28 wherein the circuitry configured to determine hydration level of at least one fuel cell is configured to determine equivalent series resistance of the fuel cell, then determine hydration level based on the equivalent series resistance.

31. A fuel cell power system in accordance with claim 30 and comprising a plurality of fuel cells, and configured such that at least one of the fuel cells is selectively decoupled from the load while other fuel cells continue to supply power to the load.

32. A fuel cell power system in accordance with claim 31 wherein the circuitry configured to determine equivalent series resistance of the fuel cell does so in timed relation to decoupling of at least one of the fuel cells from the load, the fuel cell power system further comprising circuitry configured to selectively short circuit at least one of the fuel cells in timed relation to decoupling of at least one of the fuel cells from the load.

33. A fuel cell power method comprising:

providing a fuel cell having a cathode and an anode adapted to be coupled to a fuel supply, and configured to produce electrical power having a current and voltage output;

selectively shorting the anode of the fuel cell to the cathode of the fuel cell; and

measuring resistance of the fuel cell in timed relation to the shorting.

34. A fuel cell power method in accordance with claim 33 wherein measuring resistance of the fuel cell during shunting comprises determining fuel cell voltage drop caused by shorting, determining fuel cell current increase caused by shorting, and dividing fuel cell voltage drop by fuel cell current increase.

35. A fuel cell power method in accordance with claim 33 wherein measuring resistance of the fuel cell during shunting comprises determining fuel cell voltage and current changes between a time during and a time after shunting, and dividing fuel cell voltage change by fuel cell current change.

36. A fuel cell power method as claimed in claim 33 and further comprising using an electrical switch which has open and closed electrical conditions, and using a controller which causes the electrical switch to move between the open and closed electrical conditions to selectively short the anode to the cathode, wherein the fuel cell has performance parameters comprising current and voltage outputs, and wherein in the first condition, the voltage output of the fuel cell is less than the performance parameters;

and wherein in the second condition, the electrical switch periodically opens and closes during the duty cycle to cause a resulting increase in the electrical power output of the fuel cell.

37. A fuel cell power method as claimed in claim 33, and further comprising using an electrical switch which has open and closed electrical conditions, and using a controller which causes the electrical switch to move between the open and closed electrical conditions to selectively short the anode to the cathode, wherein the fuel cell has performance parameters comprising current and voltage outputs, and wherein in the second condition the fuel cell has an operating and duty cycle, and wherein the operating and duty cycles are individually and selectively adjusted by the controller at least in part by reference to the performance parameters of the fuel cell.

38. A fuel cell power method as claimed in claim 33, and further comprising using an electrical switch which has open and closed electrical conditions, and using a controller which causes the electrical switch to move between the open and closed electrical conditions to selectively short the anode to the cathode, wherein the fuel cell has performance parameters comprising current and voltage outputs, and wherein in the second condition the fuel cell has a duty cycle, and an operating cycle of about 0.01 seconds to about 4 minutes, and wherein the operating and duty cycles are individually and selectively adjusted by the controller at least in part by reference to the changing performance parameters of the fuel cell in relative comparison to the performance parameters of other fuel cells.

39. A fuel cell power method as claimed in claim 33, and further comprising serially electrically coupling the fuel cell with another cell.

40. A fuel cell power method as claimed in claim 39, and further comprising using a controller, electrically coupled with individual fuel cells, to shunt current between the anode and cathode of selected fuel cells.

41. A fuel cell power method as claimed in claim 40, wherein the fuel cell has a duty cycle and an operating cycle of 0.01 seconds to about 4 minutes, and wherein in the second condition, the controller which is coupled with each of the fuel cells periodically shorts during the duty cycle between the anode and cathode of respective fuel cells to cause a resulting increased electrical power output from the serially electrically coupled fuel cells.

42. A fuel cell power method as claimed in claim 41, wherein in the second condition, the duty and operating cycles are individually selectively adjusted to optimize the electrical power output of the respective fuel cells;

and wherein the electrical power output of the serially electrically connected fuel cells increases by at least about 5 percent; and

wherein the duration of the shunting during the duty cycle is less than about 20% of the operating cycle.

43. A fuel cell power method as claimed in claim 40, wherein the electrical switch comprises a field effect transistor, and wherein the controller which is operable to shunt current between the anode and cathode of each of the serially connected fuel cells further comprises passive by-pass electrical circuitry which operates upon failure of the field effect transistor to shunt current between the anode and cathode of each of the fuel cells.

44. A fuel cell power method as claimed in claim 43, and wherein the passive by-pass electrical circuitry comprises a diode, and the controller is a digital controller.

45. A fuel cell power system as claimed in claim 33, wherein the controller is configured to, at time, initiate a shunting operation, the shunting operation comprising the shorting of the anode and cathode of the fuel cell.

46. A fuel cell power method comprising supplying power to a load using at least one fuel cell, and measuring equivalent series resistance of at least one of the fuel cells while power is continued to be substantially supplied the load.

47. A fuel cell power method in accordance with claim 46 and further comprising selectively decoupling at least one of the fuel cells from the load while other fuel cells continue to supply power to the load.

48. A fuel cell power method in accordance with claim 46 wherein equivalent series resistance is measured in timed relation to decoupling of at least one of the fuel cells from the load.

49. A fuel cell power method in accordance with claim 46 and further comprising selectively short circuiting at least one of the fuel cells in timed relation to decoupling of at least one of the fuel cells from the load.

50. A fuel cell power method comprising:

providing a pair of output terminals;

providing a plurality of fuel cells respectively having an anode adapted to be coupled to a fuel supply, and a cathode, which fuel cells are selectively coupled to the output terminals, and which, in operation, convert chemical energy into electrical power having a current and voltage output, wherein one or more of the fuel cells are selectively decoupled from the output terminals while other fuel cells continue to provide power to the output terminals; and

measuring equivalent series resistance of one of the fuel cells, in situ, while the other fuel cells continue to produce electrical power.

51. A fuel cell power method in accordance with claim 0050, 50 wherein measuring equivalent series resistance comprises measuring equivalent series resistance using circuitry other than high frequency AC measurement circuitry.

52. A fuel cell power method in accordance with claim 0050, 50 wherein measuring equivalent series resistance of the fuel cell comprises providing a voltage sensor and a current sensor disposed in sensing relation relative to the anode and cathode of the fuel cell for which equivalent series resistance is being measured, and wherein equivalent series resistance is determined by shorting the anode and cathode of one of the fuel cells, measuring fuel cell voltage and current changes between before and immediately after a short is applied, and dividing the voltage change by the current change.

53. A fuel cell power method in accordance with claim 0050, 50 wherein measuring resistance of the fuel cell during shunting comprises providing a voltage sensor and a current sensor in sensing relation relative to the anode and cathode of the fuel cell to measure current generated by and voltage across the fuel cell, and wherein equivalent series resistance is determined by shorting the anode and cathode of one of the fuel cells, measuring fuel cell voltage and current changes between during shorting and immediately after a short is removed, and dividing the voltage change by the current change.

54. A fuel cell power method comprising:

providing a fuel cell having a cathode and an anode adapted to be coupled to a fuel supply, and configured to produce electrical power having a current and voltage output;

providing a voltage sensor;

providing a current sensor; and

at times, performing a shunting operation including shorting the anode to the cathode of the fuel cell according to a duty cycle, and determining equivalent series resistance of the fuel cell based on fuel cell current and voltage during a shunting operation, and using the current sensor and voltage sensor, and selectively adjusting the duty cycle in response to the determined equivalent series resistance.

55. A fuel cell power method in accordance with claim 54 and further comprising increasing frequency of shunting if equivalent series resistance exceeds a predetermined threshold.

56. A fuel cell power method in accordance with claim 54 and further comprising increasing duration of shunting if equivalent series resistance exceeds a predetermined threshold.

57. A fuel cell power method in accordance with claim 56 wherein the voltage sensor is configured to measure voltage across the fuel cell, and the current sensor is configured to measure current through the fuel cell, and wherein equivalent series resistance is determined by dividing a current value by a voltage value, the current value being selected in response to current measured by the current sensor, immediately after a shorting is initiated, the voltage value being selected in response to fuel cell voltage measured by the voltage sensor, immediately after a shorting is initiated.

58. A fuel cell power method system in accordance with claim 56 wherein the voltage sensor is configured to measure voltage across the fuel cell, wherein the current sensor is configured to measure current through the fuel cell, and wherein the controller determines equivalent series resistance by dividing a current value by a voltage value, the current value being selected in response to current measured by the current sensor immediately after a shorting is removed, the voltage value being selected in response to fuel cell voltage measured by the voltage sensor, immediately after a shorting is removed.

59. A method comprising:

providing a fuel cell power system including at least one fuel cell configured to supply power to a load; and

determining hydration level of at least one fuel cell of the power system while the power system continues to substantially serve the load.

60. A method in accordance with claim 59 wherein determining hydration level of at least one fuel cell comprises determining equivalent series resistance of the fuel cell, then determining hydration level based on the equivalent series resistance.

61. A method in accordance with claim 60 and comprising providing a plurality of fuel cells, and arranging the fuel cells such that at least one of the fuel cells is selectively decoupled from the load while other fuel cells continue to supply power to the load.

62. A method in accordance with claim 61 wherein the determining of equivalent series resistance of the fuel cell is performed in timed relation to decoupling of at least one of the fuel cells from the load, the method further comprising selectively short circuiting at least one of the fuel cells in timed relation to decoupling of at least one of the fuel cells from the load.

63. A method comprising:

providing a fuel cell having an anode and a cathode and having a level of hydration;

applying a short from the anode to the cathode for a predetermined amount of time;

removing the short;

measuring the amount of time for current to recover after the short between the anode and the cathode of the fuel cell is removed; and

determining what the level of hydration of the fuel cell was prior to the shorting, in response to the measured amount of time.