Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom

US 20040220359A1
Filed: 04/15/2004
Published: 11/04/2004
Est. Priority Date: 10/15/2002
Status: Active Grant

First Claim

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1. A continuous process to produce a branched olefin polymer comprising:

1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 20% or less under selected polymerization conditions;

2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions;

3) contacting a catalyst component, one or more activators and one or more C2 to C40 olefins in a first reaction zone, at a temperature of greater than 70°

C., and at a residence time of 120 minutes or less; and

4) transfering the contents of the first reaction zone to a second reaction zone and further contacting the contents with a catalyst component, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°

C., and at a residence time of 120 minutes or less; and

5) optionally, transferring the contents of the second reaction zone to a third reaction zone and further contacting the contents with a catalyst compound, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°

C., and at a residence time of 120 minutes or less; and

6) recovering a branched olefin polymer comprising at least 50 mole% of one or more C3 to C40 olefins, where the first catalyst component is present in at least one reaction zone and the second catalyst component is present in a second reaction zone and where in at least one reaction zone the C2 to C40 olefin is a C3 to C40 alpha-olefin.

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Abstract

This invention relates to a continuous process to produce a branched olefin polymer comprising:

1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 20% or less under selected polymerization conditions;

2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% (preferably 40% or more)or more at the selected polymerization conditions;

3) contacting a catalyst component, one or more activators and one or more C2 to C40 olefins in a first reaction zone, at a temperature of greater than 70° C., and at a residence time of 120 minutes or less; and

4) transfering the contents of the first reaction zone to a second reaction zone and further contacting the contents with a catalyst component, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70° C., and at a residence time of 120 minutes or less; and

5) optionally, transferring the contents of the second reaction zone to a third reaction zone and further contacting the contents with a catalyst compound, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70° C., and at a residence time of 120 minutes or less; and

6) recovering a branched olefin polymer comprising at least 50 mole % of one or more C3 to C40 olefins,

where the first catalyst component is present in at least one reaction zone and the second catalyst component is present in a second reaction zone and where in at least one reaction zone the C2 to C40 olefin is a C3 to C40 alpha-olefin.

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56 Claims

1. A continuous process to produce a branched olefin polymer comprising:
- 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 20% or less under selected polymerization conditions;
  
  2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions;
  
  3) contacting a catalyst component, one or more activators and one or more C2 to C40 olefins in a first reaction zone, at a temperature of greater than 70°
  
  C., and at a residence time of 120 minutes or less; and
  
  4) transfering the contents of the first reaction zone to a second reaction zone and further contacting the contents with a catalyst component, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°
  
  C., and at a residence time of 120 minutes or less; and
  
  5) optionally, transferring the contents of the second reaction zone to a third reaction zone and further contacting the contents with a catalyst compound, an activator and or one or more C2 to C40 olefins, at a temperature of greater than 70°
  
  C., and at a residence time of 120 minutes or less; and
  
  6) recovering a branched olefin polymer comprising at least 50 mole% of one or more C3 to C40 olefins, where the first catalyst component is present in at least one reaction zone and the second catalyst component is present in a second reaction zone and where in at least one reaction zone the C2 to C40 olefin is a C3 to C40 alpha-olefin.
- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56)
- - 2. The process of claim 1 wherein the olefin polymer comprises from 50 to 100 mole % of propylene.
  - 3. The process of claim 1 wherein the olefin polymer is homopolypropylene.
  - 4. The process of claim 1 wherein the first catalyst component comprises a non-sterospecific metallocene catalyst compound.
  - 5. The process of claim 1 wherein the second catalyst component comprises a sterospecific metallocene catalyst compound.
  - 6. The process of claim 1 where propylene is present in the first reaction zone.
  - 7. The process of claim 1 where propylene is present in the second reaction zone.
  - 8. The process of claim 1 where propylene is present in a third reaction zone.
  - 9. The process of claim 1 where ethylene is present in the first reaction zone.
  - 10. The process of claim 1 where ethylene is present in the second reaction zone.
  - 11. The process of claim 1 where ethylene is present in a third reaction zone.
  - 12. The process of claim 1 wherein propylene and ethylene are present in the first reaction zone.
  - 13. The process of claim 1 wherein propylene and ethylene are present in the second reaction zone.
  - 14. The process of claim 1 where propylene is present in the first reaction zone at 100 weight %, based upon the weight of the monomers present.
  - 15. The process of claim 1 where propylene is present in the second reaction zone at 100 weight %, based upon the weight of the monomers present.
  - 16. The process of claim 1 where propylene is present in a third reaction zone at 100 weight %, based upon the weight of the monomers present.
  - 17. The process of claim 1 where propylene is present in the first reaction zone at 100 weight %, (based upon the weight of the monomers present in the first reaction zone) and ethylene is present in the second reaction zone at up to 50 weight %, (based upon the weight of the monomers present in the second reaction zone).
  - 18. The process of claim 1 where propylene and ethylene are present in the first reaction zone and no ethylene, other than residual ethylene monomer present in the contents of the first reaction zone, is introduced into the second reaction zone.
  - 19. The process of claim 1 where ethylene is intermittently introduced into one or more reaction zones.
  - 20. The process of claim 1 where ethylene is present in a reaction zone at less than 10 weight %, based upon the weight of the monomers in the reaction zone.
  - 21. The process of claim 1 wherein propylene is present in the first reaction zone, ethylene is present in the second reaction zone, the second catalyst component is present in the first reaction zone, and the first catalyst component is present in the second reaction zone.
  - 22. The process of claim 1 wherein propylene is present in the first reaction zone, propylene and ethylene are present in the second reaction zone, the second catalyst component is present in the first reaction zone, and the first catalyst component is present in the second reaction zone.
  - 23. The process of claim 1 wherein propylene and ethylene are present in the first reaction zone, propylene is present in the second reaction zone, the first catalyst component is present in the first reaction zone, and the second catalyst component is present in the second reaction zone.
  - 24. The process of claim 1 wherein propylene is present in the first reaction zone, propylene and ethylene are present in the second reaction zone, the second catalyst component is present in the first reaction zone, and the second catalyst component is present in the second reaction zone.
  - 25. The process of claim 1 wherein ethylene is present in the first reaction zone, propylene is present in the second reaction zone, propylene is present in the third reaction zone, the first catalyst component is present in the second reaction zone, and the second catalyst component is present in a third reaction zone, and the catalyst compound present in the first reaction zone is capable of producing polymer having an Mw of 20,000 or less and a crystallinity of 10% or less at the selected polymerization conditions.
  - 26. The process of claim 1 wherein the first catalyst component comprises a non-sterospecific metallocene catalyst compound;
    - 2) the second catalyst component comprises a sterospecific metallocene catalyst compound;
      
      3) the first reaction zone is a reactor comprising solvent, monomer, catalyst compound and activator at a temperature of greater than 70°
      
      C.; and
      
      4) The second reaction zone is a reactor comprising solvent, monomer, catalyst compound and activator at a temperature of greater than 70°
      
      C.
  - 27. The process of claim 1 where the catalyst compound capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 10% or less is selected from the group consising of:
    - rac-dimethylsilylbis(4,7-dimethylindenyl) hafnium dichloride, rac-dimethylsilylbis(4,7-dimethylindenyl)hafnium dimethyl, rac-dimethylsilylbis(4,7-dimethylindenyl)zirconium dichloride, rac-dimethylsilylbis(4,7-dimethylindenyl)zirconium dimethyl, rac-dimethylsilylbis(indenyl)hafnium dichloride, rac-dimethylsilylbis(indenyl)hafnium dimethyl, rac-dimethylsilylbis(indenyl)zirconium dichloride, rac-dimethylsilylbis(indenyl)zirconium dimethyl, rac-dimethylsilylbis(tetrahydroindenyl)hafnium dichloride, rac-dimethylsilylbis(tetrahydroindenyl)hafnium dimethyl, rac-dimethylsilylbis(tetrahydroindenyl)zirconium dichloride, rac-dimethylsilylbis(tetrahydroindenyl)zirconium dimethyl, rac-diphenylsilylbis(4,7-dimethylindenyl)hafnium dichloride, rac-diphenylsilylbis(4,7-dimethylindenyl)hafnium dimethyl, rac-diphenylsilylbis(4,7-dimethylindenyl)zirconium dichloride, rac-diphenylsilylbis(4,7-dimethylindenyl)zirconium dimethyl, rac-diphenylsilylbis(indenyl)hafnium dichloride, rac-diphenylsilylbis(indenyl)hafnium dimethyl, rac-diphenylsilylbis(indenyl)zirconium dichloride, rac-diphenylsilylbis(indenyl) zirconium dimethyl, rac-diphenylsilylbis(tetrahydroindenyl)hafnium dichloride, rac-diphenylsilylbis(tetrahydroindenyl)hafnium dimethyl, rac-diphenylsilylbis(tetrahydroindenyl)zirconium dichloride, rac-diphenylsilylbis(tetrahydroindenyl)zirconium dimethyl, rac-methylphenylsilylbis(4,7-dimethylindenyl)hafnium dichloride, rac-methylphenylsilylbis(4,7-dimethylindenyl)hafnium dimethyl, rac-methylphenylsilylbis(4,7-dimethylindenyl)zirconium dichloride, rac-methylphenylsilylbis(4,7-dimethylindenyl)zirconium dimethyl, rac-methylphenylsilylbis(indenyl)hafnium dichloride, rac-methylphenylsilylbis(indenyl)hafnium dimethyl, rac-methylphenylsilylbis(indenyl)zirconium dichloride, rac-methylphenylsilylbis(indenyl)zirconium dimethyl, rac-methylphenylsilylbis(tetrahydroindenyl)hafnium dichloride, rac-methylphenylsilylbis(tetrahydroindenyl)hafnium dimethyl, rac-methylphenylsilylbis(tetrahydroindenyl)zirconium dichloride, rac-methylphenylsilylbis(tetrahydroindenyl)zirconium dimethyl, rac-ethylenebis(4,7-dimethylindenyl)hafnium dichloride, rac-ethylenebis(4,7-dimethylindenyl)hafnium dimethyl, rac-ethylenebis(4,7-dimethylindenyl)zirconium dichloride, rac-ethylenebis(4,7-dimethylindenyl)zirconium dimethyl, rac-ethylenebis(indenyl)hafnium dichloride, rac-ethylenebis(indenyl)hafnium dimethyl, rac-ethylenebis(indenyl)zirconium dichloride, rac-ethylenebis(indenyl)zirconium dimethyl, rac-ethylenebis(tetrahydroindenyl)hafnium dichloride, rac-ethylenebis(tetrahydroindenyl)hafnium dimethyl, rac-ethylenebis(tetrahydroindenyl)zirconium dichloride, and rac-ethylenebis(tetrahydroindenyl)zirconium dimethyl.
  - 28. The process of claim 1 wherein the first catalyst component comprises one or more of dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(t-butylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(s-butylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido)titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido)titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dichloride, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido)titanium dichloride, methylene(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, methylene(tetramethylcyclopentadienyl)(cyclohexylamido)titanium dichloride, methylene(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(2,5-dimethylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclohexylamido)titanium dichloride, dimethylsilyl(2,5-dimethylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamido)titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbornylamido)titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido)titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido)titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido)titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbornylamido)titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(t-butylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(s-butylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido)titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido)titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido)titanium dimethyl, methylene(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclohexylamido)titanium dimethyl, methylene(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido)titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclohexylamido)titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamido)titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbornylamido)titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido)titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido)titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido)titanium dimethyl, and dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbornylamido)titanium dimethyl.
  - 29. The process of claim 1 wherein the second catalyst component comprises one or more of the racemic versions of:
    - dimethylsilyl (2-methyl-4-phenylindenyl)zirconium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl)zirconium dimethyl, dimethylsilyl (2-methyl-4-phenylindenyl)hafnium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl)hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dichloride, dimethylsilyl bis(indenyl)zirconium dimethyl, dimethylsilyl bis(indenyl)zirconium dichloride, the racemic isomers of;
      
      dimethylsilanediylbis(2-methyl)metal dichloride;
      
      dimethylsilanediylbis(indenyl)metal dichloride;
      
      dimethylsilanediylbis(indenyl)metal dimethyl;
      
      dimethylsilanediylbis(tetrahydroindenyl)metal dichloride;
      
      dimethylsilanediylbis(tetrahydroindenyl)metal dimethyl;
      
      dimethylsilanediylbis(indenyl)metal diethyl; and
      
      dibenzylsilanediylbis(indenyl)metal dimethyl;
      
      wherein the metal can be chosen from Zr, Hf, or Ti.
  - 30. The process of claim 1 wherein the first catalyst component comprises 1,1′
    - -bis(4-triethylsilylphenyl)methylene-(cyclopentadienyl)(2,7-di-tertiary-butyl-9-fluorenyl)hafnium dimethyl and or 1,1′
      
      -bis(4-triethylsilylphenyl)methylene-(cyclopentadienyl)(3,8-di-tertiary-butyl-fluorenyl)hafnium dimethyl.
  - 31. The process of claim 1 wherein the second catalyst component comprises dimethylsilyl bis(2-methyl-5-phenylindenyl)zirconium dicmethyl and or dimethylsilyl bis(2-methyl-4-phenylindenyl)zirconium dicmethyl.
  - 32. The process of claim 1 wherein the activator comprises dimethylaniliniumtetrakis(pentafluorophenyl)borate and or trityl tetrakis(pentafluorophenyl)borate.
  - 33. The process of claim 1 wherein the activator comprises an alumoxane.
  - 34. The process of claim 1 wherein the activator comprises an ionizing compound.
  - 35. The process of claim 1 wherein the activator comprises a non-coordinating anion.
  - 36. The process of claim 1 wherein the activator comprises one or more of methylalumoxane, trimethylammonium tetraphenylborate, triethylammonium tetraphenylborate, tripropylammonium tetraphenylborate, tri(n-butyl)ammonium tetraphenylborate, tri(t-butyl)ammonium tetraphenylborate, N,N-dimethylanilinium tetraphenylborate, N,N-diethylanilinium tetraphenylborate, N,N-dimethyl-(2,4,6-trimethylanilinium)tetraphenylborate, trimethylammonium tetrakis(pentafluorophenyl)borate, triethylammonium tetrakis(pentafluorophenyl)borate, tripropylammonium tetrakis(pentafluorophenyl)borate, tri(n-butyl)ammonium tetrakis(pentafluorophenyl)borate, tri(sec-butyl)ammonium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, N,N-diethylanilinium tetrakis(pentafluorophenyl)borate, N,N-dimethyl-(2,4,6-trimethylanilinium)tetrakis(pentafluorophenyl)borate, trimethylammonium tetrakis-(2,3,4,6-tetrafluorophenylborate, triethylammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, tripropylammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, tri(n-butyl)ammonium tetrakis-(2,3,4,6-tetrafluoro-phenyl)borate, dimethyl(t-butyl)ammonium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, N,N-dimethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, N,N-diethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl)borate, and N,N-dimethyl-(2,4,6-trimethylanilinium)tetrakis-(2,3,4,6-tetrafluorophenyl)borate;
    - di-(i-propyl)ammonium tetrakis(pentafluorophenyl)borate;
      
      dicyclohexylammonium tetrakis(pentafluorophenyl)borate;
      
      triphenylphosphonium tetrakis(pentafluorophenyl)borate;
      
      tri(o-tolyl)phosphonium tetrakis(pentafluorophenyl)borate; and
      
      tri(2,6-dimethylphenyl)phosphonium tetrakis(pentafluorophenyl)borate.
  - 37. The process of claim 1 wherein the first catalyst component is capable of polymerizing macromonomers having reactive termini;
    - and the second component is capable of producing macromonomers having reactive termini.
  - 38. The process of claim 1 wherein one or more reaction zones further comprise diolefin.
  - 39. The process of claim 1 wherein one or more reaction zones further comprise one or more C4 to C40 dienes.
  - 40. The process of claim 1 wherein one or more reaction zones further comprise one or more dienes selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
  - 41. The process of claim 1 wherein at least one reaction zone is a gas phase reactor.
  - 42. The process of claim 1 wherein at least one reaction zone is a solution phase reactor.
  - 43. The process of claim 1 wherein at least one reaction zone is a slurry phase reactor.
  - 44. The process of claim 1 wherein all of the reaction zones are a solution phase reactor.
  - 45. The process of claim 1 wherein the first catalyst component, the second catalyst component and the activator comprise one or more of the following combinations (where Me equals methyl, Ph equals phenyl, Et equals ethyl, Cp equals cyclopentadienyl, 3,6-di-t-BuFlu equals 3,8-di-tert-butylfluorenyl, 2-Me-4-PhInd equals 2-methyl-4-phenylindenyl, 2-MeInd means 2-methylindenyl, c-C₁₂H₂₃equals cyclododecyl, Me₄C₅-tetramethylcyclopentadienyl, H₄Ind equals tetrahydroindenyl, and Ind equals indenyl):
    - (1) Me₂Si(Me₄C₅)(N-c-C₁₂H₂₃)TiCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (2) Me₂Si(Me₄C₅)(N-c-C₁₂H₂₃)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator, (2a) Me₂Si(Me₄C₅)(N-c-C₁₂H₂₃)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (3) Me₂Si(Me₄C₅)(N-c-C₁₂H₂₃)TiCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (4) Me₂Si(Me₄C₅)(N-c-C₁₂H₂₃)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (4a) Me₂Si(Me₄C₅)(N-c-C₁₂H₂₃)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (5) Me₂Si(Me₄C₅)(N-1-adamantyl)TiCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (6) Me₂Si(Me₄C₅)(N-1-adamantyl)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (6a) Me₂Si(Me₄C₅)(N-1-adamantyl)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (7) Me₂Si(Me₄C₅)(N-1-adamantyl)TiCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (8) Me₂Si(Me₄C₅)(N-1-adamantyl)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (8a) Me₂Si(Me₄C₅)(N-1-adamantyl)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (9) Me₂Si(Me₄C₅)(N-t-butyl)TiCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (10) Me₂Si(Me₄C₅)(N-t-butyl)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (10a) Me₂Si(Me₄C₅)(N-t-butyl)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (11) Me₂Si(Me₄C₅)(N-t-butyl)TiCl₂and rac-Me₂Si(2-MeInd) activated with an alumoxane;
      
      (12) Me₂Si(Me₄C₅)(N-t-butyl)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (12a) Me₂Si(Me₄C₅)(N-t-butyl)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (13) Me₂Si(Me₄C₅)(N-exo-norbornyl)TiCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (14) Me₂Si(Me₄C₅)(N-exo-norbornyl)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (14a) Me₂Si(Me₄C₅)(N-exo-norbornyl)TiMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (15) Me₂Si(Me₄C₅)(N-exo-norbornyl)TiCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (16) Me₂Si(Me₄C₅)(N-exo-norbornyl)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (16a) Me₂Si(Me₄C₅)(N-exo-norbornyl)TiMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (17) (P-Et₃SiPh)₂C(Cp)(3,8-di-t-BuFlu)HfCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (18) (p-Et₃SiPh)₂C(Cp)(3,8-di-t-BuFlu)HfMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (18a) (p-Et₃SiPh)₂C(Cp)(3,8-di-t-BuFlu)HfMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (19) (p-Et₃SiPh)₂C(Cp)(3,8-di-t-BuFlu)HfCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (20) (p-Et₃SiPh)₂C(Cp)(3,8-di-t-BuFlu)HfNe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (20a) (p-Et₃SiPh)₂C(Cp)(3,8-di-t-BuFlu)HfMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (21) meso-CH₂CH₂(Ind)₂ZrCl₂and rac-Me₂Si(H₄Ind)₂ZrCl₂activated with an alumoxane;
      
      (22) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-Me₂Si(H₄Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (22a) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-Me₂Si(H₄Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (23) meso-CH₂CH₂(Ind)₂ZrCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (24) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (24a) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (25) meso-Me₂Si(Ind)₂ZrCl₂and rac-Me₂Si(H₄Ind)₂ZrCl₂activated with an alumoxane;
      
      (26) meso-Me₂Si(Ind)₂ZrMe₂and rac-Me₂Si(H₄Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (26a) meso-Me₂Si(Ind)₂ZrMe₂and rac-Me₂Si(H₄Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (27) meso-Me₂Si(Ind)₂ZrCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (28) meso-Me₂Si(Ind)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (28a) meso-Me₂Si(Ind)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (29) meso-Me₂Si(2-MeInd)₂ZrCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (30) meso-Me₂Si(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (30a) meso-Me₂Si(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (31) meso-Me₂Si(2-MeInd)₂ZrCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (32) meso-Me₂Si(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (32a) meso-Me₂Si(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (33) meso-CH₂CH₂(2-MeInd)₂ZrCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (34) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (34a) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (35) meso-CH₂CH₂(2-MeInd)₂ZrCl₂and rac-Me₂Si(2-MeInd)₂ZrCl₂activated with an alumoxane;
      
      (36) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (36a) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-Me₂Si(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (37) meso-Me₂Si(2-Me-4-PhInd)₂ZrCl₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (38) meso-Me₂Si(2-Me-4-PhInd)₂ZrMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (38a) meso-Me₂Si(2-Me-4-PhInd)₂ZrMe₂and rac-Me₂Si(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (39) meso-CH₂CH₂(2-Me-4-PhInd)₂ZrCl₂and rac-CH₂CH₂(2-Me-4-PhInd)₂ZrCl₂activated with an alumoxane;
      
      (40) meso-CH₂CH₂(2-Me-4-PhInd)₂ZrMe₂and rac-CH₂CH₂(2-Me-4-PhInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (40a) meso-CH₂CH₂(2-Me-4-PhInd)₂ZrMe₂and rac-CH₂CH₂(2-Me-4-PhInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (41) meso-CH₂CH₂(2-MeInd)₂ZrCl₂and rac-CH₂CH₂(2-MePhInd)₂ZrCl₂activated with an alumoxane;
      
      (42) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-CH₂CH₂(2-MeInd)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (42a) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-CH₂CH₂(2-MeInd)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (43) meso-CH₂CH₂(Ind)₂ZrCl₂and rac-CH₂CH₂(Ind)₂ZrCl₂activated with an alumoxane;
      
      (44) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-CH₂CH₂(Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (44a) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-CH₂CH₂(Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (45) meso-Me₂Si(Ind)₂ZrCl₂and rac-Me₂Si(Ind)₂ZrCl₂activated with an alumoxane;
      
      (46) meso-Me₂Si(Ind)₂ZrMe₂and rac-Me₂Si(Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (46a) meso-Me₂Si(Ind)₂ZrMe₂and rac-Me₂Si(Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (47) meso-CH₂CH₂(Ind)₂ZrCl₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrCl₂(4,7-Me₂Ind=4,7-dimethylindenyl) activated with an alumoxane;
      
      (48) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (48a) meso-CH₂CH₂(Ind)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakispentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (49) meso-Me₂Si(Ind)₂ZrCl₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrCl₂activated with an alumoxane;
      
      (50) meso-Me₂Si(Ind)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (50a) meso-Me₂Si(Ind)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (51) meso-CH₂CH₂(2-MeInd)₂ZrCl₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrCl₂(4,7-Me₂Ind=4,7-dimethylindenyl) activated with an alumoxane;
      
      (52) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      (52a) meso-CH₂CH₂(2-MeInd)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
      
      (53) meso-Me₂Si(2-MeInd)₂ZrCl₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrCl₂activated with an alumoxane;
      
      (54) meso-Me₂Si(2-MeInd)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with a non-coordinating anion activator;
      
      or (54a) meso-Me₂Si(2-MeInd)₂ZrMe₂and rac-CH₂CH₂(4,7-Me₂Ind)₂ZrMe₂activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron.
  - 46. The process of claim 1 wherein:
    - 1) the first catalyst component is capable of producing a polymer having an Mw of 80,000 or less and a crystallinity of 15% or less under selected polymerization conditions;
      
      2) the a second catalyst component is capable of producing polymer having an Mw of 80,000 or less and a crystallinity of 50% or more at the selected polymerization conditions;
      
      3) the temperature in the reaction zones is greater than 105°
      
      C.;
      
      4) the residence time in the reaction zones is 10 minutes or less;
      
      5) the ratio of the first catalyst to the second catalyst is from 1;
      
      1 to 20;
      
      1;
      
      6) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst compounds; and
      
      wherein at least 80% of the olefins are converted to polymer.
  - 47. The process of claim 46 wherein:
    - a) the olefins comprise propylene and one or more of butene, pentene, hexene, heptene, octene;
      
      nonene, decene, dodecene; and
      
      b) the temperature is greater than 110°
      
      C.; and
      
      c) the residence time is 5 minutes or less; and
      
      d) the ratio of the first catalyst to the second catalyst is from 1;
      
      1 to 1;
      
      10.
  - 48. The process of claim 1 wherein the step of recovering a branched olefin polymer comprising at least 50 mole % of one or more C3 to C40 olefins comprises:
    - 1) withdrawing polymer solution from the reaction zone;
      
      2) removing at least 10% solvent from the polymer solution;
      
      3) quenching the reaction;
      
      4) devolatilizing the polymer solution to form molten polymer;
      
      5) combining the molten polymer and one or more additives in a static mixer;
      
      6) removing the polymer combination from the static mixer; and
      
      7) pelletizing or drumming the polymer combination.
  - 49. The process of claim 48 wherein the additives in step 5) comprise nucleating agent.
  - 50. The process of claim 1 wherein the second catalyst component comprises one or more of:
    - dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, ⁴-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-isobutyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dichloride;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂hafnium dimethyl;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis- trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-propyl, 4- [3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylsiladiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis- trifluoromethylphenyl]indenyl)2η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)_{2 η}⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      9-silafluorendiyl(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      dimethylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)2η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis- trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      dimethylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      dimethylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      diisopropylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)_{2 η}⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)_{2 η}⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis- trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-butyl, 4-[^3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ₄-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      diisopropylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      diisopropylamidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dichloride;
      
      bis(trimethylsilyl)amidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂η
      
      ⁴-1,4-diphenyl-1,3-butadiene;
      
      bis(trimethylsilyl)amidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-tbutylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -bis-trifluoromethylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-iso-propylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-methyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl;
      
      or bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3′
      
      ,5′
      
      -di-phenylphenyl]indenyl)₂zirconium dimethyl.
  - 51. The process of claim 1 wherein the first catalyst component is also present in the second reaction zone.
  - 52. The process of claim 1 wherein one catalyst component is present in at least one reaction zone and the other catalyst component is present in the second reaction zone.
  - 53. The process of claim 1 wherein 3% or more of the combined catalyst components is not injected into the first reaction zone.
  - 54. The process of claim 1 wherein hydrogen is introduced into a reaction zone.
  - 55. The process of claim 1 wherein the temperature is different in the reaction zones.
  - 56. The process of claim 1 wherein the temperature in a reaction zone is varied.

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Litigation Campaign Assessment

Current Assignee
ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
Original Assignee
ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
Inventors
Abhari, Ramin, Canich, Jo Ann Marie, Jiang, Peijun, Johnsrud, David Raymond, Sims, Charles Lewis

Granted Patent

US 7,223,822 B2
Time in Patent Office

Days
Field of Search
US Class Current

526/65
CPC Class Codes

C08F 10/00   Homopolymers and copolymers...

C08F 110/06   Propene

C08F 2/001   Multistage polymerisation p...

C08F 210/06   Propene

C08F 210/14   Monomers containing five or...

C08F 210/16   Copolymers of ethene with a...

C08F 2420/10   Heteroatom-substituted brid...

C08F 2500/03   Narrow molecular weight dis...

C08F 2500/09   Long chain branches

C08F 2500/17   Viscosity

C08F 2500/20   Activation energy or enthalpy

C08F 297/08   polymerising mono-olefins

C08F 4/65904   in combination with another...

C08F 4/65908   in combination with an ioni...

C08F 4/65912   in combination with an orga...

C08F 4/65927   two cyclopentadienyl rings ...

Y10S 526/943   Polymerization with metallo...

Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom

First Claim

1 Assignment

0 Petitions

Accused Products

Abstract

169 Citations

56 Claims

Specification

Solutions

Use Cases

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Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom

First Claim

1 Assignment

Subscription Required

Subscription Required

0 Petitions

Subscription Required

Accused Products

Subscription Required

Abstract

169 Citations

56 Claims

Specification

Subscription Required

Solutions

Use Cases

Quick Links