Encoding methods using up-converting phosphors for high-throughput screening of catalysts
First Claim
1. A method for polymerization, comprising the steps of:
- combining a monomer with at least one labeled catalyst particle, wherein said labeled catalyst particle comprises at least one up-converting phosphor label and a catalyst, wherein said up-converting phosphor label identifies said catalyst, and comprises at least one rare earth ion and at least one phosphor host material; and
polymerizing said monomer to form a polymer bead surrounding said labeled catalyst particle.
0 Assignments
0 Petitions
Accused Products
Abstract
This invention relates to encoding methods using up-converting phosphors for high-throughput screening of catalysts. In particular, the invention relates to polymerization catalysts. In one embodiment of the invention, a monomer is combined with at least one labeled catalyst particle. The labeled catalyst particle comprises an up-converting phosphor label and a catalyst. The up-converting phosphor label identifies a particular catalyst. The monomer is polymerized to form a polymer bead surrounding the labeled catalyst particle. According to the invention, it is possible to combine two or more labeled catalyst particles in a commercially relevant large scale reactor to obtain direct comparison of different catalysts, and to avoid reactor effects that may occur when performed on the microscale. After the reaction, the resulting polymer beads are sorted, based on their size and/or phosphor labels. The polymer beads may also be further characterized to determine various physical and chemical properties of the resultant polymer.
-
Citations
25 Claims
-
1. A method for polymerization, comprising the steps of:
-
combining a monomer with at least one labeled catalyst particle, wherein said labeled catalyst particle comprises at least one up-converting phosphor label and a catalyst, wherein said up-converting phosphor label identifies said catalyst, and comprises at least one rare earth ion and at least one phosphor host material; and
polymerizing said monomer to form a polymer bead surrounding said labeled catalyst particle. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15)
-
-
16. A method for screening a library of catalysts, comprising the steps of:
-
combining a monomer with at least two labeled catalyst particles, wherein each labeled catalyst particle comprises an up-converting phosphor label and a catalyst, wherein said up-converting phosphor label identifies a particular catalyst, and comprises at least one rare earth ion and at least one phosphor host material;
polymerizing said monomer to form a polymer bead surrounding said labeled catalyst particle; and
sorting at least two of said polymer beads. - View Dependent Claims (17, 18, 19)
-
-
20. A method for screening a solid support material for a supported catalyst, comprising the steps of:
-
combining a monomer with at least one labeled catalyst particle, wherein said labeled catalyst particle comprises an up-converting phosphor label and a catalyst, wherein said up-converting phosphor label identifies a particular support material, and comprises at least one rare earth ion and at least one phosphor host material; and
polymerizing said monomer to form a polymer bead surrounding said labeled catalyst particle.
-
- 21. A composition comprising a labeled catalyst particle which comprises an up-converting phosphor label and a catalyst, wherein said up-converting phosphor label comprises at least one rare earth ion and at least one phosphor host material.
Specification