Single compartment unit dose fabric treatment product comprising pouched compositions with cationic fabric softener actives

• US 20040142840A1
• Filed: 12/19/2003
• Published: 07/22/2004
• Est. Priority Date: 12/19/2002
• Status: Abandoned Application

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Boutique, Jean-Pol, Gualco, Lorenzo Matteo Pierre, Billiauw, Jan Julien Marie-Louise, de Buzzaccarini, Francesco
• Application Number:
  US10/742,554
• Publication Number:
  US 20040142840A1
• Time in Patent Office: Days
• US Class Current: 510/296
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 1/65 Mixtures of anionic with cationic compounds
• CPC Class Codes: C11D 17/043 Liquid or thixotropic (gel) compositions
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/227 with nitrogen-containing groups

Abstract

The present invention relates a unit dose fabric treatment product comprising a non-aqueous liquid fabric treatment composition contained in a single compartment water-soluble pouch. The inner space of the pouch contains (A) a cleaning system comprising more than 5% by weight of the fabric treatment composition of at least one surfactant; (B) a fabric softening system comprising at least one fabric softening active selected from the group consisting of (i) cationic ammonium-based fabric softening compounds comprising at least one carbonyl functionality; wherein the molar ratio of anionic surfactant to ammonium-based fabric softener is at least 3:1; (ii) cationic guar gums with a charge density between 0.2 meq/gm to 5.0 meq/gm; and (iii) mixtures thereof.

The invention further relates to a method of producing such compositions and to the use of such compositions to impart fabric-cleaning and fabric-softening benefits via single compartment water-soluble pouches to fabric treated therewith.

Claims

1. A unit dose fabric treatment product comprising a non-aqueous liquid fabric treatment composition contained within a single compartment water-soluble pouch, an inner space of said pouch containing

(A) a cleaning system comprising more than 5%, by weight of the fabric treatment composition, of at least one anionic surfactant;

and

(B) a fabric softening system comprising at least one fabric softening active selected from the group consisting of

(i) cationic ammonium-based fabric softening compounds comprising at least one carbonyl functionality;

wherein the molar ratio of anionic surfactant to ammonium-based fabric softener is at least about 3;

1;

(ii) cationic guar gums with a charge density between about 0.2 meq/gm and about 5.0 meq/gm; and

(iii) mixtures thereof.

2. A unit dose fabric treatment product according to claim 1 wherein, in the cleaning system, the surfactant is present at levels of between about 10% and about 80% by weight of the fabric treatment composition.

3. A unit dose fabric treatment product according to claim 2 wherein, in the cleaning system, the surfactant is present at levels of between about 20% and about 60% by weight of the fabric treatment composition.

4. A unit dose fabric treatment product according to claim 1 wherein the cleaning system further comprises a surfactant selected from the group consisting of nonionic, cationic, zwitterionic, and amphoteric surfactants, and mixtures thereof.

5. A unit dose fabric treatment product according to claim 4 wherein, in the cleaning system, at least about 50% by weight of total surfactant comprises a non-alkoxylated anionic surfactant and less than about 50% by weight of total surfactant comprises an alkoxylated surfactant.

6. A unit dose fabric treatment product according to claim 5 wherein, in the cleaning system, at least about 75% by weight of total surfactant comprises a non-alkoxylated anionic surfactant and less than about 25% by weight of total surfactant comprises an alkoxylated surfactant.

7. A unit dose fabric treatment product according to claim 1 wherein, in the fabric softening system, the fabric softening active is present at levels of between about 0.01% and about 20% by weight of the fabric treatment composition.

8. A unit dose fabric treatment product according to claim 7 wherein, in the fabric softening system, the fabric softening active is present at levels of between about 0.5% and about 10% by weight of the fabric treatment composition.

9. A unit dose fabric treatment product according to claim 1 wherein the molar ratio of anionic surfactant to ammonium-based fabric softener is at least about 10:

1.

10. A unit dose fabric treatment product according to claim 1 wherein the cationic guar gum has a charge density between about 0.3 meq/mg and about 2 meq/mg.

11. A unit dose fabric treatment product according to claim 1 wherein the percentage content of water in said fabric treatment composition is below about 15% by weight of the fabric treatment composition.

12. A unit dose fabric treatment product according to claim 11 wherein the percentage content of water in said fabric treatment composition is between about 3.5% and about 6% by weight of the fabric treatment composition.

13. A unit dose fabric treatment product according to claim 1 wherein said fabric treatment composition further comprises a non-aqueous, organic solvent.

14. A unit dose fabric treatment product according to claim 13 wherein said solvent is selected from the group consisting of C₁-C20 linear, branched, cyclic, saturated and/or unsaturated alcohols with one or more free hydroxy groups;

ethers;

polyethers;

amines;

alkanolamines; and

mixtures thereof.

15. A unit dose fabric treatment product according to claim 14 wherein the non-aqueous solvent is selected from the group consisting of 1,2-propandiol, 1.3-propandiol, glycerol, ethylene glycol, diethyleneglycol, and mixtures thereof.

16. A unit dose fabric treatment product according claim 13 wherein the non-aqueous solvent is present at levels of from about 0.1% to about 90% by weight of the fabric treatment composition.

17. A unit dose fabric treatment product according to claim 1 wherein the fabric treatment composition further comprises at least one fatty acid or salt thereof or mixtures thereof at levels of from about 2% to about 40% by weight of the fabric treatment composition.

18. A unit dose fabric treatment product according to claim 1 wherein the fabric treatment composition further comprises a stabilizer.

19. A unit dose fabric treatment product according to claim 18 wherein the stabilizer is selected from the group consisting of trihydroxystearins, hydrogenated oils, derivatives thereof, and mixtures thereof.

20. A unit dose fabric treatment product according to claim 1 wherein the fabric treatment composition further comprises an additional fabric softening active selected from the group consisting of:

(i) a fabric softening clay;

(ii) an uncharged, neutral fabric softening silicone;

(iii) a cationic silicone polymer, when cationic guar gum is present; and

(iv) mixtures thereof.

21. A unit dose fabric treatment product according to claim 1 wherein the pouch comprises a polymer, and/or a co-polymer, and/or a ter-polymer based on polyvinyl alcohol (PVA), polyvinyl pyrrolidone, polyalkylene oxides, acrylamide, acrylic acid, cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides preferably starch, gelatine, xanthan, carragum and other natural gums;

and mixtures thereof.

23. A method of producing a unit dose fabric treatment product according to claim 1 said method comprising the steps of separately preparing said fabric cleaning system and said fabric softening system, and thereinafter combining said systems.

24. The use of a unit dose fabric treatment product according to claim 1 to treat fabrics being laundered and to impart fabric-cleaning and fabric-softening benefits via single compartment water-soluble pouches.

22. A unit dose fabric treatment product comprising a non-aqueous liquid fabric treatment composition contained within a single compartment water-soluble pouch, an inner space of said pouch containing

(A) a cleaning system comprising between about 20% and about 60%, by weight of the fabric treatment composition, of at least one anionic surfactant;

and

(B) between about 0.5% and 10%, by weight of the fabric treatment composition, of a fabric softening system comprising at least one fabric softening active selected from the group consisting of

1. cationic ammonium-based fabric softening compounds comprising at least one carbonyl functionality;

wherein the molar ratio of anionic surfactant to ammonium-based fabric softener is at least about 7;

1;

2. cationic guar gums with a charge density between about 0.3 meq/gm and about 2.0 meq/gm; and

3. mixtures thereof.

(C) from about 2% to about 40% by weight of the fabric treatment composition of at least one fatty acid or salt thereof and mixtures thereof;

wherein the percentage content of water in said fabric treatment composition is between about 3.5% and about 6% by weight of the fabric treatment composition.