Device and procedure to generate steady compound jets of immiscible liquids and micro/nanometric sized capsules

• US 20040069632A1
• Filed: 07/31/2003
• Published: 04/15/2004
• Est. Priority Date: 01/31/2001
• Status: Abandoned Application

• Current Assignee: Universidad De Malaga, Universidad de Sevilla
• Original Assignee: Universidad De Malaga
• Inventors: Calvo, Alfonso Ganan, Ripoll, Antonio Barrero, Loscertales, Ignacio Gonzalez, Bon, Raul Cortijo
• Application Number:
  US10/631,496
• Publication Number:
  US 20040069632A1
• Time in Patent Office: Days
• US Class Current: 204/450
• CPC Class Codes: A23L 27/00 Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
• CPC Class Codes: A23L 33/10 using additives addition of substantially indigestible substances A23L33/21
• CPC Class Codes: A23P 10/30 Encapsulation of particles, e.g. foodstuff additives
• CPC Class Codes: B01J 13/04 by physical processes, e.g. drying, spraying
• CPC Class Codes: B05B 5/0255 spraying and depositing by electrostatic forces only

Abstract

A device and method for generating drops. The drops are generated by applying an electrical potential to a set of feeding tips which have immiscible or poorly miscible liquids running through them.

Claims

1. - Device to produce steady compound multi-component liquid jets and micro and nanometric sized capsules, consisting of a number N of feeding tips of N liquids, such that the i-th liquid is injected at a flow rate Q_i through the i-th tip, where i varies between 1 and N. The feeding tips are arranged such that the (i−

1)-th liquid surrounds the i-th tip, and each tip is connected to an electrical potential V_i with respect to a reference electrode. The i-th liquid, which flows trough the i-th tip, is immiscible or poorly miscible with liquids (i+1)-th and (i−

1)-th. An electrified capillary liquid meniscus with a noticeable conical shape forms at the feeding points exit in such a way that from the cone apex issues a steady capillary jet made up of the N liquids, such that the (i-1)-th liquid surrounds the i-th liquid, and such that the diameter of the capillary jet has a value between 100 microns and 15 nanometers which is much smaller than the characteristic diameter of the liquid meniscus from which the jet is emitted.

3. - Device to produce steady compound multicomponent liquid jets and micro and nanometric sized capsules of claims 1 and 2, where the diameters of the N feeding tips have values between 0.01 mm and 5 mm.

4. - Device to produce steady compound multicomponent liquid jets and micro and nanometric sized capsules of claims 1-3, where the flow rate of the liquid flowing through the outermost feeding tip has a value between 10⁻

17 m3/s and 10<sup>−

7</sup> m³/s, and where the flow rates of the liquids flowing through each of the other feeding tips have values between 10<sup>−

17</sup> m³/s and 10<sup>−

7</sup> M³/s.

5. - Device to produce steady compound multicomponent liquid jets and micro and nanometric sized capsules of claims 1-4, characterized such that for a separation between a feeding tip and the electrode of reference of a value between 0.01 mm and 5 cm, the applied electric potential has to be between 10 volts and 30 Kvolts.

6. - Device to produce steady compound bi-component liquid jet and micro and nanometric sized capsules of claims 1-5, where the number of feeding points N =2, comprising:

a) A first feeding tip I through which a liquid 1 flows at a rate Q₁ connected to an electric potential V₁.

b) A second feeding tip 2 through which a liquid 2 flows at a rate Q₂ connected to an electric potential V₂

such that the feeding tip 2 is surrounded by liquid 1, and the values of V₁ and V₂ are differential values with respect to a reference electrode connected to a reference potential, such that liquids 1 and 2 are immiscible or poorly miscible, forming at the exit of the feeding tips an electrified capillary liquid meniscus with a noticeable conical shape, whose apex issues an steady capillary jet formed by both liquids 1 and 2, such that liquid 1 completely surrounds liquid 2, and such that the diameter of the jet has a value between 100 microns and 15 nanometers which is smaller than the characteristic diameter of the electrified capillary liquid meniscus from which it is emitted.

7. - Procedure to generate steady compound multicomponent liquid jets and micro and nanometric sized capsules of claims 1, 3, 4 and 5, such that an i-th liquid at a flow rate Q_{i flows} through the i-th tip, where i varies between 1 and N, and each tip is connected to an electrical potential V_i with respect to a reference electrode. The i-th liquid, which flows trough the i-th tip, is immiscible or poorly miscible with liquids (i+1)-th and (i−

1)-th. An electrified capillary liquid meniscus with a noticeable conical shape forms at the feeding points exit in such a way that from the cone apex issues a steady capillary jet made up of the N liquids, such that the (i−

1)-th liquid surrounds the i-th liquid, and such that the diameter of the capillary jet has a value between 100 microns and 15 nanometers which is much smaller than the characteristic diameter of the liquid meniscus from which the jet is emitted. The spontaneous break up of the jet thus forming capsules with diameters between 100 microns and 15 nanometers.

9. - Multicomponent and/or multilayered capsules with diameters comprised between 1000 microns and 15 nanometers, resulting from the break up of the jet generated by the procedures described in claims 7 and 8.

2. - Device to produce steady compound multicomponent liquid jets and micro and nanometric sized capsules, consisting of a number N of feeding tips of N liquids, such that the i-th liquid is injected at a flow rate Q_i through the i-th tip, where i varies between 1 and N. The feeding tips are arranged such that liquid 1 surrounds all the other feeding points. Liquid 1 is immiscible or poorly miscible with the rest of liquids. Each feeding point is connected to an electrical potential V_i, where i varies from 1 to N, respect to a reference electrode. An electrified capillary liquid meniscus with a noticeable conical shape forms at the feeding points exit in such a way that from the cone apex issues a steady capillary jet made up of the N liquids, so that liquid 1 surrounds the rest of liquids, and such that the diameter of this capillary jet has a value between 100 microns and 15 nanometers which is much smaller than the characteristic diameter of the electrified liquid meniscus from which the jet is emitted.

8. - Procedure to generate steady compound multicomponent liquid jets and micro and nanometric sized capsules of claims 2, 3, 4 and 5, such that an i-th liquid at a flow rate Q_{i flows} through the i-th tip, where i varies between 1 and N. The feeding tips are arranged such that liquid 1 surrounds all the other feeding points. Liquid 1 is immiscible or poorly miscible with the rest of liquids. Each feeding point is connected to an electrical potential V_i, where i varies from 1 to N, respect to a reference electrode. An electrified capillary liquid meniscus with a noticeable conical shape forms at the feeding points exit in such a way that from the cone apex issues a steady capillary jet made up of the N liquids, so that liquid 1 surrounds the rest of liquids, and such that the diameter of this capillary jet has a value between 100 microns and 15 nanometers which is much smaller than the characteristic diameter of the electrified liquid meniscus from which the jet is emitted. The spontaneous break up of the jet thus forming capsules with diameters between 100 microns and 15 nanometers.