Efficiency lateral micro fuel cell

• US 20040058226A1
• Filed: 04/21/2003
• Published: 03/25/2004
• Est. Priority Date: 04/25/2002
• Status: Abandoned Application

• Current Assignee: Philip A. Lamarre, Robert Scott Morris, Ryne Raffaelle, Thomas Gennett
• Original Assignee: Philip A. Lamarre, Robert Scott Morris, Ryne Raffaelle, Thomas Gennett
• Inventors: Morris, Robert Scott, Raffaelle, Ryne, Lamarre, Philip A., Gennett, Thomas
• Application Number:
  US10/419,331
• Publication Number:
  US 20040058226A1
• Time in Patent Office: Days
• US Class Current: 429/44
• CPC Class Codes: H01M 4/8605 Porous electrodes
• CPC Class Codes: H01M 4/8807 Gas diffusion layers
• CPC Class Codes: H01M 4/8828 Coating with slurry or ink
• CPC Class Codes: H01M 4/8878 Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
• CPC Class Codes: H01M 4/92 Metals of platinum group H01M4/94 , H01M4/9058 take precedence
• CPC Class Codes: H01M 4/921 Alloys or mixtures with metallic elements
• CPC Class Codes: H01M 4/926 on carbon or graphite
• CPC Class Codes: H01M 8/1004 characterised by membrane-electrode assemblies [MEA] H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A new type of electrochemical cell is described which can be used for generating electricity, or in an electrolysis mode can produce gases such as hydrogen and oxygen. The cell is constructed from laterally positioned catalyst layers as electrodes with the gap between the catalyst layers having interposed a solid polymer exchange membrane which provides an ion conductive path from the first catalyst layer to the second. The catalyst layers and the electrolyte are in the form of thin films on the surface of a supporting substrate. A plurality of these cells may be formed on the substrate and interconnected electrically forming a network of series and/or parallel connected cells. Means are provided to feed fuel and oxidant to the electrodes as separate gases through channels.

Claims

1. A fuel cell composed of a half-cell comprising a nanoporous catalytic electrode permeable to a fuel gas and connected through parts of the half-cell to an electric load circuit, a negative half-cell comprising a nanoporous catalytic electrode permeable to an oxygen containing gas and its products of the electrodic reaction and connectable through parts of the half-cell to said electrical load circuit of the cell, a cation exchange membrane separating said electrodes, means for deeding said fuel gas to said catalytic electrode of the positive cell and means for feeding oxygen containing gas to said catalytic electrode of the negative half-cell and for exhausting products of the electric reaction, characterized in that each half-cell is formed on a suitable substrate. The substrate could be either semi-insulating silicon or glass or a thin film of Mylar or other suitable material. The mention cell may be controlled by an application integrated specific circuit which is formed at the same time using compatible methods to control said cell and configure electronically said cell.

4. The application integrated specific circuit means for controlling said cell in claim 1 is to control voltage and or current and or reliability of said cell.

12. As in claim 1 for the incorporation or use of the design or specific materials in any type of fuel cell design, including but not limited to PEM, hydrogen, direct methanol, . . .

13. As in claim 1, whereby the electrodes and cell design are constructed on the substrate using lithographic, microwriting or other microprocessing technique.

2. The cell of claim one is characterized in that each half-cell nanoporous material is composed of single wall carbon nanotubes or alternatively single wall carbon nanotubes nucleated on nanoparticles of platinum or alternatively single wall carbon nanotubes nucleated on platinum ruthenium nanoparticles or other metal or non-metal particles.

8. As in claim 2, where the carbon nanotubes are synthesized by any of the current processes (Laser, Arc, CVD) or any future process.

9. As in claim 8, except to include any as-produced or processed or purified carbon nanotube materials.

10. As in claim 2, to include the use of other carbon nanotubes materials in the basic fuel cell design described.

11. As in claim 10, to include any carbon nanotube materials with post synthesis incorporation of catalyst materials by various chemical and mechanical processes.

3. The electrodic thin film material of claim one is platinum metal, platinum ruthenium metal or other suitable metallic material.

6. The method for forming the electrodic thin film material in claim 3 is either through thin film deposition and liftoff or through thin film deposition and etch back.

5. The means for delivering fuel and oxygen to the two half-cells are formed through photolithography in thick photoresist type materials or alternately the pattern is formed in photoresist type materials and the pattern is wet or dry etched into the substrate.

7. The means for delivering fuel and oxygen described in claim 5 is sealed to the substrate material through hot isostatic pressing or through hot isostatic pressing with a thin film of rubber based photoresist disposed onto the channel plate to form a hermetic seal.

14. The benefits of single wall carbon nanotubes also applies to membraneless microchannel fuel cells.