Process for applying a polyurethane dispersion based foam to an article

• US 20040109992A1
• Filed: 12/09/2002
• Published: 06/10/2004
• Est. Priority Date: 12/09/2002
• Status: Abandoned Application

• Current Assignee: Douglas P. White, James G. Kennedy, Michael Y. Gribble, Paulus C.J.M. Van Bellegem, Randal E. Autenrieth
• Original Assignee: Douglas P. White, James G. Kennedy, Michael Y. Gribble, Paulus C.J.M. Van Bellegem, Randal E. Autenrieth
• Inventors: Autenrieth, Randal E., Van Bellegem, Paulus C.J.M., Gribble, Michael Y., Kennedy, James G., White, Douglas P.
• Application Number:
  US10/314,854
• Publication Number:
  US 20040109992A1
• Time in Patent Office: Days
• US Class Current: 428/315.9
• CPC Class Codes: B29C 44/569 Shaping and joining components with different densities or hardness
• CPC Class Codes: B32B 2038/0084 Foaming
• CPC Class Codes: B32B 2262/0276 Polyester fibres
• CPC Class Codes: B32B 2266/0278 Polyurethane
• CPC Class Codes: B32B 2305/022 Foam
• CPC Class Codes: B32B 2305/18 Fabrics, textiles
• CPC Class Codes: B32B 2307/3065 Flame resistant or retardant, fire resistant or retardant
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: B32B 5/245 another layer next to it being a foam layer
• CPC Class Codes: D06N 3/0043 characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers foraminous structure obtained by stretching D06N3/0029
• CPC Class Codes: D06N 3/14 with polyurethanes
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/24998 Composite has more than two layers
• CPC Class Codes: Y10T 442/20 Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
• CPC Class Codes: Y10T 442/2803 Polymeric coating or impregnation from a silane or siloxane not specified as lubricant or water repellent

Abstract

Disclosed is a process for making a two or more component foam composite obtained by adhesion of a polyurethane foam onto a substrate comprising the steps of frothing an aqueous polyurethane formulation; applying the froth to a substrate and drying the froth into a foam wherein the foam has a dry density of 35 kg/m³ to 160 kg/m³ (2.2-10 lbs/cft). The process allows the production of foam backed textiles without the need for a flame lamination step or the need for an adhesive layer between the textile and the foam layer and is optionally optimized for superior handling properties for covering polyurethane molded foam cushions.

Claims

1. A process for making a two or more component foam composite obtained by adhesion of a polyurethane foam onto a substrate comprising the steps of frothing an aqueous polyurethane formulation;

applying the froth to a substrate and drying the froth into a foam wherein the foam has a dry density of 35 kg/m³ to 160 kg/m³ (2.2-10 lbs/cft) wherein the polyurethane formulation is prepared from a polyurethane dispersion, a frothing surfactant and a stabilizing surfactant.

2. The process of claim 1 wherein the polyurethane dispersion is prepared by admixing water, a chain extender, a sufactant, a polyurethane prepolymer under mixing conditions sufficient to prepare a stable dispersion.

3. The process of claim 2 wherein the surfactant is an anionic surfactant.

4. The process of claim 1 wherein the frothing surfactant is a carboxylic acid salt.

5. The process of claim 4 wherein the frothing surfactant is one or more surfactants of the formula:

RCO₂⁻

X⁺ 

 

(Formula

     1),

where R represents a C₈-C₂₀ linear or branched alkyl, which can contain an aromatic, a cycloaliphatic, or heterocycle; and

X is a counter ion.

6. The process of claim 5 wherein X⁺ is Na, K, or an amine.

7. The process of claim 6 wherein X⁺ is NH₄⁺.

8. The process of claim 4 wherein the surfactant is present in an amount of 1 to 15 parts dry weight surfactant per 100 parts of polyurethane dispersion solids.

9. The process of claim 7 wherein the surfactant is ammonium stearate.

10. The process of claim 1 wherein the stabilizer surfactant is an anionic surfactant based on at least one sulfonic acid salt.

11. The process of claim 10 wherein the stabilizing surfacting is one or more surfactants of the formula:

R²OOCCH₂CH(SO₃⁻

M⁺)COOR²  

 

(Formula

     2)

where R² at each occurrence is independently a C₆-C₂₀ linear or branched alkyl, which can contain an aromatic or a cycloaliphatic and M is a counter ion.

12. The process of claim 11 wherein M is ammonia or a member from Group 1A of the Periodic Table.

13. The process of claim 12 wherein the surfactant is a salt of of octadecyl sufosuccinate.

14. The process of claim 11 wherein the stabilizing surfactant is present in an amount of 0.01 to 10 parts of dry surfactant per 100 part of polyurethane dispersion solids.

15. The process of claim 1 wherein the formulation contains a flame retardant such that the foam composite meets combustion modification test FMVSS 302.

16. The process of claim 15 wherein the flame retardant is a phosphonate ester, phospate ester, halogenaed phosphate ester, dehydratable flame retardant or a mixture thereof.

17. The process of claim 16 wherein the flame retardant is a dehydratable flame retardant selected from from alkali silicates, zeolites or other hydrated phosphates, borosilicates or borates, aluminum hydroxides, cyanuric acid derivatives, phenol, melamine or urea formaldehyde resins, graphites and mica which are capable of swelling, vermiculites and perlites.

18. The process of claim 17 wherein the flame retardant is retardant is an aluminum hydroxide, aluminum hydrated oxides, hydrated alumina, or a mixture thereof.

19. The process of claim 17 wherein the flame retardant is present in an amout of 5 to 120 parts per 100 parts of dispersion solids.

20. The process of claim 1 wherein the substrate is selected from a textile, plastic film, synthetic sheet or paper.

21. The process of claim 20 wherein the substrate is a polyvinyl sheet.

22. The process of claim 20 wherein the substrate is a textile.

23. A textile fabric-flexible polyurethane composite comprised of a woven fabric, the fabric having been coated on at least one side with a flexible foam having a dry density of 35 kg/m³ to 160 k/m³ where the foam is derived from a frothed polyurethane composition comprising a polyurethane dispersion, surfactants and other additives known per se for producing such flexible polyurethane foams.

24. The composite of claim 23 wherein the surface properties of the foam are modified by inclusion of a wax in the frothed polyurethane composition at a preferred level of 1.0 to 10.0 parts per 100 parts of dispersion solids.

25. The composite of claim 23 wherein the surface properties of the foam opposite the surface attached to the fabric is modified by application of a silicone polymer, preferably as a water based emulsion or dispersion, through a spray process or a roller coating process.

26. The composite of claim 23 wherein a light weight non-woven polyethylene is applied to the flexbile foam by a heat laminating process at pressures and temperatures which do not negatively affect the textile or foam in producing the 3 component composite.