Multi component controlled delivery system for fabric care products

• US 20030203829A1
• Filed: 04/26/2002
• Published: 10/30/2003
• Est. Priority Date: 04/26/2002
• Status: Active Grant

• Current Assignee: Salvona IP LLC
• Original Assignee: Adi Shefer, Samuel David Shefer
• Inventors: Shefer, Adi, Shefer, Samuel David
• Granted Patent: US 6,740,631 B2
• Time in Patent Office: Days
• US Class Current: 510/327
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 3/505 encapsulated or adsorbed on a carrier, e.g. zeolite or clay
• CPC Class Codes: C11D 9/00 Compositions of detergents based essentially on soap compositions containing resin soap C11D15/04
• CPC Class Codes: C11D 9/26 containing oxygen C11D9/225 takes precedence
• CPC Class Codes: C11D 9/36 containing silicon C11D9/225 takes precedence

Abstract

The present invention relates to an improved controlled delivery system that can be incorporated in dry granular, or powder, fabric care products, such as laundry detergents, tumble dryer sheets, rinse added products, and other fabric care products, to enhance fragrance performance. The controlled delivery system of the present invention comprises substantially free-flowing, powder formed of solid hydrophobic, positively charged, nano-spheres of encapsulated active ingredients, such as a fragrance, that are encapsulated in a moisture sensitive micro-spheres, solid spheres. The high cationic charge density of the nano-sphere improves fragrance deposition onto the laundered fabric. The high cationic charge density on the nano-sphere surface is created by incorporating a cationic fabric conditioning agent into the solid hydrophobic matrix of the nano-spheres, by incorporating a cationic charge “booster” in the water sensitive micro-sphere matrix, or by using a cationic fabric conditioning agent in the nano-sphere matrix in conjunction with a cationic charge “booster” in the micro-sphere matrix. The fragrance carrier system also provides controlled release or prolonged fragrance release from the dry laundered fabric over an extended period of time, or yields a high impact fragrance “burst” upon ironing the fabric. The invention also pertains to fabric care products comprising the controlled release system of the present invention.

Claims

1. A multi component moisture activated composition comprising:

a plurality of solid nanoparticles, each of said solid nano particles comprising an effective amount of a first active agent, said solid nano particles are formed of a hydrophobic material said plurality of nano-particles being encapsulated in a moisture sensitive microparticle, said moisture sensitive microparticle is formed of a moisture sensitive matrix material, wherein said solid nano-particles are positively charged.

2. The composition of claim 1 wherein said nano-particles further comprise a cationic fabric conditioning agent.

3. The composition of claim 2 wherein said cationic fabric conditioning agent is quaternary ammonium salt or cationic imidazolinium.

4. The composition of claim 2 wherein said cationic fabric conditioning agent is a dialkyl dimethyl ammonium chloride or alkyl trimethyl ammonium compound wherein the alkyl has from 12 to 20 atoms.

5. The composition of claim 2 wherein said cationic fabric conditioning agent is selected from the group consisting of:

behenyltrimethylammonium chloride;

ditallowdimethylammonium methylsulfate;

ditallowdimethylammonium chloride;

methyl(1)stearylamidoethyl(2)stearylimidazolinium methosulfate;

methyl(1)stearylamidoethyl(2)stearylimidazolinium chloride;

N,N-di(tallowyl-oxy-ethyl)-N,N-dimethyl ammonium chloride;

N,N-di(canolyl-oxy-ethyl)-N,N-dimethyl ammonium chloride;

N,N-di(tallowyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium chloride;

N,N-di(canolyl-oxy-ethyl)-N-methyl, N-(2-hydroxyethyl) ammonium chloride;

N,N-di(2-tallowyloxy-2-oxo-ethyl)-N,N-dimethyl ammonium chloride;

N,N-di(2-canolyloxy-2-oxo-ethyl)-N,N-dimethyl ammonium chloride;

N,N-di(2-tallowyloxyethylcarbonyloxyethyl)-N,N-dimethyl ammonium chloride;

N,N-di(2-canolyloxyethylcarbonyloxyethyl)-N,N-dimethyl ammonium chloride;

N-(2-tallowoyloxy-2-ethyl)-N-(2-tallowyloxy-2-oxo-ethyl)-N,N-dimethyl ammonium chloride;

N-(2-canolyloxy-2-ethyl)-N-(2-canolyloxy-2-oxo-ethyl)-N,N-dimethyl ammonium chloride;

N,N,N-tri(tallowyl-oxy-ethyl)-N-methyl ammonium chloride;

N,N,N-tricanolyl-oxy-ethyl)-N-methyl ammonium chloride;

N-(2-tallowyloxy-2-oxoethyl)-N-(tallowyl)-N,N-dimethyl ammonium chloride;

N-(2-canolyloxy-2-oxoethyl)-N-(canolyl)-N,N-dimethyl ammonium chloride;

1,2-ditallowyloxy-3-N,N,N-trimethylammoniopropane chloride; and

1,2-dicanolyloxy-3-N,N,N-trimethylammoniopropane chloride; and

mixtures of thereof.

6. The composition of claim 2 wherein said cationic fabric conditioning agent comprises methyl bis(hydrogenated ditallowamidoethyl)2hydroxyethyl ammonium chloride.

7. The composition of claim 2 wherein said cationic fabric conditioning agent comprises methyl bis(hydrogenated tallow amidoethyl)-2-hydroxyethyl ammonium methyl sulfate.

8. The composition of claim 2 wherein said cationic fabric conditioning agent comprises methyl(1)hydrogenated tallow amidoethyl(2)hydrogenated tallow imidazolinium methyl sulfate.

9. The composition of claim 2 wherein said cationic fabric conditioning agent comprises behenyltrimethylammonium chloride.

10. The composition of claim 1 wherein said micro-spheres further comprise a cationic charge booster selected from the group consisting of a quaternary ammonium compound, polyvinyl amine, polyalkyleneimine, and a poly-quaternary ammonium compound.

11. The composition of claim 10 wherein said cationic charge booster comprises polyethyleneimine, having an average molecular weight of 1,800.

12. The composition of claim 10 wherein said cationic charge booster comprises polyethyleneimine, having an average molecular weight of 1,800.

13. The composition of claim 2 wherein said micro-spheres further comprise a cationic charge booster selected from the group consisting of a quaternary ammonium compound, polyvinyl amine, polyalkyleneimine, and a poly-quaternary ammonium compound.

14. The composition of claim 13 wherein said nano-spheres release said cationic fabric conditioning agent over an extended period of time.

15. The composition of claim 14 wherein said extended period of time is up to about 3 weeks.

16. The composition of claim 13 wherein said micro-spheres release an effective amount of said cationic charge booster and said nano-spheres release an effective amount of said cationic fabric conditioning agent to provide a burst upon heat treatment of said sphere.

17. The composition of claim 1 wherein said first active agent is selected from one or more of the agents of the group consisting of a fragrance, ironing aid, silicones, anti-shrinkage agent, anti-wrinkle agent, fabric crisping agent, bleaching agent, spotting agent, germicide, fungicide, stabilizer, preservative, bactericide, flow agent, and mixtures thereof.

18. The composition of claim 17 wherein said first active agent comprises a fragrance.

19. The composition of claim 1 further comprising a second active agent encapsulated in said moisture sensitive matrix wherein said matrix releases said second active agent upon contact with said moisture and continuously thereafter for an extended period of time.

20. The composition of claim 19 wherein said second active agent is selected from one or more of the agents of the group consisting of a fragrance, ironing aid, silicones, anti-shrinkage agent, anti-wrinkle agent, fabric crisping agent, spotting agent, bleaching agent, germicide, fungicide, stabilizer, preservative, bactericide, flow agent, and mixtures thereof.

21. The composition of claim 20 wherein said second active agent is a fragrance

22. The composition of claim 1 wherein said moisture sensitive matrix material is selected from the group consisting of a water soluble synthetic polymer, water dispersible synthetic polymers, a starch derivative, natural gum, polyvinyl alcohol, polysaccharide, protein, hydrocolloid, and mixtures thereof.

23. The composition of claim 22 wherein said hydrocolloid is selected from the group consisting of xanthan, maltodextrin, galactomanan, and tragacanth.

24. The composition of claim 22 wherein said natural gum is gum arabic.

25. The composition of claim 22 wherein said polyvinyl alcohol is present in an amount by weight of about 1% to about 70% by weight of said particle.

26. The composition of claim 25 wherein said polyvinyl alcohol is present in an amount by weight of about 70% to about 80% of said particle.

27. The composition of claim 22 wherein said polyvinyl alcohol has a degree of hydrolysis from about 75% to about 99%.

28. The composition of claim 22 wherein said starch derivative is present in an amount by weight of about 1% to about 70% by weight of said micro-sphere.

29. The composition of claim 22 wherein said starch derivative is present in an amount by weight of about 30% to about 40% of said sphere and said polyvinyl alcohol is present in an amount by weight of about 30% to about 40% of said sphere.

30. The composition of claim 1 wherein said hydrophobic material is selected from the group consisting of natural waxes and synthetic waxes, natural wax and silicon copolymers, synthetic wax and silicon copolymer, fatty acid esters, fatty alcohols, solid hydrogenated plant oils, natural polymers and synthetic polymers.

31. The composition of claim 1 wherein said hydrophobic material comprises candelilla wax.

32. The composition of claim 1 wherein said hydrophobic material comprises candelilla wax and silicon copolymer.

33. The composition of claim 1 wherein said first active agent comprises about 1% to about 50% by weight of a fragrance.

34. The composition of claim 23 further comprising about 1% to about 10% of an active agent selected from the group consisting of fragrances, ironing aids, silicones, anti-shrinkage agents, anti-wrinkle agents, fabric crisping agents, bleaching agent, spotting agents, germicides, fungicides, stabilizers, preservatives, bactericides, flow agents, and mixtures thereof.

35. A method for producing the composition of claim 13 comprising the steps of:

(i) incorporating the first active agent and said cationic fabric conditioning agent into said nano-spheres;

(ii) forming an aqueous mixture comprising said nano-spheres, said second active agent, and said cationic charge booster and said moisture sensitive material; and

(iii) spray drying said mixture to form a dry powder composition.

36. A method for producing the composition of claim 13 comprising the steps of:

(i) heating a hydrophobic material for forming said nano-spheres to a temperature above a melting point of said hydrophobic material to form a melt;

(ii) dissolving or dispersing the cationic fabric conditioning agent into said melt;

(iii) dissolving or dispersing a fragrance and said first active agent into said melt;

(iv) dispersing said second active agent, said cationic charge booster, and said moisture sensitive matrix material in the aqueous phase;

(v) heating the dispersion to above the melting temperature of said hydrophobic material to form a hot melt;

(vi) mixing said hot melt with the aqueous phase to form a dispersion;

(vii) homogenizing the dispersion at a temperature above the melting temperature until a homogeneous fine dispersion is obtained having a particle size of from about 1 micron to about 2 microns;

(viii) cooling the homogenized dispersion to ambient temperature to form a suspension; and

(ix) spray drying the emulsified mixed suspension to form a dry powder composition.

38. A method for providing fragrance control release over an extended period of time in a fabric care product comprising the step of providing a moisture activated composition, said composition comprising the composition of claim 1.

39. A fabric care product comprising said composition of claim 1.

40. The fabric care product of claim 36 wherein said fabric care product is selected from the group consisting of:

a fabric softener;

tumble dryer sheets, powder laundry detergent;

rinse added product;

drier-added fabric softener product; and

ironing added product.

37. A method for providing fragrance control release over an extended period of time in a fabric care product comprising the step of providing a moisture activated composition, comprising a fragrance incorporated into a hydrophobic positively charged nano-particle and encapsulated in a moisture sensitive matrix material.