Process for producing fibres, film, casings and other products from modified soluble cellose

• US 20040051200A1
• Filed: 09/05/2003
• Published: 03/18/2004
• Est. Priority Date: 09/13/2000
• Status: Abandoned Application

• Current Assignee: Instytut Wlokien Chemicznych
• Original Assignee: Instytut Wlokien Chemicznych
• Inventors: Strarostka, Pawel, Wawro, Dariusz, Mikolajczyk, Wlodzimierz, Urbanowski, Alojzy, Struszczyk, Henryk
• Application Number:
  US10/380,388
• Publication Number:
  US 20040051200A1
• Time in Patent Office: Days
• US Class Current: 264/169
• CPC Class Codes: A22C 13/0013 Chemical composition of synthetic sausage casings
• CPC Class Codes: C08L 1/02 Cellulose; Modified cellulose
• CPC Class Codes: C08L 1/06 Cellulose hydrate
• CPC Class Codes: D01D 1/02 Preparation of spinning solutions
• CPC Class Codes: D01F 2/02 from solutions of cellulose in acids, bases or salts

Abstract

Process for producing fibres, film, casings and other products from modified soluble cellulose wherein the initial cellulose is hydrothermally treated at a temperature in the 100-200° C. range, under a pressure in the range from about 0.1 to 1.5 Mpa in a water/cellulose ration on a weight basis of at least 1:1 in the presence of a complex activator composed of Lewis acids and/or bases and/or their salts in an amount of at least 0.0001% by weight calculated on cellulose. The obtained modified cellulose pulp after, a possible purification, is in a dry or never dried condition, dissolved in an aqueous solution of alkali metal hydroxides. The dissolving is carried out at a temperature not lower than 0° C. for 1-120 minutes to obtain a homogenous spinning solution with the cellulose concentration at least 1% by weight. The alkaline cellulose solution is filtered, deaerated and coagulated by contacting it with water or aqueous acidic solutions. The produced fibres, film, casings and other products are washed with water to a neutral reaction and finished in a standard way.

Claims

1. A process for producing fibres, film, casings and other products from modified soluble cellulose by a hydrothermal treatment cellulose pulp, its dissolving in aqueous alkalines and coagulation from the alkaline solutions of cellulose characterized in that the initial cellulose is subjected to hydrothermal treatment with water and/or water steam at a temperature between 100°

C. to 200°

C. under a pressure in the range of 0.1 to 1.5 MPa with a water/cellulose ratio not lower than 1;

1 in the presence of a complex activator composed of Lewis acids like ascorbic acid, acetic acid, citric acid, formic acid, carbonic acid and/or Lewis bases like ammonia hydroxide, diethanolamine and/or their salts like guanidine carbonate, ammonia chloride, natrium citrate wherein the applied amount of the activator calculated on cellulose is not less than 0.001% by weight, preferably 0.01-0.5% by weight and then the produced, modified cellulose pulp after possible drying is, in dry or never dried condition, dissolved in aqueous solutions of alkali metals hydroxides at a temperature not lower than 0°

C., preferably 3-8°

C. during 1-120 minutes, to obtain a homogenous alkaline spinning solution of cellulose with a cellulose concentration not lower than 1% by weight, preferably 6-8% by weight, a hydroxide content not higher than 10% by weight, a filterability coefficient not more than 1000, a solution stability of at least 48 hours at a temperature not lower then 15°

C. and a ball viscosity not less than 10 seconds preferably 30-100 seconds, after which the obtained alkaline cellulose solution is filtered, deaerated and next coagulated in water or an aqueous acid solution preferably sulphuric acid solution with the concentration of 0.1 to 30% by weight at a temperature of 10-30°

C. and the obtained products are washed with water to a neutral reaction and finished in a standard way.

2. The process according to claim 1 characterized in that the produced fibres, film or casings are plasticized at a temperature in the range of 20-95°

C. preferably 60-90°

C. in water or an aqueous solution of an acid like hydrochloric or sulphuric acid and/or a plasticizer like glycol or glycerol with simultaneous drawing by at least 10% preferably 40-100%.

3. The process according to claim 1 characterized in that the initial cellulose pulp is, prior to the hydrothermal treatment, defibrated and swollen for 1 minute to 24 hours with a possible addition of a wetting agent at a temperature not lower than 10°

preferably with agitation.

4. The process according to claim 1 characterized in that, the aqueous solution of the alkali metals hydroxide contains zinc compounds preferably zinc oxide in an amount not less than 0.1% by weight and/or urea in an amount not less than 1% by weight.

5. The process according to claim 1 characterized in that the cellulose pulp after the hydrothermal treatment is characterized by a controlled structure including an average polymerization degree not less than 200, a polydispersity not less than 1.5, a water retention value not less than 50, a hydrogen bond energy in the 10-20 kJ/mol range and a content of no more than 2% by weight of a part insoluble in aqueous alkali solutions.