Carbon nanotube particulate electron emitters

• US 20040150312A1
• Filed: 11/21/2003
• Published: 08/05/2004
• Est. Priority Date: 11/26/2002
• Status: Abandoned Application

• Current Assignee: Unidym, Inc. (Wisepower Co., Ltd.)
• Original Assignee: Unidym, Inc. (Wisepower Co., Ltd.)
• Inventors: Smith, Kenneth A., McElrath, Kenneth O., Yang, Yuemei
• Application Number:
  US10/719,693
• Publication Number:
  US 20040150312A1
• Time in Patent Office: Days
• US Class Current: 313/310
• CPC Class Codes: B01J 23/881 and iron
• CPC Class Codes: B01J 23/8872 Alkali or alkaline earth metals
• CPC Class Codes: B01J 35/0026 Density
• CPC Class Codes: B01J 35/023 Catalysts characterised by dimensions, e.g. grain size
• CPC Class Codes: B01J 35/31 Density
• CPC Class Codes: B01J 35/40 characterised by dimensions, e.g. grain size in a colloidal state B01J35/23; crystallite size B01J35/77
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 2202/02 Single-walled nanotubes
• CPC Class Codes: C01B 2202/04 Nanotubes with a specific amount of walls
• CPC Class Codes: C01B 2202/06 Multi-walled nanotubes
• CPC Class Codes: C01B 2202/34 Length
• CPC Class Codes: C01B 2202/36 Diameter
• CPC Class Codes: C01B 32/162 characterised by catalysts
• CPC Class Codes: C01B 32/168 After-treatment
• CPC Class Codes: C23C 16/26 Deposition of carbon only
• CPC Class Codes: C23C 16/4417 Methods specially adapted for coating powder
• CPC Class Codes: H01J 1/3048 Distributed particle emitters
• CPC Class Codes: H01J 2201/30469 Carbon nanotubes (CNTs)
• CPC Class Codes: H01J 29/481 : Electron guns using field-emission, photo-emission, or secondary-emission electron source
• CPC Class Codes: H01J 9/025 : of field emission cathodes
• CPC Class Codes: Y10S 977/752 : Multi-walled

Abstract

A carbon nanotube electron emitter comprises carbon nanotube particulates on a surface, wherein the carbon nanotube particulates comprise entangled small-diameter carbon nanotubes having one, two, three or four walls and having an outer wall diameter in the range of about 0.5 nm and about 3 nm. The carbon nanotube particulate electron emitter has a cross-sectional dimensional in a range of about 0.1 micron and about 100 microns, preferably about 0.1 micron to about 3 microns. The carbon nanotube particulate electron emitters can comprise ropes of carbon nanotubes. The carbon nanotube particulates are easily dispersed in polymers and other media. The carbon nanotube particulates can be dispersed in a viscous media and applied to a surface by various means. The carbon nanotube particulate electron emitter exhibits very low “turn-on” emission field and can be used in a variety of field emission devices.

Claims

1. An electron emitter comprising a carbon nanotube particulate on a surface wherein the carbon nanotube particulate comprises entangled small-diameter carbon nanotubes wherein the small-diameter nanotubes have an outer diameter in a range of about 0.5 nm and about 3 nm, wherein the carbon nanotube particulate has a cross-sectional dimension in a range of about 0.1 micron and about 100 microns.

2. The electron emitter of claim 1 wherein the particulate has a cross-section dimension in the range of about 0.1 micron and about 3 microns.

3. The electron emitter of claim 1 wherein the carbon nanotubes are selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, triple-walled carbon nanotubes, quadruple-walled carbon nanotubes and combinations thereof.

4. The electron emitter of claim 1 wherein the carbon nanotube particulate comprises ropes of carbon nanotubes.

5. The electron emitter of claim 4 wherein the ropes have a cross-sectional dimension in a range of about 10 nm and about 50 nm.

6. The electron emitter of claim 4 wherein the ropes have a cross-sectional dimension less than 10 nm.

7. The electron emitter of claim 4 wherein the carbon nanotube particulates comprise small-diameter carbon nanotubes having more than about 10 small-diameter carbon nanotubes/μ

m² surface area of the carbon nanotube particulates.

8. The electron emitter of claim 4 wherein the carbon nanotube particulate on the surface has been activated by etching.

9. The electron emitter of claim 4 wherein the electron emitter is a component in a cathode of a field emission device.

10. The electron emitter of claim 10 wherein the field emission device is selected from the group consisting of electron tubes, amplifiers, oscillators, mixers, microwave components, discharge initiators, laser tubes, spark gaps, controlled discharge tubes, directed energy devices, display tubes, flat-panel displays and combinations thereof.

11. A method for making a carbon nanotube electron emitter, comprising:

(a) providing a carbon nanotube particulate wherein the carbon nanotube particulate comprises entangled small-diameter carbon nanotubes, wherein the small-diameter nanotubes have an outer diameter in a range of about 0.5 nm and about 3 nm, wherein the carbon nanotubes are selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, triple-walled carbon nanotubes, quadruple-walled carbon nanotubes and combinations thereof, and wherein the carbon nanotube particulate has a cross-sectional dimension in a range of about 0.1 micron and about 100 microns, and

(b) depositing the carbon nanotube particulate on a surface.

12. The method of claim 11 wherein the carbon nanotube particulate has a cross-sectional dimension in the range of about 0.1 and about 3 microns.

13. The method of claim 11 further comprising activating the carbon nanotubes of the carbon nanotube particulate.

14. The method of claim 13 wherein the activating is done by etching means.

15. The method of claim 14 wherein the etching means is selected from the group consisting of chemical etching, electrochemical etching, physical etching and a combination thereof.

16. The method of claim 14 wherein the etching means comprises chemical etching.

17. The method of claim 16 wherein the chemical etching is done by a method selected from the group consisting of oxidative etching, etching by strong acids, etching by strong bases, and a combination thereof.

18. The method of claim 14 wherein the etching means is selected from the group consisting of sputtering, reactive ion etching, plasma etching and combinations thereof.

19. The method of claim 11 wherein the carbon nanotube particulate is an annealed carbon nanotube particulate.

20. The method of claim 19 wherein the annealed carbon nanotube particulate is prepared by heating the carbon nanotube particulate in nitrogen or an inert gas environment at a temperature between about 800°

C. and 1500°

C. for a time in the range of about 1 and about 24 hours.

21. The method of claim 11 wherein a plurality of carbon nanotube particulates is blended with a matrix material selected from the group consisting of thermoplastic polymers, thermoset polymers, metals, ceramics, and combinations thereof.

22. The method of claim 11 wherein a plurality of carbon nanotube particulates are blended with a matrix material comprising a polymer.

23. The method of claim 11 wherein the depositing of the carbon nanotube particulate on the surface is done by dispersing the particulate in a viscous media to form a carbon nanotube paste and depositing the paste on a surface by a method selected from the group consisting of screen printing, electrophoretic deposition, casting, ink-jet printing, spraying, offset printing, and combinations thereof.