Conditioning shampoo compositions containing select cationic conditioning polymers

• US 20030223951A1
• Filed: 06/04/2003
• Published: 12/04/2003
• Est. Priority Date: 06/04/2002
• Status: Abandoned Application

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Asante, Afua Asiedua, Coffindaffer, Timothy Woodrow, Wells, Robert Lee, Hughes, Kendrick Jon, Geary, Nicholas William, Brown, Mark Anthony
• Application Number:
  US10/454,234
• Publication Number:
  US 20030223951A1
• Time in Patent Office: Days
• US Class Current: 424/70.17
• CPC Class Codes: A61K 2800/5426 cationic
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61K 8/8158 Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/817 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
• CPC Class Codes: A61K 8/8182 Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8194 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 5/12 Preparations containing hair conditioners

Abstract

Disclosed are aqueous conditioning shampoo compositions which comprise an anionic detersive surfactant component; from about 0.025% to about 5% by weight of an water soluble or dispersible, cationic, non crosslinked, deposition or conditioning polymer; the conditioning shampoo may additionally comprise dispersed, liquid, droplets of a water insoluble, hair conditioning agent having a volume average particle diameter of from about 5 microns to about 125 microns. A homopolymer has a cationic charge density from about from about 2 meq/gm to about 4 meq/gm or a cationic charge density of from about 5 meq/gm to about 10 meq/gm; or an average molecular weight of at least 500,000. A copolymer is formed from one or more cationic monomer units and one or more nonionic monomer units or monomer units bearing a negative charge wherein the subsequent charge of the copolymer is positive. The cationic polymer, in combination with anionic detersive surfactant component and other essential components, provides improved deposition of the conditioning agent on hair or skin, even when the dispersed conditioning agent particles have a volume average particle size of up to about 125 microns. The composition may be applied to skin or hair, and provides improved conditioning performance even without the use of the dispersed hair conditioning agent particles.

Claims

1. A personal cleansing composition comprising:

A. from about 5% to about 50% by weight of a detersive surfactant component selected from the group consisting of anionic surfactants, amphoteric and zwitterionic surfactants having an attached group that is anionic at the pH of the composition, and combinations thereof;

B. from about 0.025% to about 5% by weight of a water soluble or dispersible, cationic, non-crosslinked, conditioning homopolymer having a cationic charge density of from about 2 meq/gm to about 4 meq/gm or a cationic charge density of from about 5 meq/gm to about 10 meq/gm; and

C. from about 20% to about 94% by weight of water.

2. The personal cleansing composition of claim 1 further comprising from about 0.05% to about 5% by weight of dispersed droplets of a water insoluble hair conditioning agent having a volume average droplet diameter of from about 5 microns to about 125 microns.

3. The personal cleansing composition of claim 1 wherein the cationic charge density of the cationic polymer is from about 5 meq/gm to about 10 meq/gm.

4. The personal cleansing composition of claim 1 wherein the cationic charge density of the cationic polymer is from about 7 meq/gm to about 10 meq/gm.

5. The personal cleansing composition of claim 1 wherein the cationic polymer has an average molecular weight of from about 1,000 to about 5,000,000.

6. The personal cleansing composition of claim 1 further comprising from about 0.1% to about 5%, by weight, of a phase separation initiator selected from the group consisting of electrolytes, amphiphiles and mixtures thereof.

7. The composition of claim 1 wherein said cationic polymer promotes the formation of a microscopic-phase separation of lyotropic liquid crystals in said composition;

the liquid crystals exhibiting birefringence.

8. A personal cleansing composition according to claim 1 comprising lytropic liquid crystals that aids in the deposition of particles.

24. A method of treating hair by administering a safe and effective amount of the composition according to claim 1.

9. A personal cleansing composition comprising:

A. from about 5% to about 50% by weight of a detersive surfactant component selected from the group consisting of anionic surfactants, amphoteric and zwitterionic surfactants having an attached group that is anionic at the pH of the composition, and combinations thereof;

B. from about 0.025% to about 5% by weight of a water soluble or dispersible, cationic, non-crosslinked, conditioning homopolymer having an average molecular weight of from about 500,000 to about 5,000,000; and

C. from about 20% to about 94% by weight of water.

10. The personal cleansing composition of claim 9 further comprising from about 0.05% to about 5% by weight of dispersed droplets of a water insoluble hair conditioning agent having a volume average droplet diameter of from about 5 microns to about 125 microns.

11. The personal cleansing composition of claim 9 wherein the cationic polymer has an average molecular weight of from about 500,000 to about 2,000,000.

12. The personal cleansing composition of claim 9 wherein the cationic polymer has an average molecular weight of from about 750,000 to about 1,250,000.

13. The personal cleansing composition of claim 9 wherein the cationic charge density of the cationic polymer is from about 2 meq/gm to about 10 meq/gm.

14. The personal cleansing composition of claim 9 further comprising from about 0.1% to about 5%, by weight, of a phase separation initiator selected from the group consisting of electrolytes, amphiphiles and mixtures thereof.

15. The composition of claim 9 wherein said cationic polymer promotes the formation of a microscopic-phase separation of lyotropic liquid crystals in said composition, the liquid crystals exhibiting birefringence.

16. A personal cleansing composition according to claim 9 comprising lytropic liquid crystals that aids in the deposition of particles.

25. A method of treating hair by administering a safe and effective amount of the composition according to claim 9.

17. A personal cleansing composition comprising:

A. from about 5% to about 50% by weight of a detersive surfactant component selected from the group consisting of anionic surfactants, amphoteric and zwitterionic surfactants having an attached group that is anionic at the pH of the composition, and combinations thereof;

B. from about 0.025% to about 5% by weight of a water soluble or dispersible, cationic, non-crosslinked, conditioning copolymer comprising;

i. one or more cationic monomer units, and

ii. one or more nonionic or monomer units bearing a terminal negative charge

wherein said copolymer has a positive charge, a cationic charge density of from about 2 meq/gm to about 10 meq/gm, and an average molecular weight of from about 1,000 to about 5,000,000; and

C. from about 20% to about 94% by weight of water.

18. The personal cleansing composition of claim 17 further comprising from about 0.05% to about 5% by weight of dispersed droplets of a water insoluble hair conditioning agent having a volume average droplet diameter of from about 5 microns to about 125 microns.

19. The personal cleansing composition of claim 17 wherein the cationic charge density of the cationic polymer is from about 3 meq/gm to about 8 meq/gm.

20. The personal cleansing composition of claim 17 wherein the cationic polymer has an average molecular weight of from about 100,000 to about 2,000,000.

21. The personal cleansing composition of claim 17 further comprising from about 0.1% to about 5%, by weight, of a phase separation initiator selected from the group consisting of electrolytes, amphiphiles and mixtures thereof.

22. The composition of claim 17 wherein said cationic polymer promotes the formation of a microscopic-phase separation of lyotropic liquid crystals in said composition;

the liquid crystals exhibiting birefringence.

23. A personal cleansing composition according to claim 17 comprising lytropic liquid crystals that aids in the deposition of particles.

26. A method of treating hair by administering a safe and effective amount of the composition according to claim 17.