Coatings for food service articles

• US 20030207038A1
• Filed: 04/30/2003
• Published: 11/06/2003
• Est. Priority Date: 05/03/2002
• Status: Abandoned Application

• Current Assignee: National Starch and Chemical Investment Holding Corporation (Ingredion Incorporated)
• Original Assignee: National Starch and Chemical Investment Holding Corporation (Ingredion Incorporated)
• Inventors: Mackewicz, Victor L., Han, Inkwan, Billmers, Robert L.
• Application Number:
  US10/427,067
• Publication Number:
  US 20030207038A1
• Time in Patent Office: Days
• US Class Current: 427/384
• CPC Class Codes: C09D 103/04 Starch derivatives
• CPC Class Codes: C09D 103/06 Esters

Abstract

Coating type compositions and methods for preparing and using the coating composition, as well as food service articles manufactured with the coating. The coating provides a water and oil resistant barrier when applied to the food service article, and is biodegradable.

Claims

1. A composition useful in coating food service articles, the coating composition comprising:

at least one starch able to be used in food contact applications; and

at least one insolubilizer for adding water resistance to the coating composition.

7. The composition according to claim 1 further comprising at least one plasticizer.

8. The composition according to claim 7 wherein the at least one plasticizer is selected from the group consisting of polyvinyl alcohol, glycerol, sorbital and combinations thereof.

9. The composition according to claim 7 wherein the at least one plasticizer is a blend of polyvinyl alcohol and glycerol.

10. The composition according to claim 1 wherein the at least one insolubilizer is selected from the group consisting of derivatives of epichlorohydrin, derivatives of glyoxal, ammonium zirconium carbonate, potassium zirconium carbonate and sodium trimetaphosphate.

11. The composition according to claim 10 wherein the at least one insolubilizer is an epichlorohydrin-modified acrylamide.

12. The composition according to claim 1 further comprising a film enhancer.

13. The composition according to claim 12 wherein the film enhancer is styrene maleic anhydride.

18. The composition according to claim 1 wherein the composition is biodegradable.

19. Food service articles coated with the coating composition of claim 1 having a surface oil resistance of less than about 10.5%.

20. Food service articles coated with the coating composition of claim 1 having a water absorption value of less than about 10 mg/cm².

31. The method according to claim 20 further comprising the step of curing the coated food service article and coating the food service article with an aqueous solution of a film enhancer.

2. The composition according to claim I wherein the at least one starch is comprised of a chemically modified starch.

3. The composition according to claim 2 wherein the chemically modified starch is comprised of an alkenyl succinate starch derivative.

4. The composition according to claim 3 wherein the alkenyl succinate starch derivative is comprised of a starch derivative substituted with octenyl succinic anhydride.

5. The composition according to claim 3 wherein the alkenyl succinate starch derivative is a converted starch.

6. The composition according to claim 5 wherein the alkenyl starch derivative is in an amount of between about 10 and about 50 high molecular weight percent when used at a total concentration of about 20% solids content.

14. The composition according to claim I further comprising a wax.

15. The composition according to claim 14 further comprising between about 5% and about 25% wax and plasticizer based on the percentage weight of starch.

16. The composition according to claim 14 wherein the wax is selected from the group consisting of paraffin wax, carnauba wax, candelilla wax, microcrystalline wax, petroleum alicyclic hydrocarbon resins, triglyceride esters, and alkyl or alkenyl esters of fatty acids and alcohols and synthetic waxes.

17. The composition according to claim 14 wherein the wax is carnauba wax.

21. A method of preparing a coating for use on food service articles, the method comprising the steps of:

preparing a dispersion of at least one starch and at least one insolubilizer; and

adjusting the pH of the dispersion to between about 5.0 and about 11.0;

wherein the dispersion is useful for coating food service articles.

22. The method according to claim 21 further comprising the step of adding a wax to the dispersion.

23. The method according to claim 21 wherein the starch is a granular starch, further comprising the step of cooking an aqueous media of the granular starch under conditions sufficient to fully disperse the starch.

24. The method according to claim 23 further comprising the step of adding at least one plasticizer before cooking the starch media.

25. The method according to claim 23 further comprising the step of adding a wax to the media before cooking the starch media.

26. The method according to claim 25 wherein the wax and at least one plasticizer are added in an amount of between about 5% and about 25% based on the percentage weight of starch.

27. The method according to claim 21 further comprising the step of adding an insolubilizer to the dispersion.

28. The method according to claim 21 further comprising the step of adding a film enhancer to the dispersion.

29. The method according to claim 21 further comprising the step of coating a food service article with the starch and insolubilizer-containing coating.

30. The method according to claim 29 further comprising the step of coating the food service article with an aqueous solution of an insolubilizer.

32. The method according to claim 29 further comprising the step of curing the coating food service article at about 100°

to about 120°

C. for about one minute to about twenty-four hours.