Photocatalytic material and uses thereof

• US 20040179978A1
• Filed: 04/30/2004
• Published: 09/16/2004
• Est. Priority Date: 10/18/2001
• Status: Abandoned Application

• Current Assignee: Noritake Company Limited (Noritake), Takeshi Kobayashi
• Original Assignee: Noritake Company Limited (Noritake), Takeshi Kobayashi
• Inventors: Kondo, Yoichi, Watanabe, Hirokazu, Kato, Shinji, Kobayashi, Takeshi, Iwata, Misao, Kurobe, Hisanori
• Application Number:
  US10/492,371
• Publication Number:
  US 20040179978A1
• Time in Patent Office: Days
• US Class Current: 422/121
• CPC Class Codes: A62D 2203/10 Apparatus specially adapted for treating harmful chemical agents; Details thereof
• CPC Class Codes: B01J 35/004 Photocatalysts
• CPC Class Codes: B01J 35/39 Photocatalytic properties

Abstract

The present invention relates to a photocatalytic material that can selectively inactivate a specific biologically harmful substance through photocatalysis, and uses thereof.

The photocatalytic material (21) provided by the present invention comprises a photocatalyst (23), and a holding substance (26) having a holding part (17) that specifically holds a specific biologically harmful substance, the holding substance (26) being disposed in a state fixed to at least a part of the surface of the photocatalyst (23). The photocatalytic material (21) is designed such that substantially all of the holding substance (26) is disposed on the surface of the photocatalyst in a form such as to be able to specifically hold a specific biologically harmful substance in the holding part (17).

Claims

1. A photocatalytic material used to selectively inactivate a specific biologically harmful substance that may be contained in a liquid or gas to be treated, the material comprising:

a photocatalyst; and

a holding substance having a holding part that specifically holds a specific biologically harmful substance, the holding substance being disposed in a state fixed to at least a part of a surface of the photocatalyst;

wherein the photocatalytic material is designed such that substantially all of the holding substance is disposed on the surface of the photocatalyst in a form such as to be able to specifically hold a specific biologically harmful substance in the holding part.

2. The photocatalytic material according to claim 1, further comprising bridging molecules that link the holding substance to the photocatalyst, wherein sites of the holding substance able to chemically bond to a specific site of each of the bridging molecules designed to link to the holding substance are limited to one location or a few locations such that substantially all of the holding substance disposed on the surface of the photocatalyst can adopt a similar three-dimensional form.

3. The photocatalytic material according to claim 2, wherein the holding substance is an immunoglobulin or a fragment thereof.

4. The photocatalytic material according to claim 1, further comprising a substrate having a prescribed form, wherein the photocatalyst is formed on a surface of the substrate.

5. The photocatalytic material according to claim 4, wherein the substrate is a powder that can be dispersed in a liquid.

11. An apparatus that treats, by photocatalysis, a specific biologically harmful substance contained in a liquid or gas to be treated, the apparatus comprising:

the photocatalytic material according to claim 1;

and

a light source that irradiates light capable of bringing about a photocatalytic reaction onto the photocatalytic material.

12. The apparatus according to claim 11, wherein the photocatalytic material is formed as a powder, the apparatus further comprises a flow path that contains the powdered photocatalytic material and through which a fluid containing the harmful substance is fed, and the light source is provided so as to be able to irradiate light onto the powdered photocatalytic material present in the flow path.

13. The apparatus according to claim 12, further comprising separating means for separating the powdered photocatalytic material out from the fluid flowing through the flow path.

6. A method of manufacturing a photocatalytic material used in selectively inactivating a specific biologically harmful substance that may be contained in a liquid or gas to be treated, the method comprising the steps of:

preparing a photocatalyst that is able to inactivate the harmful substance through photocatalysis;

disposing bridging molecules on a surface of the photocatalyst; and

bonding a holding substance having a holding part that is able to specifically hold a specific harmful substance to each of the bridging molecules disposed on the surface of the photocatalyst, this being a step of bonding the holding substance to the bridging molecules such that substantially all of the holding substance bonded to the bridging molecules comes to be in a form such as to be able to specifically hold a specific biologically harmful substance in the holding part.

7. The method according to claim 6, wherein molecules each having a specific site designed to be linked to the holding substance are used as the bridging molecules, and a substance, for which sites able to chemically bond to the specific site of each of the bridging molecules are limited to one location or a few locations such that substantially all of the holding substance chemically bonded to the bridging molecules and disposed on the surface of the photocatalyst adopts a similar three-dimensional form, is used as the holding substance.

8. The method according to claim 7, wherein an immunoglobulin or a fragment thereof is used as the holding substance.

9. The method according to claim 8, wherein one or a plurality of Fc receptors is/are used as the bridging molecules.

10. The method according to claim 7, wherein an Fab′

fragment of an immunoglobulin is used as the holding substance, and the bridging molecules and the Fab′

fragment are bonded together via the sulfur atom in a mercapto group of the Fab′

fragment.