Phase difference plate comprising polymer film containing compound having rod- shaped molecular structure

• US 20040096594A1
• Filed: 09/12/2003
• Published: 05/20/2004
• Est. Priority Date: 03/14/2001
• Status: Active Grant

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fujifilm Holdings Corporation
• Inventors: Takeuchi, Hiroshi, Fujii, Takamichi, Sata, Hiroaki, Kawanishi, Hiroyuki
• Granted Patent: US 7,060,333 B2
• Time in Patent Office: Days
• US Class Current: 428/1.2
• CPC Class Codes: C09K 2323/02 Alignment layer characterised by chemical composition
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: C09K 2323/035 Ester polymer, e.g. polycarbonate, polyacrylate or polyester
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001
• CPC Class Codes: G02F 1/133638 Waveplates, i.e. plates with a retardation value of lambda/n

Abstract

A phase difference plate which comprises one sheet of polymer film containing a compound having a rod-shaped molecular structure and exhibiting a maximum absorption wavelength (λmax) of less than 250 nm in an ultraviolet spectrum of its solution and which exhibits a retardation value as measured at a wavelength of 450 nm (Re450) of 60 to 135 nm and a retardation value as measured at a wave-length of 590 nm (Re590) of 100 to 170 nm, where the relationship: Re590-Re450≧2 nm is satisfied. The phase difference plate functions as a λ/4 plate.

Claims

1. A phase retarder comprising a single polymer film which contains a rod-like compound exhibiting a maximum absorption wavelength (λ

max) of shorter than 250 nm in an ultraviolet absorption spectrum measured in a form of a solution of the compound, wherein the film has a retardation value of Re450 in the range of 60 to 135 nm measured at a wavelength of 450 nm, and a retardation value of Re590 in the range of 100 to 170 nm measured at a wavelength of 590 nm, said Re450 and Re590 satisfying a condition of Re590-Re450≧

2 nm.

2. The phase retarder as defined in claim 1, wherein the polymer film is made of a cellulose ester.

3. The phase retarder as defined in claim 2, wherein the cellulose acetate has an acetic acid content in the range of 45.0 to 62.5%.

4. The phase retarder as defined in claim 1, wherein the polymer film is a film stretched by 3 to 100%.

5. The phase retarder as defined in claim 1, wherein a refractive index of nx along the slow axis in the film plane, a refractive index of ny in the direction perpendicular to the slow axis in the film plane and a refractive index of nz along the depth of the film satisfy a condition of 1≦

(nx−

nz)/(nx−

ny)≦

2.

6. The phase retarder as defined in claim 1, wherein the rod-like compound has a linear molecular structure.

7. The phase retarder as defined in claim 1, wherein the rod-like compound behaves as liquid crystal.

8. The phase retarder as defined in claim 1, wherein the polymer film contains the rod-like compound in an amount of 0.01 to 20 weight parts based on 100 weight parts of the polymer film.

9. The phase retarder as defined in claim 1, wherein the rod-like compound is represented by the following formula (I):

Ar¹—

L¹—

Ar² 

 

(I)

[in which each of Ar¹ and Ar² is independently an aromatic group; and

L¹ is a divalent linking group selected from the group consisting of an alkylene group, an alkenylene group, an alkynylene group, a divalent saturated heterocyclic group, —

O—

, —

CO— and

combinations thereof].

10. The phase retarder as defined in claim 9, wherein the rod-like compound is represented by the following formula (II):

Ar¹—

L²—

X—

L³—

Ar² 

 

(II)

[in which each of Ar¹ and Ar² is independently an aromatic group;

each of L² and L³ is independently a divalent linking group selected from the group consisting of an alkylene group, —

O—

, —

CO— and

combinations thereof; and

X is 1,4-cyclohexylene, vinylene or ethynylene].

11. A phase retarder comprising a single polymer film which contains a rod-like compound exhibiting a maximum absorption wavelength (λ

max) of shorter than 250 nm in an ultraviolet absorption spectrum measured in a form of a solution of the compound, wherein the film has a retardation value of Re450 in the range of 120 to 270 nm measured at a wavelength of 450 nm, and a retardation value of Re590 in the range of 200 to 340 nm measured at a wavelength of 590 nm, said Re450 and Re590 satisfying a condition of Re590-Re450≧

2 nm.

12. A circularly polarizing plate comprising a phase retarder and a polarizing membrane, said polarizing membrane having a polarizing axis essentially at an angle of 45°

to a slow axis in a plane of the phase retarder, and said phase retarder comprising a single polymer film which contains a rod-like compound exhibiting a maximum absorption wavelength (λ

max) of shorter than 250 nm in an ultraviolet absorption spectrum measured in a form of a solution of the compound, wherein the film has a retardation value of Re450 in the range of 60 to 135 nm measured at a wavelength of 450 nm, and a retardation value of Re590 in the range of 100 to 170 nm measured at a wavelength of 590 nm, said Re450 and Re590 satisfying a condition of Re590-Re450≧

2 nm.

13. A liquid crystal display of a reflection type comprising a liquid crystal cell, a circularly polarizing plate and a reflection board in this order, wherein the circularly polarizing plate is defined in claim 12, and wherein the polymer film is placed on a side of the liquid crystal cell.

14. A touch panel comprising two transparent electrically conductive substrates each of which has a transparent electrically conductive membrane on one surface, said two substrates being so arranged that the surfaces on which the membrane is provided face to each other, wherein at least one of the substrates is a λ

/4 plate or is laminated on a λ

/4 plate, said λ

/4 plate comprising a single polymer film which contains a rod-like compound exhibiting a maximum absorption wavelength (λ

max) of shorter than 250 nm in an ultraviolet absorption spectrum measured in a form of a solution of the compound, wherein the film has a retardation value of Re450 in the range of 60 to 135 nm measured at a wavelength of 450 nm, and a retardation value of Re590 in the range of 100 to 170 nm measured at a wavelength of 590 nm, said Re450 and Re590 satisfying a condition of Re590-Re450≧

2 nm.

15. The touch panel as defined in claim 14, wherein the transparent electrically conductive membrane has a surface resistance of not more than 1×

10⁴ Ω

per square.

16. The touch panel as defined in claim 14, wherein a polarizing membrane is further laminated on the polymer film so that the polarizing axis of the polarizing membrane is placed essentially at the angle of 45°

to the slow axis in the plane of the polymer film.

17. A liquid crystal display of reflection type comprising a touch panel and a liquid crystal cell of reflection type, wherein the touch panel is that defined in claim 14.

18. The liquid crystal display of reflection type as defined in claim 17, wherein the touch panel and the liquid crystal cell of reflection type hold one substrate in common, and transparent electrode layers are provided on each surfaces of the substrate.

19. A cellulose ester film containing a compound represented by the following formula (II):

Ar¹—

L²—

X—

L³—

Ar² 

 

(II)

[in which each of Ar¹ and Ar² is independently an aromatic group;

each of L² and L³ is independently a divalent linking group selected from the group consisting of an alkylene group, —

O—

, —

CO— and

combinations thereof; and

X is 1,4-cyclohexylene, vinylene or ethynylene].

20. The cellulose ester film as defined in claim 19, wherein the compound represented by the formula (II) behaves as liquid crystal.