Cellular concrete having normal compressive strength

• US 20040149170A1
• Filed: 04/16/2003
• Published: 08/05/2004
• Est. Priority Date: 02/04/2003
• Status: Abandoned Application

• Current Assignee: Osvaldo Moran
• Original Assignee: Osvaldo Moran
• Inventors: Moran, Osvaldo
• Application Number:
  US10/417,388
• Publication Number:
  US 20040149170A1
• Time in Patent Office: Days
• US Class Current: 106/672
• CPC Class Codes: B28C 5/381 Producing cellular concrete B28C5/1269 takes precedence; producing foam B01F23/235, B01F23/291
• CPC Class Codes: B28C 7/0454 Volumetric measuring devices, e.g. for consecutively delivering predetermined volumes of ingredients
• CPC Class Codes: C04B 16/0633 Polypropylene
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 20/004 inorganic
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 2103/0088 Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes
• CPC Class Codes: C04B 2103/40 Surface-active agents, dispersants
• CPC Class Codes: C04B 2111/00232 Temporary foams
• CPC Class Codes: C04B 2111/1093 Reducing the effect of the carbon content, without removing the carbon
• CPC Class Codes: C04B 22/04 Metals, e.g. aluminium used as blowing agent
• CPC Class Codes: C04B 22/126 Fluorine compounds, e.g. silico-fluorine compounds
• CPC Class Codes: C04B 24/04 Carboxylic acids; Salts, anhydrides or esters thereof
• CPC Class Codes: C04B 24/20 Sulfonated aromatic compounds
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 28/04 Portland cements
• CPC Class Codes: C04B 38/0061 closed porosity
• CPC Class Codes: C04B 38/02 by adding chemical blowing agents
• CPC Class Codes: C04B 38/10 by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: C04B 40/00 Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability active ingredients C04B22/00 - C04B24/00; hardening of a well-defined composition C04B26/00 - C04B28/00; making porous, cellular or lightening C04B38/00; mechanical aspects B28, e.g. conditioning the materials prior to shaping B28B17/02
• CPC Class Codes: C04B 40/0032 : Controlling the process of mixing, e.g. adding ingredients in a quantity depending on a measured or desired value B28C7/00 takes precedence
• CPC Class Codes: Y02W 30/91 : Use of waste materials as fillers for mortars or concrete

Abstract

A method for producing hardened cellular concrete having normal compressive strength by producing tiny, unconnected, pre-pour, air-filled bubbles during mixing of cement, cementitious substitutes, sand, coarse aggregates, water, fiber, a surfactant, aluminum flakes or powder, calcium formate, and magnesium silico fluoride and then producing additional tiny, unconnected, post-pour, hydrogen-filled bubbles to replace those air-filled bubbles which are destroyed while pouring the fresh concrete during the casting operation. Only as much matrix is added to the coarse aggregate as is needed to engulf the aggregates while enabling the aggregate particles to be in contact.

Claims

1. A method of sequentially using surfactants for producing pre-pour air-filled bubbles during mixing of fresh concrete and of including a selected amount of aluminum in said matrix for producing post-pour hydrogen-filled bubbles, whereby said post-pour bubbles replace a portion of said pre-pour bubbles which are destroyed during casting of said fresh concrete to form cellular concrete.

2. The method of claim 1, wherein said cellular concrete contains sufficient cementitious matrix that the ratio of matrix volume to aggregate volume reduces void volume in said aggregate, after compaction thereof, to approximately zero, whereby said aggregate is in contacting relationship and said matrix maintains said aggregate in position after hardening of said matrix.

3. The method of claim 2, wherein the density of said cellular concrete is within the range of about 45 to about 100 pounds per cubic foot and the compressive strength of said cellular concrete throughout said range is approximately equal to the compressive strength of normal concrete having a density of 160 pound per cubic foot.

4. The method of claim 3, wherein said fresh concrete comprises cementitious materials, fine aggregates, coarse aggregates, fiber, water, and additives.

5. The method of claim 4, wherein said cementitious materials comprise cement and/or at least one substitute as about 26% to about 27% by weight of said fresh concrete.

6. The method of claim 5, wherein said at least one substitute comprises a pozzolanic material.

7. The method of claim 6, wherein said pozzolanic material is selected from the group fly ash, slag, ground glass and mixtures thereof.

8. The method of claim 6, wherein the pozzolanic material is finely ground.

9. The method of claim 6, wherein said at least one substitute comprises up to about 80% by weight of said cementitious materials.

10. The method of claim 6, wherein said at least one substitute comprises up to about 70% by weight of said cementitious materials.

11. The method of claim 9, wherein fine aggregates comprise fine sand, as approximately 11% by weight of said fresh concrete.

12. The method of claim 11, wherein said coarse aggregates comprise expanded shale, expanded clay, pumice, and similar lightweight materials.

13. The method of claim 12, wherein said fiber is about 1% by weight of said fresh concrete, and said water is about 10.5% by weight of said fresh concrete.

14. The method of claim 13, wherein said additives are pre-mixed in powder form and comprise, as pounds per cubic foot of said fresh concrete:

a) surfactant;

about 0.04;

b) aluminum flakes;

about 0.01;

c) calcium formate;

about 0.06; and

d) magnesium silico fluoride;

about 0.006.

15. The method of claim 4, wherein said surfactant is dodecyl benzenesulfonic acid.

16. The method of claim 4, wherein said aluminum is in the form of aluminum flakes.

17. The method of claim 4, wherein said fiber is polypropylene fiber.

18. The method of claim 4, wherein said cement is Portland cement types I, II or III.

19. A method for ascertaining the exact amount of a preferred matrix to be added to a mixture of aggregates, thereby ascertaining the optimum value of the volume ratio of cementitious matrix to said aggregates, whereby said aggregates will be in contiguous contact with the interstices between said aggregrates filled with and surround by said matrix, according to the following steps:

a) provide a container of predetermined volume;

b) fill said container to the top thereof with desired amounts of aggregates;

c) gently compact said aggregates and add sufficient additional aggregates to coincide with the top of said container;

d) fill said container to overflowing with water, wait for said aggregates to be saturated with said water, if the water level falls below the plane coinciding to the opening at the top of the container, then add additional water to overflow said container;

e) remove said water from said mold and measure its volume;

f) add said volume of said matrix to said aggregates in said container, thereby forming fresh concrete; and

g) subject said fresh concrete in said container to vibration in order to remove voids and then, if necessary, add additional matrix so that said container is exactly filled to the top of said container.

20. The method of claim 19, wherein the mixture of aggregates comprises a mixture of fine and coarse aggregates.

21. The method of claim 19, wherein the suitability of a fly ash can be evaluated as to:

a) the carbon content thereof;

b) said carbon'"'"'s porous surface area; and

c) the capacity of said carbon to adsorb the surfactant, by packing said fly ash into said container, adding a matrix thereto, waiting until said carbon has adsorbed a portion of said matrix, and adding sufficient additional matrix so that said mold is exactly filled to the top of said container.

22. A method of making a fiber reinforced lightweight high strength cellular concrete casting having a cured weight of under ninety pounds per cubic foot, which comprises the steps of:

(1) entraining air in a concrete slurry in the presence of a surfactant to form an aerated concrete slurry having a cementitious cellular structure;

(2) casting the aerated concrete of step 1 in admixture with an in situ hydrogen-gas generating composition present in an amount such that hydrogen gas evolution during casting substantially maintains the cementitious cellular structure of the aerated concrete slurry produced in step 1 during the step of casting.

23. A fiber reinforced lightweight high strength cellular concrete casting having a cured weight of under ninety pounds per cubic foot, made by the process of:

(1) entraining air in a concrete slurry in the presence of a surfactant to form an aerated concrete slurry having a cementitious cellular structure;

(2) casting the aerated concrete of step 1 in an admixture with an in situ hydrogen-gas generating composition present in an amount such that hydrogen gas evolution during casting substantially maintains the cementitious cellular structure of the aerated concrete slurry produced in step 1 during the step of casting.