Lithographic process using a chemical amplification resist and steps for limiting creep of the resist

• US 20040007382A1
• Filed: 06/10/2003
• Published: 01/15/2004
• Est. Priority Date: 06/18/2002
• Status: Abandoned Application

• Current Assignee: STMicroelectronics SA (STMicroelectronics NV)
• Original Assignee: STMicroelectronics SA (STMicroelectronics NV)
• Inventors: Mortini, Benedicte
• Application Number:
  US10/459,118
• Publication Number:
  US 20040007382A1
• Time in Patent Office: Days
• US Class Current: 174/253
• CPC Class Codes: G03F 7/2024 of the already developed image
• CPC Class Codes: G03F 7/40 Treatment after imagewise removal, e.g. baking
• CPC Class Codes: G03F 7/405 Treatment with inorganic or organometallic reagents after imagewise removal

Abstract

A lithographic process employing a resist for masking a substrate includes additional steps for limiting creep of the resist. The process is suitable for chemical amplification resists incorporating substrate protection agents sensitive to the same inactivation treatment as dissolution inhibitors of the resist. The additional steps are carried out after the development of the resist by dissolution. The steps include an additional step of sensitizing the residual resist on the substrate after the development, followed by a step of bringing the residual resist into contact with neutralization compounds.

Claims

1. A lithographic process comprising:

a) depositing, on a surface of a substrate, a resist incorporating dissolution inhibitors and protection agents for protecting the substrate from the effects of a given treatment, the substrate protection agents being sensitive to a treatment for inactivating the dissolution inhibitors;

b) exposing the surface carrying the resist to a first sensitizing radiation through a mask defining masked areas and exposed areas of the resist, so as to generate a first type of compounds in the exposed areas;

c) heating the resist so that the compounds of the first type inactivate at least some of the dissolution inhibitors in the exposed areas;

d) developing the resist by means of a dissolution liquid so as to selectively dissolve the resist in the exposed areas;

e) exposing at least part of the surface of the substrate to a second sensitizing radiation so as to generate compounds of the first type in at least some of said masked areas; and

f) neutralizing the compounds of the first type with compounds of a second type which are brought into contact with the residual resist.

2. The process according to claim 1, wherein the compounds of the second type are contained in a gas.

3. The process according to claim 1, wherein the compounds of the first and second types are acid and basic compounds, respectively.

4. The process according to claim 3, wherein the compounds of the second type are ammonia, an amine, compounds of the silazane or silazane-derivative type, compounds of the pyrrolidone or pyrrolidone-derivative type, or a mixture comprising some of the above compounds.

5. The process according to claim 1, wherein the compounds of the first type inactivate the dissolution inhibitors by breaking a chemical bond between said dissolution inhibitors and a polymer of the resist.

6. The process according to claim 1, which furthermore includes, between a) and b), a heating step to stabilize the resist.

7. The process according to claim 1, wherein the first and/or the second sensitizing radiation is light radiation.

8. The process according to claim 7, wherein the first sensitizing radiation used in b) to generate compounds of the first type in said exposed areas is light radiation having a wavelength of less than or equal to 193 nanometers.

9. The process according to claim 7, wherein the second sensitizing radiation used in e) to generate compounds of the first type in said masked areas is light radiation having a wavelength of less than or equal to 193 nanometers.

10. The process according to claim 1, wherein the resist areas created during a) to d) have at least one dimension of less than 130 nanometers measured parallel to the surface of the substrate.

11. The process according to claim 1, wherein said masked areas receive, in e), a radiation energy density at least equal to 5% of the radiation energy density received by said areas exposed in b).

12. The process according to claim 1, wherein, in f), the compounds of the second type are brought into contact with said masked areas for a time of greater than 10 seconds.

13. The process according to claim 1, wherein, in f), the residual resist is raised to a temperature below the maximum temperature reached by the resist during the heating of c).

14. A substrate created by the lithographic process of claim 1.

15. The substrate according to claim 14, comprising electronic components having at least one dimension of less than 130 nanometers, measured parallel to the surface of the substrate.

16. An electrical device including a substrate created by the process of claim 1.

17. The device according to claim 16, comprising electronic features having at least one dimension of less than 130 nanometers, measured parallel to the surface of the substrate.

18. A semiconductor fabrication process wherein unexposed areas of a resist exist on a substrate surface, the process comprising:

exposing the substrate to radiation without use of a lithographic mask to release an acid from the unexposed areas of resist; and

exposing the substrate to a basic compound to neutralize the released acid in the unexposed areas and inhibit creep of the unexposed areas of resist during subsequent processing.

19. The method of claim 18 wherein the resist is a modified methacrylate polymer-based resist.

20. The method of claim 18 wherein the resist is a polymer chain to which is linked a substrate protection group and a dissolution inhibitor group.

21. The method of claim 20 wherein creep prevention accrues because the acid, once neutralized, is no longer available in the unexposed areas of resist to break the substrate protection group from the polymer chain during subsequent processing.

22. The method of claim 18 wherein the basic compound is gaseous.

23. The method of claim 22 wherein the gaseous basic compound penetrates, by diffusion, into the unexposed areas of resist to neutralize the released acid.

24. The method of claim 18 wherein the resist is a chemical amplification resist incorporating a substrate protection agent which is sensitive to a same inactivation treatment as a dissolution inhibitor present within the resist.

25. A method for semiconductor fabrication, comprising:

using lithographic processing techniques to define an unexposed area of resist on a substrate which defines a feature having a width dimension of less than or equal to 180 nanometers; and

processing the unexposed area of resist to inhibit creep of the resist beyond the 180 nanometer width during subsequent processing of the substrate.

26. The method of claim 25 wherein the processing inhibits creep of the resist with respect to subsequent processing of the substrate which occurs at temperatures less than about 150 degrees Celsius.

27. The method of claim 25 wherein the processing includes:

exposing the substrate to radiation without use of a lithographic mask to release an acid from the unexposed areas of resist; and

exposing the substrate to a basic compound to neutralize the released acid in the unexposed areas.

28. The method of claim 27 wherein the basic compound is gaseous.

29. The method of claim 28 wherein the gaseous basic compound penetrates, by diffusion, into the unexposed areas of resist to neutralize the released acid.

30. The method of claim 25 wherein the resist is a modified methacrylate polymer-based resist.

31. The method of claim 25 wherein the resist is a polymer chain to which is linked a substrate protection group and a dissolution inhibitor group.

32. The method of claim 31 wherein processing inhibits creep because the acid, once neutralized, is no longer available in the unexposed areas of resist to break the substrate protection group from the polymer chain during subsequent processing.

33. The method of claim 25 wherein the resist is a chemical amplification resist incorporating a substrate protection agent which is sensitive to a same inactivation treatment as a dissolution inhibitor present within the resist.