Water-based coating composition

• US 20030211346A1
• Filed: 09/25/2001
• Published: 11/13/2003
• Est. Priority Date: 11/22/1999
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Kausch, William L.
• Granted Patent: US 6,893,731 B2
• Time in Patent Office: Days
• US Class Current: 428/483
• CPC Class Codes: C08F 265/04 on to polymers of esters
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence
• CPC Class Codes: Y10T 428/259 Silicic material
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31794 Of cross-linked polyester
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

This invention provides a water-based composition suitable for use on polyester-based substrates for increasing adhesion between the substrate and a topcoat or overcoat. The composition comprises: (1) a latex polymer formed from the polymerization of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates and at least one monomer which imparts to the polymer the ability to be crosslinked; (2) a water soluble or water dispersible polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins and combinations thereof; and (3) a crosslinking agent.

Claims

1. A water-based composition suitable for coating a polyester-based substrate, the composition comprising:

(a) a first polymer comprising a latex polymer formed from the polymerization of

at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates;

and at least one monomer which imparts to the first polymer the ability to be crosslinked.

(b) a water-soluble or water-dispersible second polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins, and combinations thereof; and

(c) a crosslinking agent.

2. The composition of claim 1, wherein the latex polymer is a core-shell latex polymer.

3. The composition of claim 1, wherein the monomer which imparts to the first polymer the ability to be crosslinked has a hydroxyl group or an epoxy group.

4. The composition of claim 1, wherein the crosslinking agent is a melamine crosslinking agent.

5. The composition of claim 1, further comprising a surfactant.

6. The composition of claim 2, wherein the core has a lower Tg than the shell

7. The composition of claim 2, wherein:

(1) the core is formed from (i) about 60 to 95 parts by weight of at least one α

, β

-ethylenically unsaturated monomer having from about 1 to 12 carbon atoms;

(ii) 0 to about 35 parts by weight of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates; and

(iii) at least 5 parts by weight of a polar monomer, based on a total weight of the core; and

(2) the shell formed from (i) about 35 to 95 parts by weight of at least one α

, β

-ethylenically unsaturated monomer having from about 1 to about 12 carbon atoms;

(ii) 0 to about 60 parts by weight of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates; and

(iii) at least 5 parts by weight of a polar monomer, based on the total weight of the shell.

8. The composition of claim 1, wherein the first polymer is present at from about 1 to 8 percent solids by weight.

9. The composition of claim 1, wherein the second polymer is present at from about 2 to 16 percent solids by weight.

10. The composition of claim 1, wherein the crosslinking agent is present at from about 0.2 to 20 percent solids by weight.

11. The composition of claim 5, wherein the surfactant is present at from about 0.05 to 0.2 percent solids by weight.

12. The composition of claim 7, wherein the α

, β

-ethylenically unsaturated monomer is selected from the group consisting of methyl acrylate, ethyl acrylate, methyl methacrylate, isobutyl methacrylate, isodecyl methacrylate, cyclohexyl methacrylate, n-butyl acrylate, styrene, vinyl esters, and combinations thereof.

13. The composition of claim 7, wherein the monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates is selected from the group consisting of dicyclopentenyl (meth)acrylate, norbornyl (meth)acrylate, isobomyl (meth)acrylate, and combinations thereof.

14. The composition of claim 7, wherein the polar monomer is selected from the group consisting of (meth)acrylic acid, hydroxyalkyl (meth)acrylates;

N-alkylacrylamide;

N,N-dialkyl amino alkyl (meth)acrylate;

monoalkyl amino alkyl (meth)acrylate, the cationic salt of N,N-dialkyl amino alkyl (meth)acrylate, and N-alkyl amino alkyl (meth)acrylate, wherein all of the alkyl groups containing up to about 12 carbon atoms, and combinations thereof.

15. The composition of claim 1, wherein the crosslinking agent comprises at least one component selected from the group consisting of epoxy resins, alkyd resins, alkyl melamines, aryl melamines, benzo guanamines, guanamines, alkyl guanamines, aryl guanamines with an aldehyde, and combinations thereof.

16. The composition of claim 1, wherein the crosslinking agent is methylated melamine formaldehyde resin.

17. The composition of claim 5, wherein the surfactant is octyl polyethyoxy ethanol.

18. The composition of claim 1 further comprising from about 0.0001 to 10 percent solids by weight of a slip agent having an average particle size from about 0.1 micrometer to 10 micrometer.

19. The composition of claim 1 further comprising from about 0.005 to 1.0 percent solids by weight of a catalyst selected from the group consisting of para-toluene sulfonic acid and maleic acid.

20. The composition of claim 4 wherein the melamine crosslinking agent is present at from about 0.1 to 2 percent solids by weight.

29. A method of making a primed biaxially oriented polyester film, the method comprising the steps of:

(a) providing a uniaxially oriented polyester film having a major surface, the film being stretched in machine direction;

(b) coating the composition of claim 1 onto the major surface of the uniaxially oriented film;

(c) partially drying the coating composition; and

(d) stretching the uniaxially oriented film in a transverse direction.

30. The method of claim 29, wherein the biaxially oriented film is polyethylene terephthalate.

31. A method of making a primed biaxially oriented film, the method comprising the steps of:

(a) providing a biaxially oriented polyester film having a major surface;

(b) treating at least a portion of the major surface of the film with a surface treatment;

(c) coating the composition of claim 1 onto at least a portion the major surface of the biaxially oriented film; and

(d) drying the coating composition.

32. The method of claim 31, wherein the surface treatment is selected from the group consisting of nitrogen corona and air corona treatment.

33. The method of claim 32, wherein the corona treatment is about 0.2 millijoules per square meter.

21. A primed film construction, comprising a polyester-based substrate layer and a primer coating layer, the coating layer comprising:

(a) a crosslinked first polymer formed from the polymerization of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates; and

(b) a second polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins, and combinations thereof.

22. The film of claim 21, wherein the substrate is selected from the group consisting of polyethylene terephthalate, oriented polyethylene terephthalate, polyethylene naphthalate, oriented polyethylene naphthalate, and copolymers of polyethylene terephthalate and polyethylene naphthalate.

23. The film of claim 21, wherein the coating layer is light transmissible.

24. An article comprising a polyester-based substrate layer, an acrylate-based overcoat, and a primer layer disposed between the substrate layer and overcoat, the primer layer comprising:

(a) a crosslinked first polymer comprising at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates; and

(b) a second polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins, and combinations thereof.

25. The article of claim 24 wherein said acrylate-based overcoat is formed from a mixture of monomers comprising halogenated acrylate monomers.

28. The article of claim 24, wherein the adhesion between the substrate, the primer layer, and the overcoat has a value of between 4 to 5 as measured under ASTM D 3359-95a, Test Method B.

26. An article comprising a polyester-based substrate layer, a hard coat and a primer layer disposed between the substrate layer and the hard coat, the primer layer comprising

(a) a crosslinked first polymer comprising at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates;

and

(b) a second polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins, and combinations thereof.

27. The article of claim 26 wherein the hardcoat is formed from a composition comprising colloidal silicon dioxide particles dispersed in ethylenically unsaturated aliphatic and/or cycloaliphatic monomers that are substituted by a protic group.