Electrical connectors incorporating low friction coatings and methods for making them

• US 20030219622A1
• Filed: 04/22/2003
• Published: 11/27/2003
• Est. Priority Date: 04/22/2002
• Status: Active Grant

• Current Assignee: Yazaki Corporation
• Original Assignee: Yazaki Corporation
• Inventors: Niebauer, Daniel A.
• Granted Patent: US 6,923,692 B2
• Time in Patent Office: Days
• US Class Current: 428/663
• CPC Class Codes: B32B 15/01 all layers being exclusively metallic making layered metal workpieces by pressure cladding B23K20/22; making coatings with a metallic material characterised by its composition C23C30/00
• CPC Class Codes: C23C 14/0623 Sulfides, selenides or tellurides
• CPC Class Codes: H01R 13/03 characterised by the material, e.g. plating, or coating materials
• CPC Class Codes: Y10S 428/929 Electrical contact feature
• CPC Class Codes: Y10T 29/49204 Contact or terminal manufacturing
• CPC Class Codes: Y10T 428/12493 Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
• CPC Class Codes: Y10T 428/12708 Sn-base component
• CPC Class Codes: Y10T 428/12715 Next to Group IB metal-base component
• CPC Class Codes: Y10T 428/12722 Next to Group VIII metal-base component
• CPC Class Codes: Y10T 428/12826 Group VIB metal-base component
• CPC Class Codes: Y10T 428/1291 Next to Co-, Cu-, or Ni-base component

Abstract

Electrical connectors incorporate a composite coating of molybdenum disulfide and a metal, preferably tin, for one or both of the contact surfaces of the electrical connector. The coating provides for a low coefficient of friction, low contact resistance, and good electrical conductivity, as well as good mechanical properties. The coating also reduces the insertion force of the electrical connectors, thereby increasing the number of possible terminal pairs and/or reducing terminal bending and breakage for a manually mated connector. The coating can be deposited on copper, tin-plated copper, tin alloy-plated copper or other metallic substrates, using any of several physical vapor deposition methods.

Claims

1. An electrical connector comprising a male terminal and a female terminal, the male and female terminals each comprising a substrate material, wherein:

the male and female terminals each comprise contact surfaces, and at least a portion of the contact surfaces of the female terminal or the male terminal are coated by a solid thin film comprising a MoS_x-metal composite material, wherein “

x”

is the atomic ratio of sulfur to molybdenum in the MoS_x-metal composite material.

2. An electrical connector as defined in claim 1, wherein at least a portion of the contact surfaces of the male terminal is coated by the solid thin film.

3. An electrical connector as defined in claim 1, wherein the substrate material is selected from the group consisting of copper, copper alloy, tin-plated copper, tin plated copper alloy, tin alloy-plated copper, tin alloy-plated copper alloy, tin-plated brass, nickel-plated copper, nickel-plated copper alloy, nickel-plated brass, brass, silver, nickel, iron-nickel alloy, and silver-nickel alloy.

4. An electrical connector as defined in claim 3 wherein the substrate material is selected from the group consisting of copper, copper alloy, tin-plated copper, and tin-plated copper alloy.

5. An electrical connector as defined in claim 1, wherein the substrate material is in the form of a strip, and the male terminal or female terminal is prepared using forming or stamping of the substrate material.

6. An electrical connector as defined in claim 1, wherein x has a value from about 1.0 to about 2.0.

7. An electrical connector as defined in claim 1, wherein the MoS_x-metal composite material contains a metal selected from the group consisting of tin, titanium, zirconium, chromium, cobalt, nickel, tungsten, tantalum, niobium, hafnium, and alloys thereof.

8. An electrical connector as defined in claim 7, wherein the metal is tin.

9. An electrical connector as defined in claim 7, wherein the solid thin film comprises between about 2 weight percent and about 20 weight percent metal.

10. An electrical connector as defined in claim 9, wherein the solid thin film comprises between about 2 weight percent and about 14 weight percent metal.

11. An electrical connector as defined in claim 1, wherein the thickness of the solid thin film is between about 0.05 μ

m and about 2.0 μ

m.

12. An electrical connector as defined in claim 11, wherein the thickness of the solid thin film is between about 0.1 μ

m and about 1.0 μ

m.

13. An electrical connector as defined in claim 1, wherein the at least a portion of the contact surfaces of the female terminal or the male terminal are further coated by a thin intermediate metal layer deposited between the contact surfaces and the solid thin film of the MoS_x-metal composite.

14. An electrical connector as defined in claim 13, wherein the thin intermediate metal layer comprises a metal selected from the group consisting of titanium, chromium, and zirconium.

15. An electrical connector as defined in claim 14, wherein the thin intermediate metal layer comprises titanium or chromium.

16. An electrical connector as defined in claim 13, wherein the thin intermediate metal layer has a thickness between about 0.005 μ

m and about 0.2 μ

m.

17. An electrical connector as defined in claim 1, wherein the solid thin film has a coefficient of friction of less than about 0.2 at a normal load of about 5 Newtons.

18. An electrical connector as defined in claim 17, wherein the solid thin film has a coefficient of friction of less than about 0.1 at a normal load of about 5 Newtons.

19. An electrical connector as defined in claim 18, wherein the solid thin film has a coefficient of friction of less than about 0.08 at a normal load of about 5 Newtons.

20. An electrical connector as defined in claim 1, wherein the solid thin film has a contact resistance of less than about 20 milliohms at a normal load of about 5 Newtons.

21. An electrical connector as defined in claim 20, wherein the solid thin film has a contact resistance of less than about 10 milliohms at a normal load of about 5 Newtons.

22. An electrical connector as defined in claim 21, wherein the solid thin film has a contact resistance of less than about 8 milliohms at a normal load of about 5 Newtons.

23. A method for making an electrical connector comprising a male terminal and a female terminal, the male and female terminals each comprising a substrate material and contact surfaces, wherein at least a portion of the contact surfaces of the female terminal or the male terminal are coated by a solid thin film comprising a MoS_x-metal composite material, wherein “

x”

is the atomic ratio of sulfur to molybdenum in the MoS_x-metal composite material, the method comprising;

pre-cleaning the substrate material;

placing the substrate material in a vacuum deposition chamber having a refrigerated trap;

evacuating the vacuum deposition chamber to a pressure less than about 7.5×

10<sup>−

4</sup> millitorr;

cooling the refrigerated trap to a temperature less than 150 Kelvin; and

coating the substrate material with the MoS_x-metal composite material to form a solid thin film having a predetermined thickness.

24. A method as defined in claim 23, wherein the vacuum deposition chamber comprises at least one sputter deposition source.

25. A method as defined in claim 24, wherein the vacuum deposition chamber is equipped to provide for continuous motion of the substrate material relative to the at least one sputter deposition source.

26. A method as defined in claim 23, wherein the step of coating comprises using a physical vapor deposition process to coat the substrate material with the MoS_x-metal composite material.

27. A method as defined in claim 26, wherein the step of coating comprises sputtering from at least one target to coat the substrate material with the MoS_x-metal composite material.

28. A method as defined in claim 27, wherein the step of depositing comprises using a balanced planar magnetron to coat the substrate material with the MoS_x-metal composite material.

29. A method as defined in claim 27, wherein the step of depositing comprises powering the sputter deposition source in the chamber by direct current, mid-frequency alternating current, alternating current, pulsed current, radio frequency, or microwave energy.

30. A method as defined in claim 29, wherein the step of powering comprises powering by direct current or mid-frequency alternating current.

31. A method as defined in claim 30, wherein the step of powering comprises powering by direct current.

32. A method as defined in claim 27, wherein the step of coating comprises sputtering from a single target consisting essentially of MoS₂-metal composite material.

33. A method as defined in claim 27, wherein the step of coating comprises sputtering simultaneously from at least one target consisting essentially of MoS₂ and at least one target consisting essentially of metal.

34. A method as defined in claim 27, wherein the step of coating comprises sputtering from at least one target consisting essentially of molybdenum or MoS₂, and at least one target consisting essentially of metal sulfide.

35. A method as defined in claim 32, wherein the step of coating comprises sputtering from a target prepared by hot pressing of MoS₂ powder along with a metal powder or metal sulfide powder.

36. A method as defined in claim 35, wherein the step of sputtering comprises sputtering from a target prepared by hot pressing of MoS₂ powder along with tin powder at a temperature below about 232°

C.

37. A method as defined in claim 35, wherein the step of sputtering comprises sputtering from a target prepared by hot pressing of MoS₂ powder along with a powder of SnS or SnS₂.

38. A method as defined in claim 27, wherein the step of coating comprises providing a power density at the at least one target in the range of 2 W/cm² to 12 W/cm².

39. A method as defined in claim 27, wherein the step of coating comprises admitting argon to the chamber in an amount sufficient to increase the chamber pressure to a level between 0.25 millitorr and 7.5 millitorr.

40. A method as defined in claim 39, wherein the step of admitting argon comprises admitting argon in an amount sufficient to increase the chamber pressure to a level between 0.5 millitorr and 3.0 millitorr.

41. A method as defined in claim 40, wherein the step of admitting argon comprises admitting argon in an amount sufficient to increase the chamber pressure to a level between 0.75 millitorr and 1.5 millitorr.

42. A method as defined in claim 23, wherein the step of coating comprises coating using a reactive deposition process.

43. A method as defined in claim 42, wherein the step of coating using a reactive deposition process comprises using a process in which deposition is from reaction of a gaseous sulfur compound with molybdenum and the metal target.

44. A method as defined in claim 43, wherein the gaseous sulfur compound is H₂S or a vapor of elemental sulfur.

45. A method as defined in claim 23, wherein the predetermined thickness is between about 0.05 μ

m and about 2.0 μ

m.

46. A method as defined in claim 45, wherein the predetermined thickness is between about 0.1 μ

m and about 1.0 μ

m.

47. A method as defined in claim 23, wherein the method further comprises a step of coating the substrate material with chromium, titanium, or zirconium to form a thin intermediate metal layer having a predetermined thickness, before the step of coating the substrate material with the solid thin film of MoS_x-metal composite material.

48. A method as defined in claim 47, wherein the predetermined thickness of the thin intermediate metal layer is between about 0.005 μ

m and about 0.2 μ

m.

49. A method as defined in claim 23, wherein the method further comprises using an ion source for fine-cleaning the substrate by bombarding the substrate with Ar⁺ ions before the step of coating the substrate material with the MOS_x-metal composite material.

50. A method as defined in claim 23 wherein the substrate material is in the form of a thin strip.

51. A method for making an electrical connector comprising a male terminal and a female terminal, the male and female terminals each comprising a substrate material and contact surfaces, wherein at least a portion of the contact surfaces of the female terminal or the male terminal are coated by a solid thin film comprising a MoS_x-Sn composite material, wherein “

x”

is the atomic ratio of sulfur to molybdenum in the MoS_x-Sn composite material, the method comprising;

providing the substrate material in the form of a thin strip;

pre-cleaning the substrate material;

placing the substrate material in a vacuum deposition chamber having a refrigerated trap;

evacuating the vacuum deposition chamber to a pressure less than about 7.5×

10<sup>−

4</sup> millitorr;

cooling the refrigerated trap of the chamber to a temperature less than 150 Kelvin;

admitting argon in the chamber in an amount sufficient to increase the pressure in the vacuum deposition chamber to a level between 0.25 millitorr and 7.5 millitorr;

fine-cleaning the substrate material by bombarding the substrate material with Ar⁺ ions;

coating the substrate material with titanium or chromium to form a thin intermediate metal layer having a thickness between 0.005 μ

m and 0.2 μ

m; and

coating the substrate material using sputter deposition from a balanced planar magnetron with a MoS₂-Sn composite target composite material to form solid thin film having a thickness between 0.1 μ

m and 1.0 μ

m,

wherein the MoS₂-Sn composite target is manufactured by hot pressing of MoS₂ powder and tin powder at a temperature below 232°

C.,

and wherein the magnetron is powered by a direct current power supply at a power density between 2 W/cm² and 12 W/cm².