Method and apparatus for processing discharged fuel solution from a hydrogen generator

• US 20040009379A1
• Filed: 07/11/2002
• Published: 01/15/2004
• Est. Priority Date: 07/11/2002
• Status: Abandoned Application

• Current Assignee: Millennium Cell Inc.
• Original Assignee: Millennium Cell Inc.
• Inventors: Amendola, Steven C., Petillo, Stephen C., Petillo, Phillip J.
• Application Number:
  US10/193,666
• Publication Number:
  US 20040009379A1
• Time in Patent Office: Days
• US Class Current: 429/17
• CPC Class Codes: B01J 19/0006 Controlling or regulating processes controlling or regulating in general G05
• CPC Class Codes: B01J 2219/00049 Controlling or regulating processes
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: F17C 11/005 for hydrogen
• CPC Class Codes: Y02E 60/32 Hydrogen storage
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The discharged fuel solution remaining after the generation of hydrogen gas from a chemical reaction of a fuel is processed. This processing substantially reduces the liquid content of the discharged fuel thereby substantially reducing both its weight and volume. Such weight and volume reduction provides a corresponding decrease in the costs of storing and transporting the discharged fuel. This technique can be used with virtually any system that generates hydrogen via a hydrolysis process. In the disclosed embodiment, the fuel for generating hydrogen is sodium borohydride and the discharged fuel in the form of a solution or slurry of sodium metaborate is spray dried into a sodium metaborate powder. Advantageously, the present invention may be used with any of a number of techniques that accelerate the process of evaporation.

Claims

1. A system for generating hydrogen comprising

a chamber for holding a fuel solution, said fuel solution generating hydrogen and a discharged fuel solution via a chemical reaction,

first outlet and second outlets for respectively receiving said generated hydrogen, and said discharged fuel solution;

and

an element for receiving said discharged fuel solution and removing substantial amounts of the liquid therein.

2. The system of claim 1 further including a catalyst chamber for receiving said fuel solution from said chamber, said catalyst enhancing the rate at which hydrogen and discharged fuel is generated from said fuel solution.

4. The system of claim 1 wherein said fuel solution is formed from a solid fuel component and a liquid fuel component and said system further includes a sold fuel component dispenser for respectively providing predetermined amounts of a solid fuel component and a liquid fuel component to said chamber, each dispenser being operative in response to a predetermined condition.

5. The system of claim 4 further including a stabilizer dispenser for providing a certain amount of stabilizer to said chamber in response to said predetermined condition.

6. The system of claim 1 including a dispenser for providing a predetermined amount of said fuel solution to said chamber in response to a predetermined condition.

7. The system of claim 1 wherein the generated hydrogen includes moisture and said system further including apparatus, coupled to said first outlet, for reducing the moisture in the generated hydrogen.

8. The system of claim 1 wherein said element facilitates evaporation of said discharged fuel solution.

9. The system of claim 1 wherein said element includes a nozzle for outputting said discharged fuel solution as a spray.

10. The system of claim 9 wherein said nozzle receives said discharged fuel solution under pressure.

11. The system of claim 10 wherein said discharged fuel solution under pressure is provided by supplying said discharged fuel solution to a cylinder and then forcing this solution through said nozzle via movement of a piston disposed within said cylinder.

12. The system of claim 9 further including a vessel for receiving the spray provided by said nozzle.

3. The system of 1 further including a pump for pumping said fuel solution from said chamber to said catalyst chamber.

13. Apparatus for use with a discharged fuel solution, said discharged fuel solution being generated by a chemical reaction of a fuel solution that also generates hydrogen, said apparatus comprising

an input for receiving said discharged fuel solution;

and

an element for removing substantial amounts of the liquid content of said discharged fuel solution.

14. The apparatus of claim 13 wherein said element includes a nozzle for outputting said discharged fuel solution as a fine spray.

15. The apparatus of claim 14 wherein said apparatus further includes a device for supplying said discharged fuel solution to said nozzle under pressure.

16. A method of processing a discharged fuel solution generated by a chemical reaction of a fuel solution that also generates hydrogen, said method comprising the steps of

receiving said discharged fuel solution;

and

removing substantial amounts of the liquid content of said discharged fuel by in a manner that expedites the evaporation process.

17. A method of generating hydrogen comprising the steps of

providing a fuel solution capable of generating hydrogen along with a discharged fuel and coupling said generated hydrogen to an output;

and

receiving said discharged fuel solution and processing the same as so to remove substantial amounts of the liquid content of said discharged fuel solution, said processing being one that expedites the evaporation process.