Maintenance cleaning for membranes

• US 20040007525A1
• Filed: 06/16/2003
• Published: 01/15/2004
• Est. Priority Date: 07/30/1999
• Status: Abandoned Application

• Current Assignee: Zenon Technology Partnership
• Original Assignee: Zenon Technology Partnership
• Inventors: Rabie, Hamid R., Behmann, Henry, Husain, Hidayat
• Application Number:
  US10/461,687
• Publication Number:
  US 20040007525A1
• Time in Patent Office: Days
• US Class Current: 210/636
• CPC Class Codes: B01D 2321/04 Backflushing
• CPC Class Codes: B01D 2321/08 Use of hot water or water vapor
• CPC Class Codes: B01D 2321/2066 Pulsated flow
• CPC Class Codes: B01D 61/18 Apparatus therefor
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: B01D 65/08 Prevention of membrane fouling or of concentration polarisation
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 3/1273 Submerged membrane bioreactors
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage

Abstract

A method of cleaning ultrafiltration or microfiltration membranes reduces the rate of decline in the permeability of the membranes so that intensive recovery cleaning is required less frequently. In one aspect, cleaning events using a chemical cleaner are started before the membranes foul significantly and are repeated between 1 and 7 times per week. The product of the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl and the duration of all cleaning events is between 2,000 minutesmg/l and 30,000 minutesmg/l per week. When performed in situ, each cleaning event comprises (a) stopping permeation and any agitation of the membranes, (b) backwashing the membranes with a chemical cleaner in repeated pulses and (c) resuming agitation, if any, and permeation. The pulses last for between 10 seconds and 100 seconds and there is a time between pulses between 50 seconds and 6 minutes. Each cleaning event typically involves between 5 and 20 pulses. In another aspect, cleaning events using a pulsed backwash of heated water are similarly started before the membranes foul significantly and are repeated between twice a day and once every two days.

Claims

1. A method for cleaning one or more membranes normally immersed in water containing solids and used to produce a permeate on the insides of the membranes, comprising the steps of:

performing one or more cleaning events per week, wherein,

each cleaning event comprises the steps of flowing a chemical cleaner through the membranes to provide a chemical cleaner in or adjacent the membranes for a period of time; and

,

the cleaning events reduce the frequency of necessary recovery cleanings of the membranes.

2. The method of claim 1 wherein recovery cleanings of the membranes are performed from time to time and the cleaning events are performed between recovery cleanings.

3. The method of claim 2 wherein the decrease in permeability of the membranes between consecutive cleaning events is typically at least as great as the increase in the permeability of the membranes after each of the consecutive cleaning events.

4. The method of claim 3 wherein the cleaning events reduce the rate of a decline in permeability of the membranes between recovery cleanings.

5. The method of claim 2 wherein the recovery cleanings are performed at least 15 days apart from each other.

12. The method of claim 1 wherein

(a) the period of time is deemed to be the time during which the chemical cleaner is flowed through the membranes plus the shorter of (i) 5 minutes, (ii) the time between when the chemical cleaner stops flowing through the membranes and when the membranes are agitated, (iii) the time between when the chemical cleaner stops flowing through the membranes and permeate is withdrawn through the membranes, and (iv) the time between when the chemical cleaner stops flowing through the membranes and the membranes are backwashed with permeate;

and,

(b) the period of time is between about 10 minutes and 100 minutes.

13. The method of claim 12 wherein

each cleaning event has a CT which is equal to (A) the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl in cleaning efficiency multiplied by (B) the period of time;

and, (C) the one or more cleaning events has a weekly CT which is equal to the sum of the CT of each cleaning event performed in a week and is between 2000 minutes

mg/L and 20,000 minutes

mg/L.

14. The method of claim 12 wherein

each cleaning event has a CT which is equal to (A) the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl in cleaning efficiency multiplied by (B) the period of time;

and, (C) the one or more cleaning events has a weekly CT'"'"'s which is equal to the sum of the CT'"'"'s of the one or more cleaning events performed in a week and is between 10,000 minutes

mg/L and 30,000 minutes

mg/L and the membranes are normally immersed in wastewater.

15. The method of claim 13 wherein the cleaning events are performed at regular intervals and each have the same CT.

16. The method of claim 14 wherein the cleaning events are performed at regular intervals and each have the same CT.

17. The method of claim 12 wherein the membranes remain immersed during the period of time.

18. The method of claim 17 wherein the membranes are not agitated during the period of time.

19. The method of claim 1 wherein the permeate side of the membranes is flushed with permeate before permeation is resumed after a cleaning event.

20. The method of claim 1 wherein permeate first collected when permeation is resumed after a cleaning event is not used as permeate.

21. The method of claim 1 wherein the step of flowing a cleaning chemical through the membranes further comprises the steps of flowing permeate through the membranes from the permeate side of the membranes and introducing a chemical cleaner to the flowing permeate.

22. The method of claim 1 wherein some or all of the tank water is drained after the cleaning events and replaced with feed water.

23. The method of claim 22 wherein substantially all of the cleaning chemical is removed from the tank as retentate before permeation is resumed.

24. The method of claim 22 practiced in combination with a batch filtration process.

25. The method of claim 24 wherein the cleaning events are performed with the tank empty.

26. The method of claim 1 wherein the membranes are hollow fibre porous membranes.

27. The method of claim 26 wherein the membranes have an average pore size between 0.003 microns and 10 microns.

28. The method of claim 1 wherein the cleaning events are started while the permeability of a membrane is still more than 70% of its fresh permeability.

29. The method of claim 1 wherein the amount of chemical cleaner used per square meter of surface area of the membranes per week is between 50 and 1000 mg of NaOCl or equivalent.

30. The method of claim 29 wherein the amount of chemical cleaner used per square meter of surface area of the membranes per week is between 220 and 550 mg of NaOCl or equivalent.

31. The method of claim 29 wherein the membranes are immersed in waste water.

32. The method of claim 1 wherein the cleaning events are performed between 1 and 7 times per week.

33. The method of claim 32 wherein the cleaning events are performed between 2 and 4 times per week.

34. The method of claim 1 wherein the cleaning event dosage is selected to not exceed applicable regulatory or design limitations of cleaning chemical or cleaning chemical products in the permeate.

41. The method of claim 1 wherein

(a) the period of time is deemed to be the time during which the chemical cleaner is flowed through the membranes plus the shorter of (i) 5 minutes, (ii) the time between when the chemical cleaner stops flowing through the membranes and when the membranes are agitated, (iii) the time between when the chemical cleaner stops flowing through the membranes and permeate is withdrawn through the membranes, and (iv) the time between when the chemical cleaner stops flowing through the membranes and the membranes are backwashed with permeate;

and,

(b) each cleaning event has a CT which is equal to (A) the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl in cleaning efficiency multiplied by (B) the period of time; and

,

(c) the one or more cleaning events has a weekly CT'"'"'s which is equal to the sum of the CT'"'"'s of the one or more cleaning events performed in a week and is between 2000 minutes

mg/L and 20,000 minutes

mg/L.

43. The method of claim 1 wherein the cleaning events are performed at regular intervals and each have the same CT, wherein the CT of each cleaning event equal to (A) the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl in cleaning efficiency multiplied by (B) the period of time.

6. The method of clam 1 where in the cleaning chemical is an oxidant.

7. The method of claim 6 wherein the cleaning chemical comprises chlorine.

8. The method of claim 7 wherein the residual chlorine concentration in the tank after each cleaning event is less than 0.5 mg/L.

9. The method of claim 7 wherein the chemical cleaner contains between about 20 ppm and 200 ppm of chlorine.

10. The method of claim 8 wherein the permeate is intended to become drinking water.

11. The method of claim 6 wherein the cleaning chemical is NaOCl.

35. A method for cleaning one or more membranes normally immersed in water containing solids and used to produce a permeate on the insides of the membranes, comprising the steps of:

(a) performing recovery cleanings of the membranes from time to time; and

,

(b) between recovery cleanings, performing one or more cleaning events per week, each cleaning event comprising the steps of flowing a chemical cleaner through the membranes to provide a chemical cleaner in or adjacent the membranes for a period of time.

36. The method of claim 35 wherein the recovery cleanings are performed at least 15 days apart from each other.

37. The method of claim 35 wherein the membranes remain immersed and are not agitated while the chemical cleaner is flowed through the membranes.

38. The method of claim 35 wherein the chemical cleaner comprises and oxidant.

39. The method of claim 38 wherein the cleaning chemical comprises chlorine.

40. The method of claim 39 wherein the chemical cleaner contains between about 20 ppm and 200 ppm of chlorine.

42. The method of claim 35 wherein

(a) the period of time is deemed to be the time during which the chemical cleaner is flowed through the membranes plus the shorter of (i) 5 minutes, (ii) the time between when the chemical cleaner stops flowing through the membranes and when the membranes are agitated, (iii) the time between when the chemical cleaner stops flowing through the membranes and permeate is withdrawn through the membranes, and (iv) the time between when the chemical cleaner stops flowing through the membranes and the membranes are backwashed with permeate;

and,

(b) each cleaning event has a CT which is equal to (A) the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl in cleaning efficiency multiplied by (B) the period of time; and

,

(c) the one or more cleaning events has a weekly CT'"'"'s which is equal to the sum of the CT'"'"'s of the one or more cleaning events performed in a week and is between 10,000 minutes

mg/L and 30,000 minutes

mg/L and the membranes are normally immersed in wastewater.

44. The method of claim 35 wherein the permeate side of the membranes is flushed with permeate before permeation is resumed after a cleaning event.

45. The method of claim 35 wherein permeate is first collected when permeation is resumed after a cleaning event is not used as permeate.

46. The method of claim 35 wherein the step of flowing a cleaning chemical through the membranes further comprises the steps of flowing permeate through the membranes from the permeate side of the membranes and introducing a chemical cleaner to the flowing permeate.

47. The method of claim 35 wherein chemical cleaner is removed from the tank as retentate before permeation is resumed.

48. The method of claim 47 wherein substantially all of the cleaning chemical is removed from the tank as retentate before permeation is resumed.

49. The method of claim 35 wherein the membranes are hollow fibre porous membranes.

50. The method of claim 49 wherein the membranes have an average pore size between 0.003 microns and 10 microns.

51. The method of claim 35 wherein the cleaning events are started while the permeability of the membrane is still more than 70% of its their permeability after the last recovery cleaning.

52. The method of claim 35 wherein the amount of chemical cleaner used per square meter of surface area of the membranes per week is between 50 and 1000 mg of NaOCl or equivalent.

53. The method of claim 52 wherein the amount of chemical cleaner used per square meter of surface area of the membranes per week is between 220 and 550 mg of NaOCl or equivalent.

54. The method of claim 52 wherein the membranes are immersed in waste water.

55. The method of claim 35 wherein the cleaning events are performed between 1 and 7 times per week.

56. The method of claim 55 wherein the cleaning events are performed between 2 and 4 times per week.

57. The method of claim 35 wherein the cleaning event dosage is selected to not exceed applicable regulatory or design limitations of cleaning chemical or cleaning chemical products in the permeate.

58. The method of claim 35 practiced in combination with a batch filtration process.

59. The method of claim 35 wherein some or all of the tank water is drained after the cleaning events and replaced with feed water.

60. The method of claim 58 wherein the cleaning events are performed with the tank empty.

61. The method of claim 35 wherein the residual chlorine concentration in the tank after each cleaning event is less than 0.5 mg/L.