Gas sensor and method for use thereof

• US 20040094416A1
• Filed: 11/15/2002
• Published: 05/20/2004
• Est. Priority Date: 11/15/2002
• Status: Active Grant

• Current Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Original Assignee: Delphi Technologies, Inc. (BorgWarner Incorporated)
• Inventors: Bloink, Raymond L., Lin, Yingjie, Wang, Da Yu, Symons, Walter T., Chen, David K., Polikarpus, Kaius K., Srivastava, Devesh
• Granted Patent: US 7,048,844 B2
• Time in Patent Office: Days
• US Class Current: 204/426
• CPC Class Codes: G01N 27/419 Measuring voltages or currents with a combination of oxygen pumping cells and oxygen concentration cells

Abstract

A sensor comprises: a pump cell comprising an inner pump electrode, an outer pump electrode, a pump cell electrolyte layer interposed between the inner pump electrode and the outer pump electrode and a cell isolation layer disposed on the inner pump electrode on a side opposite the pump cell electrolyte, wherein the outer electrode is in fluid communication with a reducing gas. A reference cell is in operable communication with the pump cell, the reference cell comprising an outer reference electrode and an inner reference electrode, and a reference cell electrolyte interposed between the outer reference electrode and the inner reference electrode. A diffusion limiting material flanks both sides of a chamber formed between the cell isolation layer and a cell separation layer, wherein the cell separation layer comprises a via coaxial and in fluid communication with the inner pump electrode, the diffusing limiting material, and the outer reference electrode, and wherein the diffusion limiting material has a gas permeability such that the limiting current of oxygen in air is about 0.05 mA to about 5 mA per cm² of pump electrode area.

Claims

1. A sensor comprising:

a pump cell comprising;

an inner pump electrode;

an outer pump electrode;

a pump cell electrolyte layer interposed between the inner pump electrode and the outer pump electrode; and

a cell isolation layer disposed on the inner pump electrode on a side opposite the pump cell electrolyte,

a reference cell in operable communication with the pump cell, the reference cell comprising an outer reference electrode and an inner reference electrode, and a reference cell electrolyte interposed between the outer reference electrode and the inner reference electrode; and

a diffusion limiting material flanking both sides of a chamber formed between the cell isolation layer and a cell separation layer, wherein the cell separation layer comprises a via coaxial and in fluid communication with the inner pump electrode, the diffusing limiting material, and the outer reference electrode, and wherein the diffusion limiting material has a gas permeability such that the limiting current of oxygen in air is about 0.05 mA to about 5 mA per cm² of pump electrode area.

2. The sensor of claim 1, wherein the diffusion limiting material comprises aluminum oxide having a first particle size distribution of about 4.5 micrometers to about 5.5 micrometers and a second particle size distribution of about 0.3 micrometers to about 0.7 micrometers.

3. The sensor of claim 2, wherein the aluminum oxide comprises 45 wt % to about 55 wt % of each of the aluminum oxide having the first particle size and the aluminum oxide having the second particle size, based upon the total weight of the aluminum oxide.

4. The sensor of claim 1, further comprising a porous protection layer in fluid communication with the outer pump electrode.

5. The sensor of claim 1, wherein the inner pump electrode, the outer pump electrode, the inner reference electrode, and the outer reference electrode individually includes a first material comprising platinum, palladium, gold, osmium, rhodium, iridium, ruthenium, zirconium, yttrium, cerium, calcium, aluminum, alloys of the foregoing, oxides of the foregoing, or combinations comprising at least one of the foregoing first materials.

6. The sensor of claim 5, wherein the inner pump electrode comprises an additional material comprising platinum, palladium, rhodium, iridium, osmium, magnesium, ruthenium, tantalum, lanthanum, strontium, zirconium, yttrium, cerium, nickel, copper, aluminum, iron, alloys of the foregoing, oxides of the foregoing, or comprising at least one of the foregoing additional materials.

7. The sensor of claim 6, wherein the inner pump electrode comprises rhodium, copper oxide/aluminum oxide, or lanthana/strontia/iron oxide.

8. The sensor of claim 1, further comprising a heater for maintaining the reference cell and sail pump cell at a temperature sufficient to facilitate an electrochemical reaction.

9. The sensor of claim 1, further comprising means for analysing a limiting current produced by the pump cell.

10. The sensor of claim 9, wherein the limiting current comprises about 0.005 to about 0.20 milliamps.

11. A method for measuring reducing gas concentration in a gas comprising:

exposing a sensor to air, wherein the sensor comprises a pump cell, a reference cell, and a cell separation layer interposed between the pump cell and the reference cell, wherein the pump cell comprises an outer pump electrode exposed to the gas, an inner pump electrode in operable communication with a diffusion limiting material by means of a cell isolation layer, and a pump cell electrolyte interposed between the inner pump electrode and the outer pump electrode, wherein the reference cell comprises an outer reference electrode in operable communication with the diffusion limiting material, an inner reference electrode in fluid communication with a reference gas source and a reference electrolyte interposed between the outer reference electrode and the inner reference electrode, and wherein the diffusion limiting material comprises a gas permeability such that the limiting current of oxygen in air is about 0.05 mA to about 5 mA per cm² of pump electrode area.

applying a voltage to the outer pump electrode and the inner pump electrode to form a limiting current;

diffusing oxygen molecules and reducing gases across the diffusion limiting material;

generating an electromotive force signal between the outer reference electrode and the inner reference electrode;

adjusting the pump current to maintain the electromotive force signal at a predetermined value, wherein the limiting current is proportional to the reducing gases.

12. The method of claim 11, wherein the sensor operates at a temperature of about 300°

C. to about 700°

C.

13. The method of claim 12, wherein the sensor operates a temperature less than or equal to 500°

C.

14. The method of claim 11, wherein the limiting current comprises about 0.005 to about 0.20 milliamps.

15. The method of claim 11, wherein the limiting current is less than or equal to about 0.10 milliamps.

16. The method of claim 11, wherein the diffusion limiting material comprises aluminum oxide having a first particle size distribution of about 4.5 micrometers to about 5.5 micrometers and a second particle size distribution of about 0.3 micrometers to about 0.7 micrometers.

17. The sensor of claim 16, wherein the aluminium oxide comprises 45 wt % to about 55 wt % of each of the aluminum oxide having the first particle size and the aluminum oxide having the second particle size, based upon the total weight of the aluminum oxide.

18. The method of claim 11, wherein the gas comprises a hydrocarbon, hydrogen, carbon dioxide, carbon monoxide, and combinations comprising at least one of the foregoing.