Portable pH detector

• US 20040132204A1
• Filed: 01/03/2003
• Published: 07/08/2004
• Est. Priority Date: 01/03/2003
• Status: Abandoned Application

• Current Assignee: National Yunlin University of Science and Technology
• Original Assignee: National Yunlin University of Science and Technology
• Inventors: Liao, Lan Pin, Wei, Chan Hai, Chou, Jung-Chuan
• Application Number:
  US10/335,850
• Publication Number:
  US 20040132204A1
• Time in Patent Office: Days
• US Class Current: 436/163
• CPC Class Codes: G01N 27/4148 Integrated circuits therefor, e.g. fabricated by CMOS processing CMOS processing per se H01L21/82

Abstract

A portable pH detector. A pH-ISFET is immersed into a solution, and the gate voltage of the pH-ISFET is detected by a signal detection unit. The level of the detected voltage is adjusted by a gain control and level shift unit and is converted by an A/D converter circuit and then output to a 8051 microcontroller to compute the pH of the solution, with the computed result displayed on a LCD.

Claims

1. A portable pH detector, comprising:

a ISFET having a sensing film for immersion in a solution;

a signal detection unit to maintain a drain-source voltage and a drain-source current of the ISFET in a constant condition, and to detect the gate voltage of the ISFET as an output signal;

a gain control and level shift unit to adjust the level of the output signal as a first signal;

a A/D converter to convert the first signal into a first digital signal; and

a microprocessor coupled to the A/D converter to compare the first digital signal with a relational table to obtain the pH of the solution.

2. The portable pH detector of claim 1, wherein the microprocessor comprises:

a 8051 microcontroller coupled to the A/D converter circuit to produce a converter enable signal to enable the A/D converter circuit to convert the first signal into the first digital signal and to compare the first digital signal with the relational table to obtain the pH of the solution; and

a LCD coupled to the 8051 microcontroller to display the pH of the solution.

3. The portable pH detector of claim 2, wherein the relational table is stored in the 8051 microcontroller before testing the solution, and the relational table is created by measuring solutions with pH4 and pH7 for obtaining two corresponding digital values and by calculating corresponding digital values of pH1 to pH13 according to the two corresponding digital values of pH4 and pH7.

4. The portable pH detector of claim 1, wherein the gain control and level shift unit comprises:

an instrumentation amplifier coupled to the output signal and a reference voltage to subtract the level of the reference voltage from the level of the output signal and output a subtracted-level signal;

an operational amplifier coupled to the instrumentation amplifier to amplify the subtracted-level signal for a predetermined time as the first signal.

5. The portable pH detector of claim 4, wherein the gain control and level shift unit further comprises a potential supply circuit having:

a first resistor;

a second resistor coupled to the first resistor in series connection;

a zener diode coupled to the first resistor and the second resistor in parallel connection; and

a DC voltage source across two ends of the zener diode, wherein the DC voltage source is divided by the first resistor and the second resistor as the reference voltage output to the instrumentation amplifier.

6. The portable pH detector of claim 1, wherein the A/D converter circuit is an analog-to-digital converter (IC0804).

7. The portable pH detector of claim 3, wherein the microcontroller and the display reset when power is turned on.

8. The portable pH detector of claim 1, wherein the ISFET is one of a-WO3 gate ISFET or a-C:

H gate ISFET.

9. The portable pH detector of claim 1, wherein the ISFET is a-SnO2 gate ISFET.

10. The portable pH detector of claim 1, wherein the ISFET is a-Si:

H gate ISFET.

11. A method for measuring pH of a solution, compatible with a portable pH detector having a pH-ISFET with a sensing film, a signal detection unit to maintain a drain-source voltage and a drain-source current of the ISFET in a constant condition and detecting the gate voltage of the pH-ISFET, a gain control and level shift unit, a A/D converter and a microprocessor, the method comprising:

measuring a first solution with a first determined pH and a second solution with a second determined pH to obtain a first reference value and a second reference value by the pH-ISFET respectively;

creating a relational table according to the first reference value and a second reference value;

measuring a solution by the pH-ISFET to obtain a first digital value; and

comparing the first digital value and the relational table to determine the pH of the solution.

12. The method for measuring pH of a solution of claim 11, further comprising step of:

initializing the microprocessor; and

checking whether the drain-source voltage and the drain-source current provided by the signal detect unit are compatible with the pH-ISFET.

13. The method for measuring pH of a solution of claim 12, further comprising a step of adjusting the drain-source voltage and the drain-source current to compatible with the pH-ISFET by modifying the first resistor and the second resistor when the drain-source voltage and the drain-source current provided by the signal detect unit are not compatible with the pH-ISFET.

14. The method for measuring pH of a solution of claim 11, wherein steps of measuring a first solution with a first determined pH and a second solution with a second determined pH for creating the relational table comprises:

immersing the sensing film of the pH-ISFET in the first solution with the first determined pH;

measuring the gate voltage of the pH-ISFET after a first time interval;

adjusting the level of the gate voltage to an adequate level;

converting the gate voltage with adjusted level in to a first digital signal as the first reference value;

immersing the sensing film of the pH-ISFET in the second solution with the second determined pH, and measuring, adjusting, and converting the gate voltage to obtain a second digital value as the second reference value; and

creating the relational table according to the first reference value and the second reference value.

15. The method for measuring pH of a solution of claim 12, wherein the first determined time interval is 1.5 minutes.

16. The method for measuring pH of a solution of claim 13, wherein step of testing the solution to obtain the first digital value comprises:

immersing the sensing film of the pH-ISFET in the solution;

measuring the gate voltage of the pH-ISFET after a second time interval;

adjusting the level of the gate voltage to an adequate level; and

converting the gate voltage with adjusted level in to the first digital signal as the first reference value.

17. The method for measuring the pH of a solution of claim 16, wherein the second determined time interval is 1.5 minutes.

18. The method for measuring pH of a solution of claim 11, further comprising a step of displaying the pH of the solution on the microprocessor.