Method of producing wear resistant traffic markings

• US 20030224184A1
• Filed: 11/06/2002
• Published: 12/04/2003
• Est. Priority Date: 05/07/2002
• Status: Abandoned Application

• Current Assignee: Ann Robertson Hermes, Donald Craig Schall, Francis Joseph Landy
• Original Assignee: Ann Robertson Hermes, Donald Craig Schall, Francis Joseph Landy
• Inventors: Landy, Francis Joseph, Schall, Donald Craig, Hermes, Ann Robertson
• Application Number:
  US10/289,101
• Publication Number:
  US 20030224184A1
• Time in Patent Office: Days
• US Class Current: 428/447
• CPC Class Codes: C09D 5/004 Reflecting paints; Signal paints
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/8305 Miscellaneous [e.g., treated surfaces, etc.]

Abstract

A method is provided for producing wear resistant traffic markings. The method includes the application of a traffic paint composition containing select copolymer particles bearing acetoacetyl moieties and aminosilane. Also provided is a traffic marking prepared by the method of the present invention. The method allows the preparation of wear resistant traffic markings with low levels of aminosilane relative to the level of the acetoacetyl moieties.

Claims

1. A method for producing a wear resistant traffic marking on a road surface comprising the steps of:

a) applying on said road surface a layer of a traffic paint composition comprising;

copolymer particles dispersed in an aqueous evaporable carrier and an aminosilane bearing an amine moiety, wherein said copolymer particles bear pendant enamine moieties resulting from the reaction of a pendant acetoacetyl moieties with ammonia or amine;

said copolymer particles having a glass transition temperature in the range varying from −

30°

C. to 60°

C.; and

wherein the level of said aminosilane is in the range varying from 0.02 to less than 0.1 moles said amine moiety to one mole of said pendant acetoacetyl moieties; and

b) evaporating said aqueous evaporable carrier from said layer to form said wear resistant traffic marking on said road surface.

2. The method of claim 1 wherein said level of said aminosilane is in the range varying from 0.02 to 0.09 moles said amine moiety to one mole of said pendant acetoacetyl moieties.

3. The method of claim 1 or claim 2 wherein said copolymer particles comprise as polymerized units, from 1 to 10 weight percent, based on weight of said copolymer particles, of an acetoacetyl functional monomer having the following structure:

4. The method of claim 3 wherein said acetoacetyl functional monomer is selected from the group consisting of acetoacetoxyethyl methacrylate, allyl acetoacetate, acetoacetoxyethyl acrylate, acetoacetoxypropyl methacrylate, acetoacetoxybutyl methacrylate, 2,3-di(acetoacetoxy)propyl methacrylate, and combinations thereof.

5. The method of claim 1 or claim 2, wherein said aminosilane is selected from the group consisting of aminoethylaminoethylaminopropyl-trimethoxysilane, aminoethylaminopropylmethyldimethoxysilane, aminopropyltriethoxysilane, aminopropylmethyldimethoxysilane, N-methylaminopropyltrimethoxysilane, aminopropyltrimethoxysilane, aminoethylaminopropyltrimethoxysilane, polymeric aminoalkylsilicone, N-methylaminopropyltrimethoxysilane, aminopropylmethyldimethoxysilane, 4-aminobutyltriethoxysilane, oligomeric aminoalkylsilane, and combinations thereof.

6. The method of claim 1 or claim 2 wherein said layer has a no-pick-up time, as evaluated under ASTM D711-89, varying in the range of from 1 minute to 60 minutes at a relative humidity in the range of from 65 to 90 percent.

7. A traffic marking on a road surface prepared according to a method for producing a wear resistant traffic marking on a road surface;

said method comprising the steps of;

a) applying on said road surface a layer of a traffic paint composition comprising;

copolymer particles dispersed in an aqueous evaporable carrier and an aminosilane bearing an amine moiety, wherein said copolymer particles bear pendant enamine moieties resulting from the reaction of a pendant acetoacetyl moieties with ammonia or amine;

said copolymer particles having a glass transition temperature in the range varying from −

30°

C. to 60°

C.; and

wherein the level of said aminosilane is in the range varying from 0.02 to less than 0.1 moles said amine moiety to one mole of said pendant acetoacetyl moieties; and

b) evaporating said aqueous evaporable carrier from said layer to form said wear resistant traffic marking on said road surface.

8. The traffic marking of claim 7 wherein said level of said aminosilane is in the range varying from 0.02 to 0.09 moles said amine moiety to one mole of said pendant acetoacetyl moieties.

9. The traffic marking of claim 7 or claim 8 wherein said copolymer particles comprise as polymerized units, from 1 to 10 weight percent, based on weight of said copolymer particles, of an acetoacetyl functional monomer having the following structure:

10. The traffic marking of claim 7 or claim 8, wherein said aminosilane is selected from the group consisting of aminoethylaminoethylaminopropyl-trimethoxysilane, aminoethylaminopropylmethyldimethoxysilane, aminopropyltriethoxysilane, aminopropylmethyldimethoxysilane, N-methylaminopropyltrimethoxysilane, aminopropyltrimethoxysilane, aminoethylaminopropyltrimethoxysilane, polymeric aminoalkylsilicone, N-methylaminopropyltrimethoxysilane, aminopropylmethyldimethoxysilane, 4-aminobutyltriethoxysilane, oligomeric aminoalkylsilane, and combinations thereof.