Electrodes with multilayer membranes and methods of using and making the electrodes
First Claim
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1. A sensor, comprising:
- a sensing layer disposed on a substrate;
a multilayer flux-limiting membrane disposed on the sensing layer, the membrane comprising a sextet layer comprising six alternating polycationic and polyanionic layers, each layer disposed on and bound to the immediately preceding layer of the membrane.
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Abstract
A sensor including a sensing layer is disposed over an electrode or an optode and a layer-by-layer assembled mass transport limiting membrane disposed over the sensing layer. The membrane includes at least one layer of a polyanionic or polycationic material. The assembled layers of the membrane are typically disposed in an alternating manner. The sensor also optionally includes a biocompatible membrane.
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Citations
20 Claims
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1. A sensor, comprising:
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a sensing layer disposed on a substrate;
a multilayer flux-limiting membrane disposed on the sensing layer, the membrane comprising a sextet layer comprising six alternating polycationic and polyanionic layers, each layer disposed on and bound to the immediately preceding layer of the membrane. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12)
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13. A sensor, comprising:
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an osmium sensing layer disposed on a substrate;
a multilayer flux-limiting membrane disposed on the sensing layer, the membrane comprising a first polyanionic layer and a first polycationic layer, the first polyanionic layer disposed on the sensing layer, at least one of the first polyanionic layer and a first polycationic layer comprising pyridine; and
a biocompatible layer disposed over the multilayer membrane. - View Dependent Claims (14, 15, 16)
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17. A sensor, comprising:
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an osmium sensing layer disposed on a substrate;
a multilayer flux-limiting membrane disposed on the sensing layer, the membrane comprising a first polycationic layer and a first polyanionic layer, the first polycationic layer disposed on the sensing layer, at least one of the first polycationic layer and a first polyanionic layer comprising pyridine; and
a biocompatible layer disposed over the multilayer membrane. - View Dependent Claims (18, 19, 20)
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Specification