Method for removing metals from acid mine drainage
First Claim
1. A method for removing metals from metal-containing acidic mine wastewater, comprising the steps of:
- (a) dispersing lignin derivatives in said wastewater;
(b) dispersing an alkali coagulant in said wastewater, thereby increasing the pH of said wastewater;
(c) after steps (a) and (b), dispersing an alkaline composition in the wastewater, thereby increasing the pH of said wastewater and causing the formation of a floc; and
(d) separating metal-containing flocs formed in said wastewater from said wastewater.
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Accused Products
Abstract
A method for removing metal contaminants from acidic mine wastewater using lignin derivatives, such as lignosulfonates and kraft lignin, an alkali coagulant, such as a lime compound, and an alkaline composition for increasing the pH. The lignin derivatives are dispersed in the wastewater and the coagulant is added, increasing the pH to about 4.5-8.5 and causing the formation of a floc. The alkaline composition is then added to bring the pH to about 9 to 10, causing the further formation of a floc. Optionally, air oxidation is carried out, reducing the pH to about 8.1-8.6. Optionally, a ferric or ferrous salt may also be added. The flocs comprise metal-lignin colloids, metal hydroxides and metal salts. The flocs coagulate to form a sludge. Optionally, fly ash or diatomaceous earth may be added to increase the density and stability of the sludge. The sludge that is formed contains the metals and is separated from the treated water by filtration.
28 Citations
35 Claims
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1. A method for removing metals from metal-containing acidic mine wastewater, comprising the steps of:
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(a) dispersing lignin derivatives in said wastewater;
(b) dispersing an alkali coagulant in said wastewater, thereby increasing the pH of said wastewater;
(c) after steps (a) and (b), dispersing an alkaline composition in the wastewater, thereby increasing the pH of said wastewater and causing the formation of a floc; and
(d) separating metal-containing flocs formed in said wastewater from said wastewater. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35)
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Specification