Aqueous composition and method of preparing nonyellowing coating therefrom

• US 20040161542A1
• Filed: 02/05/2004
• Published: 08/19/2004
• Est. Priority Date: 02/13/2003
• Status: Abandoned Application

• Current Assignee: Allen Phillip Marks, Matthew Stewart Gebhard, Otto Carl Ziemann
• Original Assignee: Allen Phillip Marks, Matthew Stewart Gebhard, Otto Carl Ziemann
• Inventors: Marks, Allen Phillip, Ziemann, Otto Carl, Gebhard, Matthew Stewart
• Application Number:
  US10/772,984
• Publication Number:
  US 20040161542A1
• Time in Patent Office: Days
• US Class Current: 427/385.5
• CPC Class Codes: C08F 2/22 Emulsion polymerisation
• CPC Class Codes: C08F 265/04 on to polymers of esters
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C09D 133/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: C09D 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00

Abstract

An aqueous composition containing at least one unsaturated fatty acid ester and polymer having pendant crosslinking groups is provided. The aqueous composition contains less than 5 weight % volatile organic compounds, based on the weight of the aqueous composition. A method is provided for preparing a nonyellowing dry crosslinked coating. The aqueous composition is useful for preparing crosslinked coatings, suitable in coating applications such as architectural or maintenance paints.

Claims

1. An aqueous composition comprising:

a) polymer having pendant crosslinking groups; and

b) one or more unsaturated fatty acid esters;

wherein said unsaturated fatty acid esters have an average iodine number of at least 50;

wherein said unsaturated fatty acid esters comprise less than 10 weight % triethylenically unsaturated fatty acid ester based on the weight of said unsaturated fatty acid esters; and

wherein said aqueous composition comprises less than 5 weight % volatile organic compounds based on weight of said aqueous composition.

2. The aqueous composition according to claim 1 wherein said pendant crosslinking groups are selected from the group consisting of acetoacetoxy groups, cyanoacetoxy groups, amine groups, and vinyl groups.

3. The aqueous composition according to claim 1 wherein said polymer has a minimum film formation temperature of less than 25°

C.

4. The aqueous composition according to claim 1 wherein said unsaturated fatty acid ester is selected from the group consisting of esters of palmitoleic acid, oleic acid, caproleic acid, linoleic acid, and mixtures thereof.

5. The aqueous composition according to claim 1 comprising less than 1.7 weight % of said volatile organic compounds based on weight of said aqueous composition.

6. The aqueous composition according to claim 1 wherein said polymer having pendant crosslinking groups comprising as polymerized units, from 1 to 10 mole % crosslinking monomer, based on total polymerized monomer contained in said polymer having pendant crosslinking groups.

7. A method of preparing a nonyellowing crosslinked coating, comprising the steps of:

a) applying an aqueous composition onto a substrate;

wherein said aqueous composition comprises;

1) polymer having pendant crosslinking groups; and

2) one or more unsaturated fatty acid esters;

wherein said unsaturated fatty acid esters have an average iodine number of at least 50;

wherein said unsaturated fatty acid esters comprise less than 10 weight % triethylenically unsaturated fatty acid ester based on the weight of said unsaturated fatty acid esters; and

wherein said aqueous composition comprises less than 5 weight % volatile organic compounds based on weight of said aqueous composition;

b) drying or allowing to dry said aqueous composition applied to said substrate to prepare a dry coating; and

c) crosslinking or allowing to crosslink said dry coating in the presence of oxygen to provide said nonyellowing crosslinked coating.

8. The method according to claim 7 comprising less than 1.7 weight % of said volatile organic compounds based on the weight of said aqueous composition.

9. The method according to claim 7 wherein said polymer has a minimum film formation temperature of less than 25°

C.

10. The method according to claim 9 wherein said aqueous composition comprises from 0.1 to 3 weight % of said unsaturated fatty acid esters, based on the weight of said aqueous composition.