Method and apparatus for rapid screening of volatiles

• US 20040191122A1
• Filed: 04/13/2004
• Published: 09/30/2004
• Est. Priority Date: 03/06/2000
• Status: Abandoned Application

• Current Assignee: James Claude Carnahan, John Patrick Lemmon, Radislav Alexandrovich Potyrailo, Ralph Joseph May
• Original Assignee: James Claude Carnahan, John Patrick Lemmon, Radislav Alexandrovich Potyrailo, Ralph Joseph May
• Inventors: Potyrailo, Radislav Alexandrovich, Lemmon, John Patrick, May, Ralph Joseph, Carnahan, James Claude
• Application Number:
  US10/823,945
• Publication Number:
  US 20040191122A1
• Time in Patent Office: Days
• US Class Current: 422/68.1
• CPC Class Codes: G01N 33/0009 General constructional details of gas analysers, e.g. portable test equipment G01N1/22 takes precedence
• CPC Class Codes: G01N 33/0047 for organic compounds

Abstract

In one embodiment, the present method includes the steps of introducing a volume of a sample into a vapor delivery line and volatilizing at least a portion of the volume as it is carried through the vapor delivery line. At least a portion of the volatilized volume contacts a sensor element, which produces a signal that is monitored to reveal information about the sample. All components upstream of the sensor element are substantially free of sorbent materials so that the sample volume does not contact a substantially sorbent material before contacting the sensor element.

Claims

1. An apparatus for rapidly screening volatile substances in a sample, said apparatus comprising:

a) an injector;

b) a vapor delivery line in fluid communication with said injector;

c) a sensor element in fluid communication with said vapor delivery line and positioned downstream of said injector and said vapor delivery line, wherein all components upstream of said sensor element are substantially free of sorbent materials; and

d) a monitor in communication with said sensor element.

2. The apparatus of claim 1, wherein said sensor element is an optical sensor element.

3. The apparatus of claim 1, wherein said sensor element is an electrochemical sensor element.

4. The apparatus of claim 1, wherein said sensor element comprises a semiconductor.

5. The apparatus of claim 1, wherein said sensor element is coated with a chemically sensitive material to form a chemically sensitive film proximate the surface of said sensor element.

6. The apparatus of claim 1, wherein said sensor element comprises a quartz crystal.

7. The apparatus of claim 5, wherein said sensor element is coated with a hard-soft block elastomer.

8. The apparatus of claim 7, wherein said sensor element is coated with a silicone polyimide.

9. The apparatus of claim 7, wherein said sensor element is coated with a block dimethylsiloxane-carbonate copolymer.

10. The apparatus of claim 5, wherein said sensor element is coated with an amorphous fluoropolymer.

11. The apparatus of claim 10, wherein said sensor element is coated with a random copolymer of tetrafluoroethylene and perfluoro-2,2-dimethyl-1,3-dioxole.

12. The apparatus of claim 1, comprising an array of sensor elements in fluid communication with said vapor delivery line.

13. The apparatus of claim 5, wherein said monitor is adapted to receive a signal from said sensor element representing a measured property of said chemically sensitive film.

14. The apparatus of claim 13, wherein said monitor comprises a frequency counter to produce data representing said signal as a function of time.

15. The apparatus of claim 14, wherein said monitor further comprises a computer adapted to store said data.