Method of generating hydrogen from borohydrides and water

• US 20040052723A1
• Filed: 09/13/2002
• Published: 03/18/2004
• Est. Priority Date: 09/13/2002
• Status: Active Grant

• Current Assignee: GM Global Technology Operations LLC (General Motors Company)
• Original Assignee: GM Global Technology Operations Incorporated (General Motors Company)
• Inventors: Jorgensen, Scott Willis
• Granted Patent: US 6,866,836 B2
• Time in Patent Office: Days
• US Class Current: 423/648.1
• CPC Class Codes: B01F 27/722 the helices closely surrounded by a casing
• CPC Class Codes: B01J 2219/182 horizontal
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: B01J 8/10 moved by stirrers or by rotary drums or rotary receptacles or endless belts
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: H01M 8/04216 characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
• CPC Class Codes: H01M 8/065 by dissolution of metals or alloys; by dehydriding metallic substances
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A method is provided that generates hydrogen to power a hydrogen consuming device. Hydrogen is stored on-board a vehicle in dry lithium and/or sodium borohydride particles. Upon demand from the hydrogen consuming device, such as a fuel cell, a portion of the borohydride is conveyed to an axial flow reactor. Water is then injected into the reactor in controlled amounts to hydrolyze the borohydride particles thus, producing hydrogen gas and solid-phase by-products. The reactor includes parallel, closely spanned, counter rotating augers to mix and convey the borohydride particles and solid by-products through the reactor. A separate grinding mechanism can be used to further crush and grind large by-product particles to increase packing efficiencies in a by-products storage vessel, where reaction products will later be stored. Hydrogen gas produced in the reaction is delivered to either a hydrogen buffer container for temporary storage or to the hydrogen consuming device.

Claims

1. A method of generating hydrogen in a fuel supply system combined with a hydrogen fuelled power device, said method comprising the steps of:

conveying lithium borohydride and/or sodium borohydride particles to an axial flow reactor upon demand for hydrogen from said power device;

injecting water into said axial flow reactor upon demand for hydrogen from said power device, the amount of said water being chemically balanced to the amount of said borohydride for the hydrolysis of said borohydride;

hydrolyzing said borohydride particles with said water in said reactor at a temperature above approximately 90°

C. to produce reaction products comprising hydrogen gas and solid by-products while mixing said borohydride particles and solid by-products in said reactor to expose unreacted borohydride particle surfaces for reaction with said water, and conveying the mixed materials through said reactor, said mixing and conveying using two rotating augers, the rate of conveying of said borohydride being controlled so as to retain a hydrogen gas volume in said reactor;

removing said reaction products from said reactor; and

conveying said hydrogen gas to said hydrogen fuelled device or to a hydrogen buffer container for said device.

2. A method as recited in claim 1 comprising hydrolyzing said borohydride particles at temperatures of at least 120°

C.

3. A method as recited in claim 1 comprising injecting said water in the amount of 1.6 to 2.5 parts by weight per 1 part of said lithium borohydride particles.

4. A method as recited in claim 1 comprising injecting said water in the amount of 1 to 1.5 parts by weight per 1 part of said sodium borohydride particles.

5. A method as recited in claim 1 comprising conveying said reaction products from said reactor to an unheated by-products storage vessel.

6. A method as recited in claim 1 comprising conveying said reaction products from said reactor to an unheated by-products storage vessel and conveying hydrogen gas from said by-products storage vessel to said hydrogen fuelled device or to a hydrogen buffer container for said device.

7. A method as recited in claim 1 further comprising conveying said reaction products from said reactor to a grinding vessel and further mixing and grinding said borohydride particles and said solid by-products in said grinding vessel before conveying said hydrogen gas to said hydrogen fuelled device or to a hydrogen buffer container for said device.

8. A method of generating hydrogen in a fuel supply system combined with a hydrogen consuming device, said method comprising the steps of:

conveying lithium borohydride and/or sodium borohydride particles to an axial flow reactor upon demand for hydrogen from said hydrogen consuming device;

injecting water into said axial flow reactor upon demand for hydrogen from said hydrogen consuming device, the rate of injection of said water being chemically balanced to the rate of conveying of said lithium borohydride for the hydrolysis of said borohydride;

reacting said borohydride particles and water in said axial flow reactor at a temperature above approximately 90°

C. to produce reaction products comprising hydrogen gas and solid by-products while mixing said borohydride particles and solid by-products in said reactor to expose unreacted borohydride particle surfaces for reaction with said water, and conveying the mixed materials through said reactor, said mixing and conveying using two rotating augers, the rate of conveying of said borohydride being controlled so as to maintain a hydrogen gas volume at least as large as the volume of said mixed materials in said reactor;

removing said reaction products from said reactor;

conveying said reaction products and said borohydride particles to a grinder/reactor;

reacting said borohydride particles and water in said grinder/reactor at a temperature of about 120°

C. to produce further reaction products comprising hydrogen gas and solid by-products;

removing said reaction products from said grinder/reactor; and

conveying said hydrogen gas to said hydrogen consuming device or to a hydrogen buffer container for said device.

9. A method as recited in claim 8 comprising injecting said water in the amount of 1.6 to 2.5 parts by weight per 1 part of said lithium borohydride particles.

10. A method as recited in claim 8 comprising injecting said water in the amount of 1 to 1.5 parts by weight per 1 part of said sodium borohydride particles.

11. A method as recited in claim 8, comprising conveying said reaction products from said grinder/reactor to an unheated by-products storage vessel.

12. A method as recited in claim 8, comprising conveying said reaction products from said grinder/reactor to an unheated by-products storage vessel and conveying hydrogen gas from said by-products storage vessel to said hydrogen consuming device or to a hydrogen buffer container for said device.