System and method for monitoring changes in state of matter with terahertz radiation

• US 20030226969A1
• Filed: 10/29/2002
• Published: 12/11/2003
• Est. Priority Date: 12/28/1999
• Status: Active Grant

• Current Assignee: Luna Innovations, Inc.
• Original Assignee: Picometrix LLC (Luna Innovations, Inc.)
• Inventors: Williamson, Steven L
• Granted Patent: US 6,849,852 B2
• Time in Patent Office: Days
• US Class Current: 250/341.1
• CPC Class Codes: G01N 2021/1761 A physical transformation being implied in the method, e.g. a phase change
• CPC Class Codes: G01N 21/3563 for analysing solids; Preparation of samples therefor
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/3586 by Terahertz time domain spectroscopy [THz-TDS]
• CPC Class Codes: G01N 21/532 with measurement of scattering and transmission
• CPC Class Codes: G01N 21/59 Transmissivity G01N21/25 takes precedence

Abstract

A system and method for using terahertz radiation to detect and monitor a substance undergoing a change in phase from a liquid phase to a solid phase or vice-versa is disclosed. By employing terahertz radiation in either the pulsed mode or in the continuous-wave (CW) mode, the system can non-invasively monitor these changes. The system uses the principle that matter in a liquid state will absorb and attenuate terahertz radiation to a larger degree than matter in a semisolid or solid state. Most terahertz radiation absorption occurs due to the rotational motions of molecules, i.e. either whole molecules or groups of atoms rotating about molecular bonds.

Claims

1. A system for determining whether a sample under inspection is undergoing a change in state, the system comprising:

a laser light source for generating laser light;

an optically-driven terahertz transmitter which converts the laser light into terahertz electromagnetic radiation, wherein the terahertz electromagnetic radiation is transmitted through the sample;

an optically-driven terahertz receiver positioned opposite the terahertz transmitter for receiving the terahertz electromagnetic radiation transmitted through the sample; and

an analyzer for comparing the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to the terahertz electromagnetic radiation received by optically-driven terahertz receiver to determine whether the sample is undergoing a change in state.

2. The system of claim 1 wherein the analyzer further compares a transmitted power of the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to a received power of the terahertz electromagnetic radiation received by the optically-driven terahertz receiver to determine whether the sample is undergoing a change in state.

3. The system of claim 1 wherein the analyzer further compares a transmitted peak voltage amplitude of the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to a received peak voltage amplitude of the terahertz electromagnetic radiation received by the optically-driven terahertz receiver determine whether the sample is undergoing a change in state.

4. The system of claim 1, wherein the laser light source is a laser capable of producing an optical pulse having a duration of approximately 100 femtoseconds.

5. The system of claim 4, wherein a fiber delivery system is used to deliver the optical pulse from the laser light source to the optically-driven terahertz transmitter and receiver.

6. The system of claim 5, further comprising a precompensator for adding dispersion to cancel dispersion acquired in the fiber delivery system.

7. The system of claim 1, wherein the laser light source further comprises a plurality of single-frequency light sources for generating a plurality of single frequency-light signals, wherein the plurality of single frequency-light signals are added coherently at the optically-driven terahertz transmitter and receiver.

8. The system of claim 7, further comprising a fiber combiner for spatially overlapping the plurality of single frequency-light signals.

9. The system of claim 1, wherein the terahertz transmitter and receiver further comprise a photoconductive element for converting the laser light to the terahertz electromagnetic radiation.

10. The system of claim 9, wherein the photoconductive element is a low-temperature-grown GaAs semiconductor.

11. The system of claim 1, wherein the terahertz transmitter and receiver further comprise an electro-optic element for converting the laser light to the terahertz electromagnetic radiation.

12. The system of claim 11, wherein the electro-optic element is comprised of ZnTe.

13. The system of claim 1, wherein the terahertz transmitter and receiver further comprise an antenna for improving coupling efficiency of the terahertz electromagnetic radiation out of the transmitter and into the receiver

14. The system of claim 1, further comprising an optical delay device for introducing a delay in the transmission of the laser light from the laser light source to the optically-driven terahertz receiver.

15. The system of claim 1, further comprising a terahertz optical element in alignment with the terahertz transmitter for focusing the terahertz electromagnetic radiation onto the sample.

16. The system of claim 1, further comprising a terahertz optical element in alignment with the terahertz receiver for concentrating the terahertz electromagnetic radiation onto the terahertz receiver.

17. A method for determining whether a sample under inspection is undergoing a change in state, the method comprising:

generating a coherent lightwave using a laser light source;

converting the coherent lightwave into terahertz electromagnetic radiation using an optically-driven terahertz transmitter, wherein the optically-driven terahertz transmitter transmits the terahertz electromagnetic radiation through the sample;

receiving the terahertz electromagnetic radiation transmitted through the sample using an optically-driven terahertz receiver positioned opposite the optically-driven terahertz transmitter; and

comparing the transmitted terahertz electromagnetic radiation to the received terahertz electromagnetic radiation to determine whether the sample is undergoing a change in state.

18. The method of claim 17, wherein comparing the transmitted terahertz electromagnetic radiation to the received terahertz electromagnetic radiation further comprises comparing a transmitted power of the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to a received power of the terahertz electromagnetic radiation received by the optically-driven terahertz receiver for determining whether the sample is undergoing a change in state.

19. The method of claim 17, wherein comparing the transmitted terahertz electromagnetic radiation to the received terahertz electromagnetic radiation further comprises comparing a transmitted peak voltage amplitude of the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to a received peak voltage amplitude of the terahertz electromagnetic radiation received by the optically-driven terahertz receiver for determining whether the sample is undergoing a change in state.

20. The method of claim 17, further comprising producing an optical pulse having a duration of approximately 100 femtoseconds.

21. The method of claim 20, further comprising delivering the optical pulse to the optically-driven terahertz transmitter and receiver using a fiber optic delivery system.

22. The method of claim 21, further comprising adding dispersion using a precompensator to cancel dispersion acquired in the optical delivery system.

23. The method of claim 17, further comprising improving coupling efficiency of the terahertz electromagnetic radiation out of the optically-driven terahertz transmitter and into the optically-driven terahertz receiver using an antenna, wherein each the transmitter and receiver include the antenna.

24. The method of claim 17, further comprising focusing the terahertz electromagnetic radiation onto the sample using a terahertz optical element in alignment with the optically-driven terahertz transmitter.

25. The method of claim 17, further comprising focusing the terahertz electromagnetic radiation transmitted through the sample onto the optically-driven terahertz receiver using a terahertz optical element in alignment with the terahertz receiver.

26. The method of claim 17, wherein generating a coherent lightwave using a laser light source further comprises generating a plurality of single frequency-light signals using a plurality of single frequency-light sources, wherein the plurality of single frequency-light signals are added coherently at the optically-driven terahertz transmitter and receiver.

27. A system for determining whether a sample under inspection is undergoing a change in state, the system comprising:

a pulsed laser light source for generating a pulse of laser light;

an optically-driven terahertz transmitter which converts the laser light into a pulse of terahertz electromagnetic radiation, wherein the terahertz electromagnetic radiation is transmitted through the sample;

an optically-driven terahertz receiver positioned opposite the terahertz transmitter for receiving the terahertz electromagnetic radiation transmitted through the sample;

a fiber delivery system for transmitting the laser light from the laser light source to the optically-driven terahertz transmitter and receiver;

an optical delay device for introducing a delay in the transmission of the laser light from the laser light source to the optically-driven terahertz receiver; and

an analyzer for comparing the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to the terahertz electromagnetic radiation received by the optically-driven terahertz receiver to determine whether the sample is undergoing a change in state.

28. The system of claim 27, wherein the laser light source is a laser capable of producing an optical pulse having a duration of approximately 100 femtoseconds.

29. The system of claim 27, further comprising a precompensator for adding dispersion to cancel dispersion acquired in the fiber delivery system.

30. The system of claim 27 wherein the analyzer further compares a transmitted power of the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to a received power of the terahertz electromagnetic radiation received by the optically-driven terahertz receiver to determine whether the sample is undergoing a change in state.

31. The system of claim 27 wherein the analyzer further compares a transmitted peak voltage amplitude of the terahertz electromagnetic radiation transmitted by the optically-driven terahertz transmitter to a received peak voltage amplitude of the terahertz electromagnetic radiation received by the optically-driven terahertz receiver determine whether the sample is undergoing a change in state.