Impregnated fiber precursors and methods and systems for producing impregnated fibers and fabricating composite structures

• US 20040119188A1
• Filed: 12/20/2002
• Published: 06/24/2004
• Est. Priority Date: 12/20/2002
• Status: Abandoned Application

• Current Assignee: Orbital ATK Inc. (Northrop Grumman Corporation)
• Original Assignee: Orbital ATK Inc. (Northrop Grumman Corporation)
• Inventors: Lowe, Kenneth A.
• Application Number:
  US10/327,688
• Publication Number:
  US 20040119188A1
• Time in Patent Office: Days
• US Class Current: 264/131
• CPC Class Codes: B29B 15/125 by dipping
• CPC Class Codes: B29B 15/127 by spraying
• CPC Class Codes: B29C 53/60 using internal forming surfaces, e.g. mandrels
• CPC Class Codes: B29C 70/50 for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]

Abstract

Methods, apparatus, and systems for impregnation of fibers and their use in the fabrication of composite structures using two or more different but cooperative matrix components applied to separate tows of dry fibers to form single component prepregs. A single tow of dry fibers may also be impregnated with one matrix component and subsequently with at least one other matrix component. The first matrix component may predominantly comprise a substantially uncatalyzed component and the at least one other matrix component may predominantly comprise a substantially unreacted hardener component. Until the at least two components are combined, the tows impregnated with the at least two different matrix components have virtually infinite shelf life at room temperature. Only when at least two differently impregnated tows are combined during the composite fabrication process is an overall stoichiometrically correct matrix composition obtained to enable the final curing and hardening of the composite part.

Claims

1. A method of forming a fiber system for use in the fabrication of composite structures, the method comprising:

providing a matrix precursor in the form of a first matrix component and at least a second, different but cooperative matrix component, the first and at least a second matrix components formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

providing at least two tows of fibers;

applying to at least a first tow of the at least two tows of fibers a first matrix component comprising a substantially uncatalyzed resin component; and

applying to at least a second tow of the at least two tows of fibers at least a second matrix component comprising a substantially unreacted hardener component.

2. The method of claim 1, further comprising selecting the first matrix component to comprise a substantially uncatalyzed resin component and the at least a second matrix component to comprise a substantially unreacted hardener component.

3. The method of claim 2, further comprising formulating the first matrix component to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and formulating the at least a second matrix component to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

4. The method of claim 1, further comprising selecting the fibers from glass fibers, carbon fibers, and organic fibers.

5. The method of claim 1, further including selecting the matrix components from polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides and phenolic triazines and combinations thereof.

6. A method of fabricating a composite structure, comprising:

providing a matrix precursor in the form of a first matrix component and at least a second, different but cooperative matrix component, the first and the at least a second matrix components formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

providing at least two tows of fibers;

applying to at least a first tow of the at least two tows of dry fibers the first matrix component;

applying to at least a second tow of the at least two tows of dry fibers the at least a second matrix component;

commingling the at least first and second tows to which the first matrix component and the at least a second matrix component have been applied into at least one consolidated tow; and

using the at least one consolidated tow to form a composite structure.

7. The method of claim 6, further comprising selecting the first matrix component to comprise a substantially uncatalyzed resin component and the at least a second matrix component to comprise a substantially unreacted hardener component.

8. The method of claim 7, further comprising formulating the first matrix component to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and formulating the at least a second matrix component to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

9. The method of claim 7, further comprising selecting the fibers from glass fibers, carbon fibers, and organic fibers.

10. The method of claim 6 further comprising, before commingling the at least first and second tows to which the first matrix component and the at least a second matrix component have been applied into at least one consolidated tow, storing at least one of the at least first and second tows off-line on a storage spool before forming the composite structure.

11. The method of claim 10, further including storing the at least one of the at least first and second tows at ambient temperature.

12. The method of claim 6, further including selecting the matrix components from polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, and phenolic triazines and combinations thereof.

13. A method of fabricating a composite structure, comprising:

providing a matrix precursor in the form of a first matrix component and at least a second, different but cooperative matrix component, the first and the at least a second matrix components formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

providing at least one tow of dry fibers;

applying to the at least one tow of dry fibers one of the first and the at least a second matrix components to form at least one high-sized tow of fibers;

applying another of the first and the at least a second matrix components to the at least one high-sized tow of fibers to provide a tow having commingled first and second matrix components; and

using the tow having the commingled first and at least a second matrix components to form a composite structure.

14. The method of claim 13, further comprising selecting the first matrix component to comprise a substantially uncatalyzed resin component and the at least a second matrix component to comprise a substantially unreacted hardener component.

15. The method of claim 14, further comprising formulating the first matrix component to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and formulating the at least a second matrix component to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

16. The method of claim 13 further comprising, before applying another of the first and the at least a second matrix components to the at least one high-sized tow of fibers, storing the at least one high-sized, pre-impregnated tow of fibers off-line on a storage spool.

17. The method of claim 16, further comprising storing the at least one high-sized tow of fibers at room temperature.

18. The method of claim 14, further comprising formulating the one of the first and the at least a second matrix components to have a concentration level ranging from about 1% up to about 40% by weight.

19. The method of claim 13, further comprising selecting the fibers from glass fibers, carbon fibers, and organic fibers.

20. The method of claim 13, further including selecting the matrix components from polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides and phenolic triazines and combinations thereof.

21. An apparatus for forming a fiber system for use in the fabrication of composite structures, comprising:

a source of a first matrix component;

at least another source of at least a second, different but cooperative matrix component;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

a first impregnation assembly configured to receive at least one tow of fibers, to apply the first matrix component to the at least first tow of fibers and to deliver the at least first tow of fibers to at least one storage spool after the application of the first matrix component; and

at least a second impregnation assembly configured to receive at least a second tow of fibers, to apply the at least a second matrix component to the at least second tow of fibers and to deliver the at least a second tow of impregnated fibers to at least a second storage spool after the application of the at least a second matrix component.

22. The apparatus of claim 21, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

23. The apparatus of claim 22, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

24. The apparatus of claim 21, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

25. The apparatus of claim 21, wherein the first and the at least a second matrix components are comprised of epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.

26. The apparatus of claim 21, further including a room temperature storage environment for the spools.

27. An apparatus for use in fabricating a composite structure, comprising:

a source of a first matrix component;

at least another source of at least a second, different but cooperative matrix component;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

a first assembly configured to receive at least a first tow of fibers, to apply the first matrix component to the at least first tow of fibers;

at least a second assembly configured to receive at least a second tow of fibers, to apply the at least a second matrix component to the at least a second tow of fibers;

a commingling assembly configured to commingle a plurality of tows;

a forming assembly configured to receive at least one commingled fiber from the commingling assembly and apply the at least one commingled fiber to form a composite structure.

28. The apparatus of claim 27, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

29. The apparatus of claim 28, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

30. The apparatus of claim 27, further comprising at least two storage spools, each configured to store thereon at least one tow having the first or the at least a second component applied thereto prior to delivery to the commingling assembly.

31. The apparatus of claim 30, further comprising an ambient temperature spool storage environment.

32. The apparatus of claim 27, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

33. The apparatus of claim 27, wherein the first and the at least a second matrix components are comprised of polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.

34. An apparatus for use in fabricating a composite structure, comprising:

a source of a first matrix component;

at least another source of at least a second, different but cooperative matrix component;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

a first assembly configured to receive at least one tow of fibers, to apply to the at least first tow of fibers a high-sizing matrix comprising one of the first and the at least a second matrix components to form at least one high-sized tow of fibers;

at least a second assembly configured to receive the at least first high-sized tow of fiber and to apply at least another of the first and the at least a second matrix components thereto; and

a fabrication assembly configured to receive the at least one high-sized tow of fiber having the first and second matrix components applied thereto and to apply the at least one high-sized tow of fiber having the first and the at least a second matrix components applied thereto to form a composite structure.

35. The apparatus of claim 34, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

36. The apparatus of claim 35, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

37. The apparatus of claim 34, further comprising at least one storage spool configured to store the at least first high-sized tow of fibers having the one of the first and the at least a second matrix components applied thereto before application of the at least another of the first and the at least a second matrix components.

38. The apparatus of claim 37, further comprising an ambient temperature storage spool environment.

39. The apparatus of claim 35, wherein the one of the first and the at least a second matrix components has a concentration level ranging from about 1% up to about 40% by weight.

40. The apparatus of claim 34, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

41. The apparatus of claim 34, wherein the first and the at least a second matrix components are comprised of polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.

42. A system for producing a matrix precursor having an extended shelf life, comprising:

a source of a first matrix component;

at least another source of at least a second, different but cooperative matrix component;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

at least two fiber sources;

at least two fiber storage elements, each configured for storage of at least one tow of fibers;

a first assembly configured to apply the first matrix component from the source to fibers from at least one of the at least two fiber sources and to deliver fibers having the first matrix component applied thereto to a fiber storage element; and

at least a second assembly configured to apply the at least a second matrix component from the at least another source to fibers from at least one of the at least two fiber sources and to deliver fibers having the at least a second component applied thereto to a fiber storage element.

43. The system of claim 42, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

44. The system of claim 43, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

45. The system of claim 42, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

46. The apparatus of claim 43, wherein the first and the at least a second matrix components are comprised of polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.

47. The system of claim 42, further comprising an ambient temperature fiber storage element environment.

48. A composite structure fabrication system comprising:

a source of a first matrix component;

at least another source of at least a second, different but cooperative matrix component;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

at least two fiber sources;

at least two fiber storage elements, each configured for storage of at least one tow of fibers;

a first assembly configured to apply the first matrix component from the source to fibers from at least one of the at least two fiber sources and to deliver fibers having the first matrix component applied thereto to a fiber storage element; and

at least a second assembly configured to apply the at least a second matrix component from the at least another source to fibers from at least one of the at least two fiber sources and to deliver fibers having the at least a second component applied thereto to another fiber storage element;

an assembly configured to commingle fibers having respectively applied thereto the first matrix component and the second matrix component into at least one consolidated tow; and

a forming assembly configured to receive at least one consolidated tow and apply the at least one consolidated tow to form a composite structure.

49. The system of claim 48, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

50. The system of claim 49, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

51. The apparatus of claim 48, further comprising at least two fiber storage elements, each configured to store thereon at least one group of fibers having the first or the at least a second component applied thereto prior to delivery to the commingling assembly.

52. The system of claim 51, further comprising an ambient temperature fiber storage element environment.

53. The system of claim 48, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

54. The system of claim 48, wherein the first and the at least a second matrix components are comprised of polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.

55. A composite structure fabrication system, comprising:

a source of a first matrix component;

at least another source of at least a second, different but cooperative matrix component;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden;

at least one source of fibers;

a first assembly configured to receive fibers from the at least one source of fibers, to apply to the fibers a high-sizing matrix comprising one of the first and the at least a second matrix components to form at least one high-sized tow of fibers;

at least a second assembly configured to receive the at least first high-sized tow of fiber and to apply another of the first and the at least a second matrix components thereto; and

a commingling assembly configured to receive the at least one high-sized tow of fiber having the first and the at least a second matrix components applied thereto and to commingle the first and the at least a second matrix components; and

a fabrication assembly configured to receive the at least one high-sized tow of fiber having the first and the at least a second matrix components applied thereto and to apply the at least one high-sized tow of fiber having the first and the at least a second matrix components applied thereto to form a composite structure.

56. The system of claim 55, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

57. The system of claim 56, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

58. The system of claim 55, further comprising an ambient temperature fiber storage element environment.

59. The system of claim 55, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

60. The system of claim 55, wherein the first and the at least a second matrix components are comprised of polyesters, epoxies, anhydrides, amines, Lewis acid-catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.

61. The system of claim 55, further comprising at least one storage element configured to store the at least first high-sized tow of fibers having the one of the first and the at least a second matrix components applied thereto before application of the at least another of the first matrix and the at least a second matrix components.

62. The system of claim 61, further comprising an ambient temperature storage element environment.

63. The system of claim 55, wherein the one of the first and the at least a second matrix components has a concentration level ranging from about 1% up to about 40% by weight.

64. A fiber system precursor for use in fabrication of composite structures, comprising:

at least a first tow of fibers having a first matrix component applied thereto; and

at least a second tow of fibers having at least a second, different but cooperative matrix component applied thereto;

wherein the first and the at least a second matrix components are formulated to form, when commingled, a stoichiometrically effective matrix enabled to cure and harden.

65. The system of claim 64, wherein the first matrix component comprises a substantially uncatalyzed resin component and the at least a second matrix component comprises a substantially unreacted hardener component.

66. The system of claim 65, wherein the first matrix component is formulated to comprise an amount of the resin component and, optionally, an amount of the hardener ranging from 0% of the hardener component to an adduct of the resin and the hardener components in less than stoichiometric proportions required to enable the matrix to harden and cure, and the at least a second matrix component is formulated to comprise an amount of the hardener component and, optionally, an amount of the resin component ranging from 0% of the resin component to an adduct of the hardener and the resin components in less than stoichiometric proportions required to enable the matrix to harden and cure.

67. The system of claim 64, wherein the fibers comprise glass fibers, carbon fibers, or organic fibers.

68. The system of claim 64, wherein the first and the at least a second matrix components are comprised of polyesters, epoxies, anhydrides, amines, Lewis acid catalysts, imidazoles, cyanate esters, bismaleimides, or phenolic triazines and combinations thereof.