Methods of fracturing subterranean zones penetrated by well bores and fracturing fluids therefor
First Claim
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1. A method of fracturing a subterranean zone comprising:
- pumping a viscous aqueous fracturing fluid into said subterranean zone by way of a well bore at a rate and pressure sufficient to fracture said zone, said aqueous fracturing fluid comprising water, a terpolymer of 2-acrylamido-2-methylpropane sulfonic acid present in an amount of about 60 weight %, acrylamide present in an amount of about 39.5 weight % and acrylic acid or its salts present in an amount of about 0.5 weight %, a cross-linking agent for said terpolymer and a delayed viscosity breaker for effecting a controlled reduction in the viscosity of said fracturing fluid; and
creating a fracture in said formation.
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Abstract
The present invention provides improved methods of fracturing subterranean zones penetrated by well bores and improved fracturing fluids. The fracturing fluids are basically comprised of water, a terpolymer of 2-acrylamido-2-methylpropane sulfonic acid, acrylamide and acrylic acid, or its salts, a cross-linking agent for the terpolymer and a delayed viscosity breaker for effecting a controlled reduction in the viscosity of the fracturing fluid.
35 Citations
30 Claims
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1. A method of fracturing a subterranean zone comprising:
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pumping a viscous aqueous fracturing fluid into said subterranean zone by way of a well bore at a rate and pressure sufficient to fracture said zone, said aqueous fracturing fluid comprising water, a terpolymer of 2-acrylamido-2-methylpropane sulfonic acid present in an amount of about 60 weight %, acrylamide present in an amount of about 39.5 weight % and acrylic acid or its salts present in an amount of about 0.5 weight %, a cross-linking agent for said terpolymer and a delayed viscosity breaker for effecting a controlled reduction in the viscosity of said fracturing fluid; and
creating a fracture in said formation. - View Dependent Claims (2, 4, 5, 6, 7, 8, 10, 11, 12, 13, 14)
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3. (canceled).
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9. (canceled)
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15. A method of fracturing a subterranean zone comprising:
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pumping a viscous aqueous fracturing fluid into said subterranean zone by way of a well bore at a rate and pressure sufficient to fracture said zone, said aqueous fracturing fluid being comprised of water, a terpolymer formed of about 15 to about 80 weight % of 2-acrylamido-2-methylpropane sulfonic acid, from about 20 to about 85 weight % of acrylamide and up to about 10 weight % of acrylic acid or its salts present in said fracturing fluid in an amount of about 0.24 to about 2% by weight of water therein;
, a tetrakis(triethanolaminato)zirconium(IV) cross-linking agent present in said fracturing fluid in an amount of about 0.02 to about 0.7% by weight of water therein and a viscosity breaker comprising sodium bromate present in an amount of from about 0.01 to about 1% by weight of water therein; and
creating a fracture in said formation. - View Dependent Claims (16, 17)
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18. A fluid composition comprising:
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water;
a terpolymer of 2-acrylamido-2-methylpropane sulfonic acid, acrylamide and acrylic acid or its salts for viscosifying said fluid;
a cross-linking agent for said terpolymer; and
a delayed viscosity breaker for effecting a controlled reduction in the viscosity of said fluid. - View Dependent Claims (19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30)
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Specification