Radiation polymerisable compositions having accelerated cure

• US 20040044094A1
• Filed: 03/05/2003
• Published: 03/04/2004
• Est. Priority Date: 09/05/2000
• Status: Abandoned Application

• Current Assignee: John Lyndon Garnett
• Original Assignee: John Lyndon Garnett
• Inventors: Garnett, John Lyndon
• Application Number:
  US10/379,623
• Publication Number:
  US 20040044094A1
• Time in Patent Office: Days
• US Class Current: 522/1
• CPC Class Codes: C08F 2/46 Polymerisation initiated by wave energy or particle radiation
• CPC Class Codes: C08F 216/125 Monomers containing two or more unsaturated aliphatic radicals, e.g. trimethylolpropane triallyl ether or pentaerythritol triallyl ether
• CPC Class Codes: C08F 222/06 Maleic anhydride

Abstract

A radiation polymerisable composition comprising: (A) a donor/acceptor component for forming a charge transfer complex said component being selected from the group consisting of: (i) a bifunctional compound having an electron donor group and an electron withdrawing group and a polymerisable unsaturated group; (ii) a mixture of (a) at least one unsaturated compound having an electron donor group and a polymerisable unsaturated moiety; and (b) at least one unsaturated compound having an electron acceptor group and a polymerisable unsaturated group; and (B) a Lewis acid.

Claims

1. A radiation polymerisable composition comprising:

(A) a donor/acceptor component for forming a charge transfer complex said component being selected from the group consisting of;

(i) a bifunctional compound having an electron donor group and an electron withdrawing group and a polymerisable unsaturated group;

(ii) a mixture of (a) at least one unsaturated compound having an electron donor group and a polymerisable unsaturated moiety; and

(b) at least one unsaturated compound having an electron acceptor group and a polymerisable unsaturated group; and

(B) a Lewis acid.

2. A radiation polymerisable composition according to claim 1 wherein the Lewis acid is selected from the group consisting of hard Lewis acids (as categorized by the Pearson classification), borderline Lewis acids (as categorized as borderline by the Pearson classification) and mixtures thereof.

3. A radiation polymerisable composition according to claim 1 wherein the Lewis acid is selected from the group consisting of salts of magnesium, zinc, antimony and mixtures thereof.

4. A radiation polymerisable composition according to claim 1 wherein the Lewis acid is a halide salt of a Lewis acid selected from the group consisting of Sb³⁺, Sb⁵⁺, Zn²⁺, Fe²⁺, Fe³⁺, Sn²⁺, Sn⁴⁺, Cu²⁺, Mg²⁺, Mn²⁺, Co²⁺ and Co³⁺.

5. A radiation polymerisable composition according to claim 1 wherein the Lewis acid is a protic acid selected from the group consisting of hydrogen halides, sulphuric acid, sulphonic acids, phosphoric acids, phosphonic acids, nitric acid, carboxylic acids and mixtures thereof.

6. A radiation polymerisable composition according to claim 5 wherein the Lewis acid is selected from the group consisting of hydrogen halides, saturated and unsaturated carboxylic acids, saturated and unsaturated polycarboxylic acids and mixtures thereof.

7. A radiation polymerisable composition according to claim 6 wherein the Lewis acid is selected from the group consisting of HCl, C₁ to C₈ carboxylic acids which may optionally be branched straight chain saturated or unsaturated, polycarboxylic acids and para toluene sulphonic acid.

8. A radiation polymerisable composition according to claim 1 wherein the Lewis acid is present in a molar ratio of less than 0.5 mole per mole of double bonds in the charge transfer complex component.

9. A radiation polymerisable composition according to claim 8 wherein the molar ratio is in the range of from 0.0005 to 0.1 mole per mole of double bonds in the charge transfer complex.

10. A radiation polymerisable composition according to claim 8 wherein the molar ratio is in the range of from 0.005 to 0.05 mole of Lewis acid per mole of double bonds in the charge transfer complex.

11. A radiation polymerisable composition according to claim 1 wherein the charge transfer complex is formed from

(a) at least one unsaturated compound having an electron acceptor group and a polymerisable unsaturated moiety and represented by the formula (A)_nR wherein R is the structural part of the backbone and A is the structural fragment importing acceptor properties to the double bond and is selected from the group consisting of maleic diesters, maleic amide half esters, maleic diamides maleimides;

and

(b) at least one unsaturated compound having an electron donor group and a polymerisable unsaturated moiety being represented by the formula (D)_nR wherein R is the structural part of the backbone and D is the structural fragment importing donor properties to the double bond and is selected from the group consisting of vinyl ethers, alkenyl ethers, substituted cyclopentanes, substituted cyclohexanes, substituted furanes or thiophens, substituted pyrans and thiopyrans, ring substituted styrenes, substituted alkenyl benzenes, substituted alkenyl cyclopentanes and cyclohexenes.

12. A polymerisable composition according to claim 1 wherein in the charge transfer complex the acceptor component comprises maleic anhydride and the donor is selected from the group consisting of mono and divinyl ether and mixture thereof.

13. A radiation polymerisable composition according to claim 1 comprising an accepter selected from the group consisting of di-(C₁-C₂) alkyl ester of maleic acid and a donor selected from the group consisting of mono and divinyl ethers.

14. A radiation polymerisable composition according to claim 1 wherein the donor acceptor complex comprises vinyl ether or malonate capped urethane oligomer or mixture thereof.

15. A radiation polymerisable composition according to claim 1 further comprising a binder polymer.

16. A process for forming a coating on a substrate comprising providing a coating composition comprising:

(A) a donor/acceptor component for forming a charge transfer complex said component being selected from the group consisting of;

(i) a bifunctional compound having an electron donor group and an electron withdrawing group and a polymerisable unsaturated group;

(ii) a mixture of (a) at least one unsaturated compound having an electron donor group and a polymerisable unsaturated moiety; and

(b) at least one unsaturated compound having an electron acceptor group and a polymerisable unsaturated group; and

(B) a Lewis acid;

applying a coating of the composition to the substrate and subjecting the coating to radiation for sufficient time to cure the coating.