HYDROGEN TO STEAM REFORMING OF NATURAL GAS TO SYNTHESIS GAS

• US 20040018144A1
• Filed: 07/23/2002
• Published: 01/29/2004
• Est. Priority Date: 07/23/2002
• Status: Active Grant

• Current Assignee: BP Corporation North America Incorporated (BP PLC)
• Original Assignee: BP Corporation North America Incorporated (BP PLC)
• Inventors: Briscoe, Michael D.
• Granted Patent: US 6,749,829 B2
• Time in Patent Office: Days
• US Class Current: 423/652
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0238 the reforming step being a carbon dioxide reforming step
• CPC Class Codes: C01B 2203/062 Hydrocarbon production, e.g. Fischer-Tropsch process
• CPC Class Codes: C01B 2203/1264 Catalytic pre-treatment of the feed
• CPC Class Codes: C01B 2203/142 At least two reforming, decomposition or partial oxidation steps in series
• CPC Class Codes: C01B 3/323 Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
• CPC Class Codes: C01B 3/38 using catalysts
• CPC Class Codes: C01B 5/00 Water

Abstract

The present invention is directed to a process for producing synthesis gas comprising the steps of reacting a hydrogen-containing stream with an oxygen-containing stream and producing an oxidized stream comprising water; contacting a feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen with the oxidized stream comprising water and forming a reforming feedstream; and passing the reforming feedstream into a reforming reaction zone at reforming reaction conditions and producing a synthesis gas product.

Claims

1. A process for producing synthesis gas comprising the steps of:

reacting a hydrogen-containing stream with an oxygen-containing stream and producing an oxidized stream comprising water;

contacting a feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen with said oxidized stream comprising water and forming a reforming feedstream; and

passing said reforming feedstream into a reforming reaction zone at reforming reaction conditions and producing a synthesis gas product.

2. The process of claim 1 wherein said oxygen-containing stream comprises oxygen and said oxygen-containing stream is reacted in an amount ranging from about 80 mole % to about 105 mole % of the stoichiometrically required amount of oxygen required to fully oxidize said hydrogen-containing stream to water and carbon dioxide.

3. The process of claim 1 wherein said hydrogen-containing stream comprises at least 70 mole percent hydrogen and more than 60 mole % of the hydrogen-containing stream is oxidized to water, carbon dioxide or both in said reacting step.

4. The process of claim 1 wherein water is added to at least one stream selected from the group consisting of said oxygen-containing stream, said hydrogen-containing stream and said feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen.

5. The process of claim 4 wherein:

said reacting step is conducted in a burner;

said water is added to at least one stream selected from the group consisting of said oxygen-containing stream and said hydrogen-containing stream; and

said water is processed through said burner so as to reduce the adiabatic flame temperature exiting said burner compared to the adiabatic flame temperature exiting said burner in the absence of said water.

6. The process of claim 1 wherein:

said hydrogen-containing stream comprises at least 70 mole percent hydrogen;

said feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen comprises less than 2 mole percent molecular oxygen; and

said oxygen-containing stream comprises at least 70 mole percent oxygen and said oxygen-containing stream is reacted in said reacting step in an amount ranging from about 80 mole % to about 105 mole % of the stoichiometrically required amount of oxygen required to fully oxidize said hydrogen-containing stream to water, carbon dioxide or both.

7. The process of claim 1 wherein:

said reforming reaction zone comprises a reforming catalyst;

said reforming reaction conditions comprise a reaction zone inlet temperature of at least 2000°

F. and a reaction zone pressure of from about 150 psia to about 600 psia; and

said synthesis gas product exiting said reforming reaction zone has a molecular hydrogen to carbon monoxide molar ratio of from about 2.5;

1 to about 5;

1.

8. The process of claim 7 wherein said reforming reaction conditions comprise a reaction zone outlet temperature ranging from about 1600°

F. to about 2200°

F.

9. The process of claim 1 wherein at least a portion of said synthesis gas product exiting said steam reforming reaction zone is directed to a hydrogen separation step for separating said synthesis gas into a stream comprising hydrogen and a second synthesis gas product and at least a portion of said stream comprising hydrogen is added to said hydrogen-containing stream.

10. The process of claim 7 wherein said second synthesis gas product has a hydrogen to carbon monoxide molar ratio of from about 1.5:

1 to about 2.5;

1.

11. A process for producing synthesis gas comprising the steps of:

oxidizing at least a portion of a hydrogen-containing stream with an oxygen-containing stream in an amount ranging from about 80 mole % to about 105 mole % of the stoichiometrically required amount of oxygen required to fully oxidize said hydrogen-containing stream to water, carbon dioxide or both and producing an oxidized stream comprising water at elevated temperature;

contacting a feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen with said oxidized stream comprising water and forming a reforming feedstream; and

passing said reforming feedstream into a steam reforming reaction zone at steam reforming reaction conditions and producing a synthesis gas product.

12. The process of claim 11 wherein said oxygen-containing stream comprises oxygen and said oxygen-containing stream is reacted in an amount ranging from about 90 mole % to about 102 mole % of the stoichiometrically required amount of oxygen required to fully oxidize said hydrogen-containing stream to water and carbon dioxide.

13. The process of claim 11 wherein:

said hydrogen-containing stream comprises at least 80 mole percent hydrogen;

said feedstream comprising hydrocarbon or hydrocarbon comprising at least one atom of oxygen comprises water and less than 2 mole percent molecular oxygen;

said oxygen-containing stream comprises at least 90 mole percent oxygen; and

more than 60 mole % of said hydrogen-containing stream is oxidized to water, carbon dioxide or both in said reacting step.

14. The process of claim 11 wherein:

said steam reforming reaction zone comprises a reforming catalyst further comprising at least one active metal selected from the group consisting of nickel, rhodium, copper, and cobalt;

said steam reforming reaction conditions comprise a reaction zone inlet temperature of at least 2000°

F. and an average reaction zone pressure of from about 150 psia to about 600 psia; and

said synthesis gas product exiting said steam reforming reaction zone has a hydrogen to carbon monoxide molar ratio of from about 2.5;

1 to about 5;

1.

15. The process of claim 11 wherein at least a portion of said synthesis gas product exiting said steam reforming reaction zone is directed to a hydrogen separation step for separating said synthesis gas into a stream comprising hydrogen and a second synthesis gas product and at least a portion of said stream comprising hydrogen is added to said hydrogen-containing stream.

16. The process of claim 15 wherein said second synthesis gas product has a hydrogen to carbon monoxide molar ratio of from about 1.5:

1 to about 2.5;

1.

17. A process for producing synthesis gas comprising the steps of:

oxidizing at least a portion of a hydrogen-containing stream with a stream comprising oxygen such that more than 60 mole % of said hydrogen-containing stream is oxidized to water, carbon dioxide or both in said reacting step and producing an oxidized stream comprising water at elevated temperature;

contacting a hydrocarbon feedstream with said oxidized stream comprising water and forming a reforming feedstream; and

passing said reforming feedstream into a steam reforming reaction zone at steam reforming reaction conditions and producing a synthesis gas product,

wherein a substantial portion of the steam reforming heat of reaction is provided by said oxidizing step.

18. The process of claim 17 wherein

said hydrogen-containing stream comprises at least 80 mole percent hydrogen;

said hydrocarbon feedstream comprises water and less than 2 mole percent molecular oxygen; and

said stream comprising oxygen comprises at least 90 mole percent oxygen and substantially all of said oxygen from said oxygen-containing stream is reacted so as to form said oxidized stream comprising water.

19. The process of claim 17 wherein

said steam reforming reaction zone comprises a reforming catalyst further comprising at least one active metal selected from the group consisting of nickel, rhodium, copper, and cobalt;

said steam reforming reaction conditions comprise a reaction zone inlet temperature of at least 2400°

F. and a reaction zone outlet temperature ranging from about 1600°

F. to about 2200°

F.; and

said synthesis gas product exiting said steam reforming reaction zone has a hydrogen to carbon monoxide molar ratio of from about 2.5;

1 to about 5;

1.

20. The process of claim 17 wherein:

at least a portion of said synthesis gas product exiting said steam reforming reaction zone is directed to a hydrogen separation step for separating said synthesis gas into a stream comprising hydrogen and a second synthesis gas product;

at least a portion of said stream comprising hydrogen is added to said hydrogen-containing stream; and

said second synthesis gas product has a hydrogen to carbon monoxide molar ratio of from about 1.5;

1 to about 2.5;

1.