Materials and structures for enhancing the performance or organic light emitting devices
First Claim
1. A device, comprising:
- an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a material having the structure;
wherein;
M is a metal selected from the group consisting of Ti, Zr, Hf, Nb, Re, Sn and Ge;
R1, R2, R3, R4, R5, R6, R7 and R8 each represent no substitution, mono-, di-, or tri- substitution, and wherein the substituents are independently selected from the group consisting of;
alkyl and aryl groups.
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Accused Products
Abstract
A device is provided, having an anode, a cathode, and a first organic layer disposed between the anode and the cathode. The first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode. A second organic layer disposed between the first organic layer and the cathode is also provided. The second organic layer is in direct contact with the first organic layer. The second organic layer may comprise a material having the structure:
M may be selected from the group Ti, Zr, Hf, Nb, Re, Sn and Ge. The substituents R1 through R10 may be selected from the group consisting of alkyl and aryl groups. Each of R1 through R10 may represent no substitution, mono-, di-, or tri- substitution. The second organic layer may comprise a material having a dipole moment less than about 2.0 debyes, such that the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial photon flux of about 1018 photons/sr-sec. The second organic layer may comprise a metal complex having a plurality of ligands, wherein each ligand makes the same contribution to the highest occupied molecular orbital and the lowest unoccupied molecular orbital of the metal complex. The second organic layer may be in direct contact with the cathode, or there may be a separate organic layer between the second organic layer and the cathode. Other metal complexes having quinolate ligands may be used.
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Citations
31 Claims
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1. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a material having the structure;
wherein;
M is a metal selected from the group consisting of Ti, Zr, Hf, Nb, Re, Sn and Ge;
R1, R2, R3, R4, R5, R6, R7 and R8 each represent no substitution, mono-, di-, or tri- substitution, and wherein the substituents are independently selected from the group consisting of;
alkyl and aryl groups. - View Dependent Claims (2, 3, 4, 5, 6, 7)
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8. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a material having the structure;
wherein;
x is an integer from 2 to 4, defining a number of quinolate ligands;
y is an integer from 0 to 3;
M is a metal selected from the group consisting of Ca, Sr, Ba, Ti, Zr, Hf, V, Nb, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Ni, Pd, Pt, Zn, Cd, Hg, Ge, Sn, and Pd. i ranges from 1 to x;
Rai and Rbi each represent no substitution, mono-, di-, or tri- substitution, and wherein the substituents are independently selected from the group consisting of;
alkyl and aryl groups. - View Dependent Claims (9, 10, 11, 12)
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13. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a material having the structure;
- View Dependent Claims (14)
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15. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a material having the structure - View Dependent Claims (16)
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17. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a material having a dipole moment less than about 2.0 debyes, and wherein the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial photon flux of about 1018 photons/sr-sec. - View Dependent Claims (18, 19, 20, 21, 22)
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23. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises an organic material having a dipole moment less than about 2.0 debyes, and a highest unoccupied molecular orbital that is not more than 0.7 eV less than the highest occupied molecular orbital of the hole transporting material in the first organic layer. - View Dependent Claims (24, 25, 26)
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27. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, and wherein the second organic layer comprises a metal complex having a plurality of ligands, wherein each ligand makes the same contribution to the highest occupied molecular orbital and the lowest unoccupied molecular orbital of the metal complex, and wherein the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial photon flux of about 1018 photons/sr-sec. - View Dependent Claims (28)
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29. A device, comprising:
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an anode;
a cathode;
an first organic layer disposed between the anode and the cathode, wherein the first organic layer is capable of phosphorescent emissive when a voltage is applied between the anode and the cathode;
a second organic layer disposed between the first organic layer and the cathode, wherein the second organic layer is in direct contact with the first organic layer, wherein the second organic layer is in direct contact with the cathode, and wherein the device has an unmodified external quantum efficiency of at least about 3% and a lifetime of at least about 1000 hours at an initial photon flux of about 1018 photons/sr-sec. - View Dependent Claims (30, 31)
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Specification